UN/SCEGHS/35/INF.9/Rev.1
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1 Committee of Experts on the Transport of Dangerous Goods and on the Globally Harmonized System of Classification and Labelling of Chemicals 26 April 2018 Sub-Committee of Experts on the Globally Harmonized System of Classification and Labelling of Chemicals Thirty-fifth session Geneva, 4-6 July 2018 Item 4 (b) of the provisional agenda Hazard communication: improvement of annexes 1 to 3 and further rationalization of precautionary statements Proposed changes to and Transmitted by the expert from the United Kingdom on behalf of the working group on improving Annexes 1, 2 and 3 of the GHS
2 2 New text is shown in red. Deleted text is shown in strikethrough. Annex 3 Section 2 Table A3.2.2: Codification of prevention precautionary statements Code Prevention precautionary statements Hazard class Hazard category Conditions for use (1) (2) (3) (4) (5) Delet ed Explosives (chapter 2.1) Unstable explosive Do not handle until all safety precautions have been read and understood. Do not use until all available safety information is understood: follow all specified safety Germ cell mutagenicity (chapter 3.5) 1A, 1B, 2 - omit for consumer products where is used. Carcinogenicity (chapter 3.6) 1A, 1B, 2 Reproductive toxicity (chapter 3.7) 1A, 1B, 2 Reproductive toxicity, effects on or via lactation (chapter 3.7) Explosives (chapter 2.1) Flammable gases (chapter 2.2) Additional category Unstable explosive A, B (chemically unstable gases) Germ cell mutagenicity (chapter 3.5) 1A, 1B, 2 Carcinogenicity (chapter 3.6) 1A, 1B, 2 Reproductive toxicity (chapter 3.7) 1A, 1B, 2 Reproductive toxicity, effects on or via lactation (chapter 3.7) Additional category
3 3 Annex 3 Section 3 EXPLOSIVES (Chapter 2.1) Hazard category Symbol Signal word Hazard statement Unstable explosive Exploding bomb Danger H200 Unstable explosive Do not use until all available safety information is understood: follow all specified safety P250 Do not subject to grinding/shock/friction/ if the explosive is mechanically sensitive. Manufacturer/supplier or the competent authority to specify applicable rough handling. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/... authority to specify the appropriate personal protective equipment. P370 + P372 + P380 + P373 In case of fire: Explosion risk. Evacuate area. DO NOT fight fire when fire reaches explosives. P401 Store in accordance with... Manufacturer/supplier or the competent authority to specify local/regional/ national/international regulations as applicable. P503 Refer to manufacturer/supplier/ for information on disposal/recovery/recycling. Manufacturer/supplier or the competent authority to specify appropriate source of information in accordance with local/regional/national/international regulations as applicable.
4 4 FLAMMABLE GASES (Chapter 2.2) (Chemically unstable gases) Hazard category Symbol Signal word Hazard statement 1A, chemically unstable gas A 1A, chemically unstable gas B Flame Danger H220 H230 Flame Danger H220 H231 Extremely flammable gas May react explosively even in the absence of air Extremely flammable gas May react explosively even in the absence of air at elevated pressure and/or temperature Do not handle until all safety precautions have been read and understood. Do not use until all available safety information is understood: follow all specified safety P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely. P381 In case of leakage, eliminate all ignition sources. P403 Store in a well-ventilated place. Note: This table lists only the precautionary statement that is assigned due to the flammability and the chemical instability of the gas. For the other precautionary statements that are assigned based on the pyrophoricity see the respective table for pyrophoric gas.
5 5 GERM CELL MUTAGENICITY (CHAPTER 3.5) Hazard category Symbol 1 Health hazard 2 Health hazard Signal word Hazard statement Danger H340 May cause genetic defects <...> Warning H341 Suspected of causing genetic defects <...> <...> (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard) - omit for consumer products where is used. Do not handle until all safety precautions have been read and understood. Do not use until all available safety information is understood: follow all specified safety P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/... authority to specify the appropriate personal protective equipment. P308 + P313 IF exposed or concerned: Get medical advice/attention. Manufacturer/supplier or the competent authority to select medical advice or attention as appropriate. P405 Store locked up P501 Dispose of contents/container to in accordance with local/regional/national/international regulations (to be specified). authority to specify whether disposal requirements apply to contents, container or both.
6 6 CARCINOGENICITY (CHAPTER 3.6) Hazard category Symbol Signal word Hazard statement 1 Health hazard Danger H350 May cause cancer <...> 2 Health hazard Warning H351 Suspected of causing cancer <...> <...> (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard) - omit for consumer products where is used. Do not handle until all safety precautions have been read and understood. Do not use until all available safety information is understood: follow all specified safety P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/... authority to specify the appropriate personal protective equipment. P308 + P313 IF exposed or concerned: Get medical advice/attention. Manufacturer/supplier or the competent authority to select medical advice or attention as appropriate. P405 Store locked up. P501 Dispose of contents/container to in accordance with local/regional/national/international regulations (to be specified). Manufacturer/supplier or the competent authority to specify whether disposal requirements apply to contents, container or both.
7 7 REPRODUCTIVE TOXICITY (CHAPTER 3.7) Hazard category Symbol Signal word Hazard statement 1 Health hazard Danger H360 May damage fertility or the unborn child <...> <<...>> 2 Health hazard Warning H361 Suspected of damaging fertility or the unborn child <...> <<...>> <...> (state specific effect if known) <<...>> (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard) - omit for consumer products where is used. Do not handle until all safety precautions have been read and understood. Do not use until all available safety information is understood: follow all specified safety P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/... authority to specify the appropriate personal protective equipment. P308 + P313 IF exposed or concerned: Get medical advice/attention. authority to select medical advice or attention as appropriate. P405 Store locked up. P501 Dispose of contents/container to in accordance with local/regional/national/international regulations (to be specified). Manufacturer/supplier or the competent authority to specify whether disposal requirements apply to contents, container or both.
8 8 REPRODUCTIVE TOXICITY (CHAPTER 3.7) (effects on or via lactation) Hazard category Symbol Signal word Hazard statement (additional) No symbol No signal word H362 May cause harm to breast-fed children - omit for consumer products where is used. Do not handle until all safety precautions have been read and understood. Do not use until all available safety information is understood: follow all specified safety P260 Do not breathe dusts or mists. if inhalable particles of dusts or mists may occur during use. P263 Avoid contact during pregnancy and while nursing. P264 Wash thoroughly after handling. authority to specify parts of the body to be washed after handling. P270 Do not eat, drink or smoke when using this product. P308 + P313 IF exposed or concerned: Get medical advice/attention. authority to select medical advice or attention as appropriate.
Nations, All rights reserved ANNEX 3
ANNEX 3 CODIFICATION OF HAZARD STATEMENTS, CODIFICATION AND USE OF PRECAUTIONARY STATEMENTS, CODIFICATION OF HAZARD PICTOGRAMS AND EXAMPLES OF PRECAUTIONARY PICTOGRAMS ANNEX 3 Section 1 CODIFICATION OF
Code Hazard Statement Hazard Class Pictogram Unstable explosive Explosive; mass explosive hazard Explosive; severe projection hazard
Physical Hazards Code Hazard Statement Hazard Class Pictogram H200 H201 H202 H203 Unstable explosive Explosive; mass explosive hazard Explosive; severe projection hazard Explosive; fire, blast or projection
ANNEX 1 ALLOCATION OF LABEL ELEMENTS
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ANNEX 3 CODIFICATION OF HAZARD STATEMENTS, CODIFICATION AND USE OF PRECAUTIONARY STATEMENTS AND EXAMPLES OF PRECAUTIONARY PICTOGRAMS
ANNEX 3 CODIFICATION OF HAZARD STATEMENTS, CODIFICATION AND USE OF PRECAUTIONARY STATEMENTS AND EXAMPLES OF PRECAUTIONARY PICTOGRAMS - 297- Annex 3 Section 1 CODIFICATION OF HAZARD STATEMENTS A3.1.1 Introduction
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GHS Pictograms GHS Pictogram Symbol in the GHS pictogram GHS hazard classes Means Skull and crossbones Acute toxicity (for oral, skin and inhalation); skin corrosion; respiratory sensitizer Toxic Flame
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SAFETY DATA SHEET (SDS)
1. PRODUCT AND COMPANY IDENTIFICATION 1.1 Product Name: Part Number: CAS-No.: SDS Number: 1.2 Recommended Use: Basic Fuchsin Stain 0.5%, Aqueous 1012 Not applicable 2390 Laboratory Chemicals 1.3 Company:
Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name Product code : Mixture : PHT Load UP : M77727 1.2. Relevant identified
Dry-Graph A Safety Data Sheet
SECTION 1: Product and company identification Product name : Dry-Graph A Use of the substance/mixture : Aerosol Dry lubricant Product code : 1075 SDS Number: 8211 Company : AIS Specialty Products, Inc
Metalworking Coolant & Lube Safety Data Sheet
SECTION 1: Product and company identification Product name : Metalworking Coolant & Lube Use of the substance/mixture : Lubricant. Product code : 0303 Company : Total Solutions P.O. Box 240014 Milwaukee,
: Bone Dry Original Pro
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : Bone Dry Original Pro 1.2. Relevant identified uses of the substance or mixture
Bust B Safety Data Sheet
SECTION 1: Product and company identification Product name : Use of the substance/mixture : Lubricant Product code : 513341 SDS Number: 0302 Company : Superco Specialty Products 25041 Anza Drive Valencia,
: Visible Stain Detection Paste, Copper/Orange
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name. Product code : Mixture : Visible Stain Detection Paste, Copper/Orange
Emergency Tel.No. Please contact the regional HiMedia representation in your country
1. Identification of the substances/ mixture and of the company/ undertaking 1.1 Product Identifiers Product Code GRM6100 Product Name Nickel (II) acetate tetrahydrate, Extra pure 1.2 Relevant identified
SCJP Windex Cleaner Non-Ammoniated
1. PRODUCT AND COMPANY IDENTIFICATION Product information Product name : Recommended use : Hard Surface Cleaner Manufacturer, importer, supplier : S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236
: Amido Black Powder
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Substance name Product code : Substance : : LV501 1.2. Relevant identified uses of
Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
SECTION 1: Identification 1.1. Identification Product form Product name Product code : Mixture : Pigment Eraser II : M77996 1.2. Relevant identified uses of the substance or mixture and uses advised against
Safety Data Sheet 1/6. Manganese(IV)oxide,KISHIDA CHEMICAL CO., LTD.,4729E-1,02/07/2018. Date of issue: 02/07/2018
1/6 Date of issue: 02/07/2018 Safety Data Sheet 1. Identification of the substance/mixture and of the company/undertaking Product identifier: Product name: Manganese(IV)oxide Product code(sds NO): 4729E-1
SC Johnson Professional Defoamer
1. PRODUCT AND COMPANY IDENTIFICATION Product information Product name : Recommended use : Carpet Care Manufacturer, importer, supplier : S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236
: CSP R-97 Water Repellent
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : 1.2. Relevant identified uses of the substance or mixture and uses advised against
SECTION 1: Identification. SECTION 2: Hazard(s) identification. SECTION 3: Composition/information on ingredients
SECTION 1: Identification Manganese Nitrate Date of issue: 12/27/2016 Version: 1.0 1.1. Identification Product form : Mixture Product name : Manganese Nitrate CAS No : 17141-63-8 1.2. Relevant identified