Standard Thinners SAFETY DATA SHEET

Transcription

1 SAFETY DATA SHEET According to Regulation (EC) No 1907/2006, Annex II, as amended by Regulation (EU) 453/2010 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product Name Container Size Variable 1.2. Relevant identified uses of the substance of mixture and uses advised against Identified Uses Uses advised against No additional information available No additional information available 1.3. Details of the supplier of the safety data sheet Supplier Meon Ltd. Railside Northarbour Spur Portsmouth PO9 3TU +44 (0) (0) Emergency Telephone Number Emergency telephone +44 (0) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Flammable liquids, Category 2 Regulation (EC) No. 1272/2008 Skin corrosion/irritation, Category 2 [CLP] Serious eye damage/eye irritation, Category 2 Reproductive toxicity, Category 2 Specific target organ toxicity Single exposure, Category 3, Narcosis Specific target organ toxicity Repeated exposure, Category 2 Full text of H statements : see Section 16 Classification according to Repr.Cat.3; R63 Directive 67/548/EEC or 1999/45/EC Xn; R20/21 Xn; R48/20 Xi; R36/38 Full text of R-phrases: see section Label Elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Signal word Hazard pictograms Danger GHS02: Flame GHS07: Exclamation mark H225 H315 H319 H361 H336 H

2 GHS08: Health hazard Hazardous ingredients TOLUENE, Acetone H- statement(s) H225 - Highly flammable liquid and vapour H315 - Causes skin irritation H319 - Causes serious eye irritation H336 - May cause drowsiness or dizziness H361 - Suspected of damaging fertility or the unborn child H373 - May cause damage to organs through prolonged or repeated exposure P- statement(s) P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P233 - Keep container tightly closed P240 - Ground/bond container and receiving equipment P241 - Use explosion-proof electrical/ventilating/lighting/ equipment P260 - Do not breathe dust/fume/gas/mist/vapours/spray P264 - Wash... thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves/protective clothing/eye protection/face protection P302+P352 - IF ON SKIN: Wash with plenty of water/ P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308+P313 - IF exposed or concerned: Get medical advice/attention P312 - Call a POISON CENTER/doctor/ if you feel unwell P321 - Specific treatment (see... on this label) P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P362+P364 - Take off contaminated clothing and wash it before reuse P370+P378 - In case of fire: Use... to extinguish P403+P233 - Store in a well-ventilated place. Keep container tightly closed P403+P235 - Store in a well-ventilated place. Keep cool P405 - Store locked up P501 - Dispose of contents/container to... Security closing plug for children No Tactile warning No 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable Mixtures Name Product Identifier Classification according to Directive 67/548/EEC 2 9 Classification according to Regulation (EC) 1272/2008 [CLP] %

3 Acetone (CAS No) (EC no) (EC index no) (REACH-no) Xi; R36 R66 R67 Eye Irrit. 2, H319 STOT SE 3, H Xylene (CAS No) (EC no) (EC index no) R10 Xn; R20/21 Xi; R38 Flam. Liq. 3, H226 Acute Tox. 4 (Inhalation), H332 Acute Tox. 4 (Dermal), H312 Skin Irrit. 2, H Toluene (CAS No) (EC no) (EC index no) (REACH-no) Repr.Cat.3; R63 Xn; R65 Xn; R48/20 Xi; R38 Repr. 2, H361d Asp. Tox. 1, H304 STOT RE 2, H373 Skin Irrit. 2, H Isopropanol (CAS No) (EC no) (EC index no) (REACH-no) Xi; R36 R67 Eye Irrit. 2, H319 STOT SE 3, H Methanol Ethyl Acetate (CAS No) (EC no) (EC index no) X (REACH-no) (CAS No) (EC no) (EC index no) (REACH-no) T; R23/24/25 T; R39/23/24/25 Xi; R36 R66 R67 Acute Tox. 3 (Inhalation), H331 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Oral), H301 STOT SE 1, H370 Eye Irrit. 2, H319 STOT SE 3, H336 Specific concentration limits: Name Product Identifier Specific concentration limits: DSD/DPD Specific concentration limits: CLP calculator Xylene (CAS No) (EC no) (EC index no) (C >= 12.5) Xn;R20/21 Methanol (CAS No) (EC no) (EC index no) X (REACH-no) Full text of R- and H-phrases: see section 16 (3 =< C < 20) Xn;R20/21/22 (3 =< C < 10) Xn;R68/20/21/22 (C >= 10) T;R39/23/24/25 (C >= 20) T;R23/24/25 (3 =< C < 10) STOT SE 2, H371 (C >= 10) STOT SE 1, H370 SECTION 4: First aid measures As a general rule, in case of doubt or if symptoms persist, always call a doctor. NEVER induce swallowing by an unconscious person Description of first aid measures General measures If exposed or concerned: Get medical advice/attention. If inhaled Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. In case of skin contact Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see... on this label). In case of eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention Most important symptoms and effects, both acute and delayed 3 9

4 Symptoms/injuries Suspected of damaging fertility or the unborn child. Causes damage to organs. Symptoms/injuries after May cause drowsiness or dizziness. inhalation Symptoms/injuries after Causes skin irritation. skin contact Symptoms/injuries after Causes serious eye irritation. eye contact 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures Flammable. Chemical powders, carbon dioxide and other extinguishing gas are suitable for small fires Extinguishing media 5.2. Special hazards arising from the substance or mixture Fire hazard Highly flammable liquid and vapour. Explosion hazard May form flammable/explosive vapour-air mixture Advice for firefighters SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking. For non-emergency personnel: For emergency responders: Avoid breathing dust/fume/gas/mist/vapours/spray Environmental precautions 6.3. Methods and material for containment and cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage Requirements relating to storage premises apply to all facilities where the mixture is handled Precautions on safe handling Additional hazards when Handle empty containers with care because residual vapours are flammable. processed Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible materials 7.3. Specific end uses SECTION 8: Exposure controls/personal protection 8.1. Control parameters No naked lights. No smoking. Use only non-sparking tools. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a wellventilated area. Wash... thoroughly after handling. Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Keep in fireproof place. Keep container tightly closed. Heat sources. 4 9

5 EU IOELV TWA (mg/m³) 266 mg/m³ (8 hours) EU IOELV TWA (ppm) 200 ppm (8 hours) EU IOELV STEL (mg/m³) 333 mg/m³ (15 mins) EU IOELV STEL (ppm) 250 ppm (15 mins) EU IOELV TWA (ppm) 200 ppm EU IOELV STEL (ppm) 400 ppm EU IOELV TWA (mg/m³) 999 mg/m³ (8 hours) EU IOELV TWA (ppm) 400 ppm (8 hours) EU IOELV STEL (mg/m³) 1250 mg/m³ (15 mins) EU IOELV STEL (ppm) 500 ppm (15 mins) 8.2. Exposure controls Skin and body protection Respiratory protection Wear suitable protective clothing. Where exposure through inhalation may occur from use, respiratory protection equipment is recommended. SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Physical state Liquid Appearance Clear, colourless liquid Colour Clear Odour Characteristic Odour threshold ph 5-9 Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point ( C) Flash point ( C) < 21 Self-ignition temperature Decomposition temperature Flammability (solid, gas) 0.9 C, highly flammable liquid and vapour Vapour pressure Relative vapour density at 20 C Relative density Density (g/cm 3 ) Solubility Low Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Highly flammable liquid and vapour. May form flammable/explosive vapour-air mixture. 5 9

6 10.3. Possibility of hazardous reactions Conditions to avoid Open flame. Direct sunlight Incompatible materials Hazardous decomposition products May release flammable gases. SECTION 11: Toxicological information Information on toxicological effects LD50 oral rat LD50 dermal rabbit LC50 inhalation rat (mg/l) LD50 oral rat LD50 dermal rabbit LC50 inhalation rat (mg/l) LD50 oral rat LD50 oral rabbit LC50 inhalation rat (mg/l) 1187 mg/kg mgkg mg/l/4h 5600 mg/kg mg/kg 58 mg/l (8 hours) 4700 mg/kg 2000 mg/kg 46.5 mg/l/4h Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Causes skin irritation. ph 5-9 Causes serious eye irritation. ph 5-9 Not classified Not classified Not classified Suspected of damaging fertility or the unborn child. May cause drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure. Not classified Substances Mixture SECTION 12: Ecological information Toxicity LC50 fishes mg/l (Lepomis macrochirus (Bluegill) 96 hours) EC50 Daphnia mg/l (48 hours) EC50 other aquatic organisms 1 ~ mg/l (Pseudokirchneriella sucapitata, 96 hours) LC50 fishes mg/l (Pimephales promelas; 96 hours) EC50 Daphnia mg/l (Daphnia magna; 48 hours) (DIN 38412) EC50 other aquatic organisms mg/l (Desmodesmus subspicatus (green algae); 48 hours) EC50 other aquatic organisms mg/l (Pseudomonas putida; 16 hours) 6 9

7 LC50 fishes mg/l (48 hours) LC50 other aquatic organisms mg/l (Algae, 72 hours) EC50 Daphnia mg/l (48 hours) Substances Mixtures Persistence and degradability Persistence and degradability Readily biodegradable. Persistence and degradability The product evaporates easily from water surface. Readily biodegradable. Biodegradation 79 % (Exposure Time: 20 days)(oecd 301 D) Acetone ( ) Persistence and degradability Not established. Persistence and degradability Biodegradable Bioaccumulative potential Log Pow -0.7 Bioaccumulative potential The product has low potential for bioaccumulation. Log Pow 0.6 Bioaccumulative potential BCF: 30 (3 days). Acetone ( ) Bioaccumulative potential Not established. Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating Mobility in soil Ecology - soil The product is miscible with water. May spread in water systems Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Proper waste management of the mixture and/or its container must be determined in accordance with Directive 2008/98/EC Waste treatment methods Waste disposal recommendations Dispose of contents/container to Additional information Handle empty containers with care because residual vapours are flammable. SECTION 14: Transport information Transport product in compliance with provisions of the ADR for road, RID for rail, IMDG for sea and ICAO/IATA for Air Transport (ADR IMDG ICAO/IATA 2014) UN number ADR UN proper shipping name ADR ACETONE Transport hazard class(es) ADR 3 ADR Danger labels 3 7 9

8 14.4. Packing group ADR II Environmental hazards Dangerous for the environment No Marine pollutant No Other information No supplementary information available Special precautions for user ADR Classification code F1 ADR Limited quantities 1L ADR Excepted quantities E2 ADR Packing instructions P001, IBC02, R001 ADR Mixed packing instructions MP19 ADR Mixed portable tank and T4 bulk container instructions ADR Mixed portable tank and TP1 bulk container special provisions ADR tank codes LGBF Vehicle for tank carriage FL ADR Transport category 2 ADR Special provisions for S2, S20 carriage- Operation Hazard identification number 33 (Kemler No.) Orange plates ADR Tunnel restriction code D/E EAC Code 2YE Transport in bulk according to Annex II of MARPOL3/78 and the IBC Code Not applicable. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no substances with Annex XVII restrictions. Contains no REACH candidate substances. Contains no REACH Annex XIV substances National regulations Chemical safety assessment SECTION 16: Other information Full text of R-, H-, and EUH- phrases Acute Tox. 3 (Dermal) - Acute toxicity (dermal), Category 3 Acute Tox. 3 (Inhalation) - Acute toxicity (inhal.), Category 3 Acute Tox. 3 (Oral) - Acute toxicity (oral), Category 3 Acute Tox. 4 (Dermal) - Acute toxicity (dermal), Category 4 Acute Tox. 4 (Inhalation) - Acute toxicity (inhal.), Category 4 8 9

9 Asp. Tox. 1 - Aspiration hazard, Category 1 Eye Irrit. 2 - Serious eye damage/eye irritation, Category 2 Flam. Liq. 2 - Flammable liquids, Category 2 Flam. Liq. 3 - Flammable liquids, Category 3 Repr. 2 - Reproductive toxicity, Category 2 Skin Irrit. 2 - Skin corrosion/irritation, Category 2 STOT RE 2 - Specific target organ toxicity Repeated exposure, Category 2 STOT SE 1 - Specific target organ toxicity single exposure, Category 1 STOT SE 3 - Specific target organ toxicity Single exposure, Category 3, Narcosis H225 - Highly flammable liquid and vapour H226 - Flammable liquid and vapour H301 - Toxic if swallowed H304 - May be fatal if swallowed and enters airways H311 - Toxic in contact with skin H312 - Harmful in contact with skin H315 - Causes skin irritation H319 - Causes serious eye irritation H331 - Toxic if inhaled H332 - Harmful if inhaled H336 - May cause drowsiness or dizziness H361 - Suspected of damaging fertility or the unborn child H361d - Suspected of damaging the unborn child H370 - Causes damage to organs H373 - May cause damage to organs through prolonged or repeated exposure R10 - Flammable R11 - Highly flammable R20/21 - Harmful by inhalation and in contact with skin R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed R36 - Irritating to eyes R36/38 - Irritating to eyes and skin R38 - Irritating to skin R39/23/24/25 - Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation R63 - Possible risk of harm to the unborn child R65 - Harmful: may cause lung damage if swallowed R66 - Repeated exposure may cause skin dryness or cracking R67 - Vapours may cause drowsiness and dizziness F - Highly flammable T - Toxic Xi - Irritant Xn - Harmful SDS EU (REACH Annex II) Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 9 9