SAFETY DATA SHEET WOCO WATER BASED METAL PRIMER 621

Transcription

1 SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name Product number Relevant identified uses of the substance or mixture and uses advised against Identified uses Paint Details of the supplier of the safety data sheet Supplier Witham Group 5-6 Newcombe Road, Lowestoft, Suffolk NR32 1XA Tel: Fax: Emergency telephone number Emergency telephone (01502) Monday to Thursday 8.00am to5.00pm, Friday 8.00am to 4.30pm. SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Not Classified Health hazards Environmental hazards Not Classified Not Classified Classification (67/548/EEC or 1999/45/EC) Label elements Hazard statements EUH208 Contains METHYL-2H or METHYL-4 (3:1) Mixture of EC NO May produce an allergic reaction Other hazards SECTION 3: Composition/information on ingredients 3.2. Mixtures 1/8

2 ISOBUTYRIC ACID ESTER WITH 2,2,4 TRIMETHYL-1,3 PENTANEDIOL <1% CAS number: EC number: Classification Not Classified Classification (67/548/EEC or 1999/45/EC) - METHYL-2H or METHYL-4 (3:1) Mixture of EC NO <1% CAS number: M factor (Acute) = 10 M factor (Chronic) = 10 Classification Acute Tox. 3 - H301 Acute Tox. 3 - H311 Acute Tox. 3 - H331 Skin Corr. 1B - H314 Eye Dam. 1 - H318 Skin Sens. 1 - H317 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Classification (67/548/EEC or 1999/45/EC) T;R23/24/25 C;R34 R43 N;R50/53 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: First aid measures 4.1. Description of first aid measures General information Inhalation Ingestion Skin contact Eye contact Protection of first aiders Keep the affected person warm and at rest. Get prompt medical attention. Never give anything by mouth to an unconscious person. Move affected person to fresh air at once. Get medical attention if any discomfort continues. Place unconscious person on their side in the recovery position and ensure breathing can take place. Get medical attention if any discomfort continues. Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Do not induce vomiting. Remove affected person from source of contamination. Remove contaminated clothing immediately and wash skin with soap and water. Remove any contact lenses and open eyelids wide apart. Rinse immediately with plenty of water. Continue to rinse for at least 10 minutes. Get medical attention immediately. Continue to rinse. No specific requirements are anticipated under normal conditions of use Most important symptoms and effects, both acute and delayed General information See Section 11 for additional information on health hazards Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Use fire-extinguishing media suitable for the surrounding fire Special hazards arising from the substance or mixture 2/8

3 Specific hazards No unusual fire or explosion hazards noted Advice for firefighters Protective actions during firefighting Control run-off water by containing and keeping it out of sewers and watercourses. If risk of water pollution occurs, notify appropriate authorities. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. For non-emergency personnel Avoid contact with skin and eyes Environmental precautions Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up Provide adequate ventilation. Contain spillage with sand, earth or other suitable noncombustible material. Avoid the spillage or runoff entering drains, sewers or watercourses. Wash thoroughly after dealing with a spillage. Inform authorities if large amounts are involved. Absorb spillage with inert, damp, non-combustible material. Flush contaminated area with plenty of water Reference to other sections Reference to other sections For personal protection, see Section 8. SECTION 7: Handling and storage 7.1. Precautions for safe handling Usage precautions Avoid spilling. Avoid contact with eyes Conditions for safe storage, including any incompatibilities Storage precautions Storage class Store in tightly-closed, original container in a dry, cool and well-ventilated place. Store in closed original container at temperatures between 5 C and 25 C. Chemical storage Specific end use(s) Specific end use(s) The identified uses for this product are detailed in Section 1.2. Usage description Avoid inhalation of vapours and contact with skin and eyes. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Ingredient comments WEL = Workplace Exposure Limits ISOBUTYRIC ACID ESTER WITH 2,2,4 TRIMETHYL-1,3 PENTANEDIOL (CAS: ) DNEL Industry - Dermal; Long term : 13.9 mg/kg/day Industry - Inhalation; Long term : 49 mg/m³ Consumer - Inhalation; Long term : 14.5 mg/m³ Consumer - Dermal; Long term : 8.3 mg/kg/day Consumer - Oral; Long term : 8.3 mg/kg/day 8.2. Exposure controls 3/8

4 Protective equipment Eye/face protection Hand protection Other skin and body protection Hygiene measures Respiratory protection Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. The following protection should be worn: Chemical splash goggles. Chemical-resistant, impervious gloves complying with an approved standard should be worn if a risk assessment indicates skin contact is possible. Wear apron or protective clothing in case of contact. Provide eyewash station. Wash at the end of each work shift and before eating, smoking and using the toilet. Promptly remove any clothing that becomes wet or contaminated. Do not smoke in work area. Use appropriate hand lotion to prevent defatting and cracking of skin. When using do not eat, drink or smoke. No specific recommendations. Respiratory protection must be used if the airborne contamination exceeds the recommended occupational exposure limit. If ventilation is inadequate, suitable respiratory protection must be worn. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Colour Odour Coloured liquid. Red-brown. Grey. Slight. ph ph (concentrated solution): Relative density 1.20 Solubility(ies) Miscible with water Other information Volatile organic compound This product contains a maximum VOC content of <1.0 g/l. SECTION 10: Stability and reactivity Reactivity Reactivity No dangerous reactions known Chemical stability Stability Stable at normal ambient temperatures and when used as recommended Possibility of hazardous reactions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid Conditions to avoid Avoid freezing Incompatible materials Materials to avoid Avoid contact with the following materials: Acids Hazardous decomposition products 4/8

5 Hazardous decomposition products Does not decompose when used and stored as recommended. SECTION 11: Toxicological information Information on toxicological effects Skin corrosion/irritation Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/irritation Serious eye damage/irritation Respiratory sensitisation Respiratory sensitisation Skin sensitisation Skin sensitisation Germ cell mutagenicity Genotoxicity - in vitro Carcinogenicity Carcinogenicity Reproductive toxicity Reproductive toxicity - fertility Aspiration hazard Aspiration hazard May cause mild, short lasting discomfort to the eyes. Data lacking. Data lacking. Data lacking. Not relevant. Data lacking. Based on available data the classification criteria are not met. Inhalation Ingestion Skin contact Eye contact Acute and chronic health hazards Medical symptoms Medical considerations Harmful by inhalation. May cause discomfort if swallowed. Skin irritation should not occur when used as recommended. Irritating to eyes. Swallowing concentrated chemical may cause severe internal injury. No specific acute or chronic health impact noted, but this chemical may still have adverse impact on human health, either in general or on certain individuals with pre-existing or latent health problems. No specific symptoms noted, but this chemical may still have adverse health impact, either in general or on certain individuals. Allergies. Toxicological information on ingredients. Acute toxicity - oral ISOBUTYRIC ACID ESTER WITH 2,2,4 TRIMETHYL-1,3 PENTANEDIOL Acute toxicity oral (LD₅₀ mg/kg) Species 3,300.0 Rat Acute toxicity - dermal Acute toxicity dermal (LD₅₀ mg/kg) 15, /8

6 Species Rabbit METHYL-2H or METHYL-4 (3:1) Mixture of EC NO Acute toxicity - oral ATE oral (mg/kg) Acute toxicity - dermal ATE dermal (mg/kg) SECTION 12: Ecological information Ecotoxicity There are no data on the ecotoxicity of this product Toxicity Ecological information on ingredients. ISOBUTYRIC ACID ESTER WITH 2,2,4 TRIMETHYL-1,3 PENTANEDIOL Acute aquatic toxicity Acute toxicity - fish Acute toxicity - aquatic invertebrates Acute toxicity - aquatic plants LC₅₀, 96 hours: 30 mg/l, Fish EC₅₀, 48 hours: 95 mg/l, Daphnia magna IC₅₀, 72 hours: 18.4 mg/l, Algae METHYL-2H or METHYL-4 (3:1) Mixture of EC NO Acute aquatic toxicity LE(C)₅₀ 0.01 < L(E)C M factor (Acute) 10 Acute toxicity - fish Acute toxicity - aquatic invertebrates Acute toxicity - aquatic plants EC₅₀, 96 hours: 0.22 mg/l, Oncorhynchus mykiss (Rainbow trout) EC₈₀, 48 hours: 0.1 mg/l, Daphnia magna EC₈₀, 72 hours: mg/l, Pseudokirchneriella subcapitata Chronic aquatic toxicity M factor (Chronic) Persistence and degradability Persistence and degradability The product is biodegradable Bioaccumulative potential Bioaccumulative potential Bioaccumulation is unlikely. Ecological information on ingredients. METHYL-2H or METHYL-4 (3:1) Mixture of EC NO Mobility in soil Partition coefficient log Kow: /8

7 Mobility The product is soluble in water Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods General information Disposal methods Waste should be treated as controlled waste. Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority. Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority. Absorb in vermiculite, dry sand or earth and place into containers. Dispose of waste via a licensed waste disposal contractor. SECTION 14: Transport information General The product is not covered by international regulations on the transport of dangerous goods (IMDG, IATA, ADR/RID) UN number Not classified as dangerous goods for transport UN proper shipping name Proper shipping name (ADR/RID) PAINT RELATED MATERIAL Proper shipping name (IMDG) PAINT RELATED MATERIAL Proper shipping name (ICAO) Proper shipping name (ADN) PAINT RELATED MATERIAL PAINT RELATED MATERIAL Transport hazard class(es) Not applicable Packing group Not applicable Environmental hazards Environmentally hazardous substance/marine pollutant Special precautions for user Transport in bulk according to Annex II of MARPOL and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations Health and Safety at Work etc. Act 1974 (as amended). Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. 7/8

8 EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (as amended) Chemical safety assessment No chemical safety assessment has been carried out. SECTION 16: Other information Issued by Technical manager Revision date 24/01/2019 Revision 1 Supersedes date 09/08/2018 SDS number Hazard statements in full H301 Toxic if swallowed. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H331 Toxic if inhaled. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. EUH208 Contains METHYL-2H or METHYL-4 (3:1) Mixture of EC NO May produce an allergic reaction. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 8/8