REV. DATE: REV. DATE: CAS # Proprietary Proprietary Proprietary. n.e. n.e. air = 1. water = 1

Transcription

1 Aliphatic Amines Polyamide Amine Curing Agent Epoxy Resin Amine Catalyst COMPONENTS ND INDUSTRIES, INC BARRETT ROAD TROY, MICHIGAN (248) Fax: (248) hr. EMERGENCY CHEMTREC: ND 920B FLEXIBLE EPOXY HARDENER MSDS ID: ND3507 ORIG. DATE: 7/24/2008 REV. DATE: REV. DATE: CAS # Proprietary Proprietary Proprietary PERCENT % OSHA PEL PREPARED BY: Chemical Safety SECTION I -Material Identification and Information H: 3 F: 1 R: 0 PPE: ACGIH TLV OTHER LIMITS RECOMMENDED 10 ppm WEEL All ingredients are listed on the TSCA Inventory. = not applicable / =not established SECTION II -Physical and Chemical Characteristics BOILING POINT: VAPOR DENSITY: VAPOR PRESSURE: MELTING POINT: SPECIFIC GRAVITY: EVAPORATION RATE: WATER REACTIVE: SOLUBILITY IN WATER: APPEARANCE AND ODOR: air = water = 1 Soluble Amber liquid with ammoniacal odor. VOC #/US gal. : DENSITY OF COATING: SECTION III - Fire and Explosion Hazard Data FLASH POINT: AUTOIGNITION TEMPERATURE: FLAMMABILITY LIMITS % IN AIR: LEL: UEL: EXTINGUISHER MEDIA: Dry chemical, Carbon dioxide, Alcohol resistant foam SPECIAL FIREFIGHTING PROCEDURES: Wear self contained breathing apparatus for fire fighting. UNUSUAL FIRE HAZARDS AND CONDITIONS TO AVOID: May generate ammonia gas. May generate toxic nitrogen gases. Use of water may result in the formation of toxic aqueous solutions. Do not allow run-off to enter drains or water courses.

2 ND 920B FLEXIBLE EPOXY HARDENER SECTION IV - Reactivity Hazard Data STABILITY: CONDITIONS TO AVOID: stable: HAZARDOUS POLYMERIZATION: x unstable: may occur: will not occur: Sodium hypochlorite, organic acids, mineral acids, oxidizing agents. Reaction with peroxides may result in violent decomposition of peroxide possibly creating an explosion. x INCOMPATIBILITY: Bases HAZARDOUS DECOMPOSITION PRODUCTS: Nitrogen oxides, nitric acid, organic acid vapors, ammonia, carbon monoxide. Nitrogen oxide can react with water vapors to form corrosive nitric acid. SECTION V - Health Hazard Data PRIMARY ROUTES OF ENTRY: EYE CONTACT: INHALATION: X INGESTION: SKIN ABSORPTION: x Causes eye burns. May cause blindness. Product vapor can cause corneal edema when absorbed into the tissue of the eye from the atmosphere. Hold eyelids apart, flush with water for at least 15 minutes. Get medical attention immediately. If medical attention is not promptly available, continue to flush eyes for one hour. Seek medical attention. SKIN CONTACT: Causes skin burns. If absorbed through the skin, may cause central nervous system effects, such as headache, nausea, dizziness, confusion, breathing difficulties. Harmful in contact with skin. INHALATION: Remove contaminated clothing immediately. Wash affected area with soap and water for at least 15 minutes. Get medical attention immediately. If medical attention is not promptly available continue washing affected are Can cause respiratory tract burns. May cause nose, throat, and lung irritation. Severe cases of overexposure may can result in respiratory failure. Move to fresh air. Seek medical attention. INGESTION: t an anticipated route of entry. If swallowed, do not induce vomiting. Prevent aspiration of vomit. Get medical attention. CHRONIC EFFECTS: Carcinogenic:

3 ND 920B FLEXIBLE EPOXY HARDENER Component Oral LD50 Dermal LD50 Inhalation LC50 Aliphatic Amines Polyamide Amine Curing Agent Epoxy Resin Amine Catalyst 3160 mg/kg (rat) 4310 mg/kg (rat) 500 mg/kg (rat) >2000 mg/kg 1673 mg/kg (rat) >2500 mg/kg (rabbit) 2000 mg/kg (rabbit) >2000 mg/kg 1242 mg/kg (rabbit) SECTION VI - Control and Protective Measures RESPIRATORY PROTECTION: Wear appropriate respirator when ventilation is inadequate. PROTECTIVE GLOVES: EYE PROTECTION: VENTILATION TO BE USED: Use chemical impervious gloves, such as neoprene, butyl-rubber, nitrile. glove material is dependent on use and intended use period. Chemical resistant goggles. LOCAL EXHAUST: x MECHANICAL: x SPECIFIC: OTHER (specify): Provide readily accessible eye wash stations and safety showers. Provide adequate ventilation. PROTECTIVE CLOTHING AND EQUIPMENT: Wear chemical impervious clothing. HYGIENIC WORK PRACTICES: Wash hands thoroughly before eating, smoking, or using toilet, and at the end of each shift. SECTION VII - Precautions for Safe Handling and Spill/Leak Procedures STEPS TO BE TAKEN IF MATERIAL IS SPILLED OR RELEASED: Stop material flow if safe to do so. Use self contained breathing apparatus and chemical protective clothing. Only trained personnel should clean up spills. Construct dike to prevent material spread. Use appropriate absorbent. Place materials in an appropriate container. WASTE DISPOSAL METHODS: Dispose of this product in accordance with all local, state, and federal regulations. SAFE HANDLING AND STORAGE: Do not store in reactive metal containers. Keep container tightly closed. Store in a cool dry and well ventilated place. OTHER PRECAUTIONS AND SPECIAL HAZARDOUS INFORMATION: RECOMMENDED NFPA/HMIS RATING HEALTH 3 FLAMMABILITY 1 REACTIVITY 0 note: ratings may differ according to application, environment, and physical state. PERSONAL PROTECTION

4 ND 920B FLEXIBLE EPOXY HARDENER NOTES: SECTION 313 SUPPLIER NOTIFICATION Detaching this notification from the Material Safety Data Sheet is prohibited by law and any copying or distribution of same requires this attachment be included. This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 and 40 CFR 372: CAS # CHEMICAL NAME % BY WEIGHT ne This product contains the following materials that under California Proposition 65 of the Safe Drinking Water and Toxic Enforcement Act of 1986 are recognized to cause cancer or reproductive toxicity. Material Phenyl Glycidyl Ether CAS # Concentration % <6 ppm Cancer Agent X Reproductive Toxin cancer agent & Reproductive Toxin The information contained herein is based on the data available to us and is believed to be correct. However, ND Industries, Inc. makes no warranty, expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. Information is supplied upon the condition that the persons receiving same will make their own determination as to its suitability for their properties prior to use. Since conditions of use are beyond our control, all risks are assumed by the user.

5 COMPONENTS Epoxy Resin Acrylic Copolymer Reaction product-epichlorohydrin & bisphenol-a ND INDUSTRIES, INC BARRETT ROAD TROY, MICHIGAN (248) Fax: (248) hr. EMERGENCY CHEMTREC: ND 920A FLEXIBLE EPOXY RESIN MSDS ID: ND3506 ORIG. DATE: 7/24/2008 REV. DATE: REV. DATE: CAS # Trade Secret PERCENT % OSHA PEL PREPARED BY: Chemical Safety SECTION I -Material Identification and Information H: *2 F: 1 R: 0 PPE: ACGIH TLV OTHER LIMITS RECOMMENDED All ingredients are listed on the TSCA Inventory. = not applicable / =not established SECTION II -Physical and Chemical Characteristics BOILING POINT: VAPOR DENSITY: VAPOR PRESSURE: MELTING POINT: SPECIFIC GRAVITY: EVAPORATION RATE: WATER REACTIVE: SOLUBILITY IN WATER: APPEARANCE AND ODOR: air = 1 VOC #/US gal. : DENSITY OF COATING: 1.13 water = 1 Negligible White viscous liquid with slight epoxy odor. SECTION III - Fire and Explosion Hazard Data FLASH POINT: >480 F AUTOIGNITION TEMPERATURE: FLAMMABILITY LIMITS % IN AIR: LEL: UEL: EXTINGUISHER MEDIA: Dry Chemical, Foam, Carbon Dioxide, Water Spray SPECIAL FIREFIGHTING PROCEDURES: Fire fighters should control run-off water to prevent environmental contamination. Avoid scattering burning material. Move fire exposed containers if safe to do so. Cool fire exposed containers with water. Structural firefighters should wear self contained breathing apparatus and full protective equipment. UNUSUAL FIRE HAZARDS AND CONDITIONS TO AVOID: This material poses a slight fire hazard at elevated temperatures.

6 ND 920A FLEXIBLE EPOXY RESIN SECTION IV - Reactivity Hazard Data STABILITY: stable: HAZARDOUS POLYMERIZATION: CONDITIONS TO AVOID: X Exposure to extreme temperatures. unstable: may occur: will not occur: X INCOMPATIBILITY: Oxidizing materials, Lewis or mineral acids, mineral and organic bases, amines. Avoid unintended contact with water, especially if material is molten as this can cause violent reactions and splatter hot material or ignite other nearby materials. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, phenolics, and various polymer compounds. SECTION V - Health Hazard Data PRIMARY ROUTES OF ENTRY: EYE CONTACT: INHALATION: X INGESTION: SKIN ABSORPTION: May cause mild irritation, pain, reddening, and watering. Abrasion to eye tissue may occur and irritation may be delayed by several hours. Contact with heated material can cause thermal burns. Flush eyes with water for a minimum of 15 minutes, opening top and bottom eye lids. Get medical attention. SKIN CONTACT: INHALATION: Prolonged skin contact may cause dermatitis, inflammation, and reddening. This product may cause dermal sensitization and allergic skin reaction in susceptible individuals. Symptoms may include redness, itching, and rash. Wash thoroughly with soap and water for 15 minutes. If symptoms develop or persist, get medical attention. Inhalation of mists or sprays from this product if heated may irritate the respiratory system. Symptoms include coughing and sneezing. This product may cause allergic respiratory reaction that resembles asthma. Remove victim to fresh air. If symptoms develop of persist get medical attention. INGESTION: Ingestion is not anticipated to be a likely route of entry. If large amounts of this product are swallowed, mouth, throat, and esophagus irritation, and other digestive system irritation may occur. Do not induce vomiting. Call physician or poison control center for most current information. CHRONIC EFFECTS: Repeated skin contact may result in dermatitis. Inhalation and skin contact may result in sensitization and allergic reaction in susceptible individuals. Carcinogenic:

7 ND 920A FLEXIBLE EPOXY RESIN Component Oral LD50 Dermal LD50 Inhalation LC50 Epoxy Resin Acrylic Copolymer Reaction product-epichlorohydrin and bisphenol-a A >2000 mg/kg 1100 mg/kg (rat) >2000 mg/kg 1200 mg/kg (rat) SECTION VI - Control and Protective Measures RESPIRATORY PROTECTION: ne needed under normal circumstance of use. PROTECTIVE Use Ethyl Vinyl Alcohol, Butyl Rubber, Nitrile gloves when handling this product. GLOVES: EYE PROTECTION: Safety glasses with side shields, or splash goggles if operations can generate mists or sprays. VENTILATION LOCAL EXHAUST: X MECHANICAL: X SPECIFIC: TO BE USED: OTHER (specify): Ensure eyewash/shower stations are available near areas where this product is used. PROTECTIVE CLOTHING AND EQUIPMENT: Use body protection appropriate to task. HYGIENIC WORK PRACTICES: Wash hands thoroughly after using this product. SECTION VII - Precautions for Safe Handling and Spill/Leak Procedures STEPS TO BE TAKEN IF MATERIAL IS SPILLED OR RELEASED: Small releases can be cleaned using a damp sponge or polypad. Avoid skin contact. Wear gloves. Large spills should be cleaned by appropriately trained personnel, using appropriate protective equipment. Keep untrained personnel away from spill areas. Use inert absorbent material. Clean spill area with soap and water. Final rinse with water. Place spill residue in appropriate container. WASTE DISPOSAL METHODS: Dispose of in accordance with all local, state, and federal regulations. SAFE HANDLING AND STORAGE: Store this product in a cool dry place, away from direct sunlight, or sources of intense heat. Keep containers closed when not in use. OTHER PRECAUTIONS AND SPECIAL HAZARDOUS INFORMATION: RECOMMENDED NFPA/HMIS RATING HEALTH *2 FLAMMABILITY 1 REACTIVITY 0 note: ratings may differ according to application, environment, and physical state. PERSONAL PROTECTION

8 ND 920A FLEXIBLE EPOXY RESIN NOTES: Proper shipping name: t Regulated SECTION 313 SUPPLIER NOTIFICATION Detaching this notification from the Material Safety Data Sheet is prohibited by law and any copying or distribution of same requires this attachment be included. This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 and 40 CFR 372: CAS # CHEMICAL NAME % BY WEIGHT ne This product contains the following materials that under California Proposition 65 of the Safe Drinking Water and Toxic Enforcement Act of 1986 are recognized to cause cancer or reproductive toxicity. Material CAS # 1,3-Butadiene Acrylonitrile Epichlorohydrin Concentration % Cancer Agent Reproductive Toxin cancer agent & Reproductive Toxin The information contained herein is based on the data available to us and is believed to be correct. However, ND Industries, Inc. makes no warranty, expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. Information is supplied upon the condition that the persons receiving same will make their own determination as to its suitability for their properties prior to use. Since conditions of use are beyond our control, all risks are assumed by the user.