Bases of GHS. GHS Hazard

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Cory Hicks
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1 Bases of GHS GHS Physical s Explosives Flammable gases Flammable aerosols Oxidizing gases Gases under pressure Flammable liquids Flammable solids Pyrophoric liquids Pyrophoric solids Self-heating Substances and which, in contact with water, emit flammable gases Oxidizing liquids Oxidizing solids Organic peroxides Corrosive to metals Health s (Oral) (Dermal) (Inhalat: Gases) (Inhalat: Vapours) (Inhalat: Dusts) (Inhalat: Mists) Skin corros/irritat Serious eye damage/eye irritat Respiratory sensitizat Skin sensitizat Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity Single exposure Specific target organ toxicity Repeated exposure Aspirat hazard Environmental s to Chronic toxicity to

2 Name of Flame Flame over circle Exploding bomb Corros Gas cylinder Skull and crossbones Exclamat mark Environment Health hazard

Pictgram of hazards Explosives,, Organic peroxides Flammable gases, Flammable aerosols, Flammable liquids,

water, emit flammable gases,organic peroxides Oxidizing gases, Oxidizing liquids, Oxidizing solids (Category

Specific target organ toxicity - Single exposure (Category 3) (Category 1-3) Gases under pressure Corrosive

sensitizat, Germ cell mutagenicity, Carcinogenicity, Reproductive toxicity, Specific target organ toxicity -

3 Pictgram of hazards Explosives,, Organic peroxides Flammable gases, Flammable aerosols, Flammable liquids, Flammable solids,, Pyrophoric liquids, Pyrophoric solids,self-heating, Substances and which, in contact with water, emit flammable gases,organic peroxides Oxidizing gases, Oxidizing liquids, Oxidizing solids (Category 4), Skin corros/irritat (Category 2), Serious eye damage/eye irritat (Category 2A), Skin sensitizat, Specific target organ toxicity - Single exposure (Category 3) (Category 1-3) Gases under pressure Corrosive to metals, Skin corros /irritat (Category 1A-C), Serious eye damage/eye irritat (Category 1) Respiratory sensitizat, Germ cell mutagenicity, Carcinogenicity, Reproductive toxicity, Specific target organ toxicity - Single exposure (Category 1-2), Specific target organ toxicity - Repeated exposure, Aspirat hazard Toxicity to the aquatic

4 Label elements and Category in - Oral LD 50 (mg/kg) Criteria Category 1 Category 2 Category 3 Category 4 Category 5 5 or less 50 or less 300 or less 2,000 or less 5,000 or less Pictgram No Pictgram May be Fatal if Fatal if Toxic if Harmful if harmful if statement swallowed swallowed swallowed swallowed swallowed Table of,,, and statement in GHS statement 1 Explosives Unstable Explosive Unstable Explosive 2 Explosives Divis 1.1 Explosive; mass explos hazard 3 Explosives Divis 1.2 Explosive; severe project hazard 4 Explosives Divis 1.3 Explosive; fire, blast or project hazard 5 Explosives Divis 1.4 Fire or project hazard 6 Explosives 7 Explosives Divis 1.5 Divis on orange background 1.6 on orange background May mass explode in fire 8 Flammable gases 1 Extremely flammable gas 9 Flammable gases 2 Flammable gas 10 Flammable aerosols 1 Extremely flammable aerosol

5 statement 11 Flammable aerosols 2 Flammable aerosol 12 Oxidizing gases 1 May cause or intensify fire; oxidizer 13 Gases under pressure Compress ed gas Contains gas under pressure; may explode if heated 14 Gases under pressure Liquefied gas Contains gas under pressure; may explode if heated 15 Gases under pressure Refrigerat ed liquefied gas Contains refrigerated gas; may cause cryogenic burns or injury 16 Gases under pressure Dissolved gas Contains gas under pressure; may explode if heated 17 Flammable liquids 1 Extremely flammable liquid and vapour 18 Flammable liquids 2 Highly flammable liquid and vapour 19 Flammable liquids 3 Flammable liquid and vapour 20 Flammable liquids 4 Combustible liquid 21 Flammable solids 1 Flammable solid 22 Flammable solids 2 Flammable solid 23 Type A Heating may cause an explos 24 Type B Heating may cause a fire or explos 25 Type C Heating may cause a fire

6 statement Type D Heating may cause a fire Type E Heating may cause a fire Type F Heating may cause a fire Type G 30 Pyrophoric liquids 1 Catches fire spontaneously if exposed to air 31 Pyrophoric solids 1 Catches fire spontaneously if exposed to air 32 Self-heating 1 Self-heating; may catch fire 33 Self-heating 2 Self-heating in large quantities; may catch fire Substances and which, in contact with water, emit flammable gases Substances and which, in contact with water, emit flammable gases Substances and which, in contact with water, emit flammable gases In contact with water releases flammable gases which may ignite spontaneously In contact with water releases flammable gases In contact with water releases flammable gases 37 Oxidizing liquids 1 May cause fire or explos; strong oxidizer 38 Oxidizing liquids 2 May intensify fire; oxidizer

7 statement 39 Oxidizing liquids 3 May intensify fire; oxidizer 40 Oxidizing solids 1 May cause fire or explos; strong oxidizer 41 Oxidizing solids 2 May intensify fire; oxidizer 42 Oxidizing solids 3 May intensify fire; oxidizer 43 Organic peroxides Type A Heating may cause an explos 44 Organic peroxides Type B Heating may cause a fire or explos 45 Organic peroxides Type C Heating may cause a fire 46 Organic peroxides Type D Heating may cause a fire 47 Organic peroxides Type E Heating may cause a fire 48 Organic peroxides Type F Heating may cause a fire 49 Organic peroxides Type G 50 Corrosive to metals 1 May be corrosive to metals 51 (Oral) 1 Fatal if swallowed 52 (Oral) 2 Fatal if swallowed 53 (Oral) 3 Toxic if swallowed

8 statement 54 (Oral) 4 Harmful if swallowed 55 (Oral) 5 May be harmful if swallowed 56 (Dermal) 1 Fatal in contact with skin 57 (Dermal) 2 Fatal in contact with skin 58 (Dermal) 3 Toxic in contact with skin 59 (Dermal) 4 Harmful in contact with skin 60 (Dermal) 5 May be harmful in contact with skin 61 (Inhalat: Gases) 1 Fatal if inhaled (gases) 62 (Inhalat: Gases) 2 Fatal if inhaled (gases) 63 (Inhalat: Gases) 3 Toxic if inhaled (gases) (Inhalat: Gases) (Inhalat: Gases) (Inhalat: Vapours) (Inhalat: Vapours) (Inhalat: Vapours) 4 Harmful if inhaled (gases) 5 May be harmful if inhaled (gases) 1 Fatal if inhaled (vapours) 2 Fatal if inhaled (vapours) 3 Toxic if inhaled (vapours)

9 (Inhalat: Vapours) (Inhalat: Vapours) (Inhalat: Dusts) statement 4 Harmful if inhaled (vapours) 5 May be harmful if inhaled (vapours) 1 Fatal if inhaled (dusts) 72 (Inhalat: Dusts) 2 Fatal if inhaled (dusts) 73 (Inhalat: Dusts) 3 Toxic if inhaled (dusts) 74 (Inhalat: Dusts) 4 Harmful if inhaled (dusts) 75 (Inhalat: Dusts) 5 May be harmful if inhaled (dusts) 76 (Inhalat: Mists) 1 Fatal if inhaled (mists) 77 (Inhalat: Mists) 2 Fatal if inhaled (mists) 78 (Inhalat: Mists) 3 Toxic if inhaled (mists) 79 (Inhalat: Mists) 4 Harmful if inhaled (mists) 80 (Inhalat: Mists) 5 May be harmful if inhaled (mists) 81 Skin corros/irritat 1A Causes severe skin burns and eye damage 82 Skin corros/irritat 1B Causes severe skin burns and eye damage 83 Skin corros/irritat 1C Causes severe skin burns and eye damage

10 statement Skin corros/irritat Skin corros/irritat Serious eye damage/eye irritat Serious eye damage/eye irritat Serious eye damage/eye irritat Respiratory sensitizat 2 Causes skin irritat 3 Causes mild skin irritat 1 Causes serious eye damage 2A Causes serious eye irritat 2B Causes eye irritat 1 May cause allergy or asthma symptoms or breathing difficulties if inhaled 90 Skin sensitizat 1 May cause an allergic skin react 91 Germ cell mutagenicity 1A May cause genetic defects 92 Germ cell mutagenicity 1B May cause genetic defects 93 Germ cell mutagenicity 2 Suspected of causing genetic defects 94 Carcinogenicity 1A May cause cancer 95 Carcinogenicity 1B May cause cancer 96 Carcinogenicity 2 Suspected of causing cancer 97 Reproductive toxicity 1A May damage fertility or the unborn child 98 Reproductive toxicity 1B May damage fertility or the unborn child

11 statement 99 Reproductive toxicity 2 Suspected of damaging fertility or the unborn child Reproductive toxicity Specific target organ toxicity Single exposure (via lactat) May cause harm to breastfed children. 1 Causes damage to organs 102 Specific target organ toxicity Single exposure 2 May cause damage to organs 103 Specific target organ toxicity Single exposure 3(respirat ory irritat) May cause respiratory irritat 104 Specific target organ toxicity Single exposure 3(drowsin ess and dizziness) May cause drowsiness and dizziness 105 Specific target organ toxicity Repeated exposure 1 Causes damage to organs through prolonged or repeated exposure 106 Specific target organ toxicity Repeated exposure 2 May cause damage to organs through prolonged or repeated exposure 107 Aspirat hazard Aspirat hazard 2 May be fatal if swallowed and enters airways May be harmful if swallowed and enters airways to to to Chronic toxicity to Chronic toxicity to Chronic toxicity to 1 Very toxic to aquatic life 2 Toxic to aquatic life 3 Harmful to aquatic life Very toxic to aquatic life with long lasting effects Toxic to aquatic life with long lasting effects Harmful to aquatic life with long lasting effects

12 115 Chronic toxicity to 4 statement May cause long lasting harmful effects to aquatic life JICA-DOSH Knowledge Site

ANNEX 1 ALLOCATION OF LABEL ELEMENTS

ANNEXES - 229 - ANNEX 1 ALLOCATION OF LABEL ELEMENTS - 231 - Annex 1 ALLOCATION OF LABEL ELEMENTS For the GHS, the assigned pictogram, signal word and hazard statement are given in that order for each