Ion Exchange resin, Strong acid cation

Transcription

1 SECTION 1: PRODUCT AND COMPANY INFORMATION PRODUCT TYPE: Ion Exchange resin, Strong acid cation PRODUCT NAME: C-211 H family, including C-211 H, C-211 XRR H, C-211 UPS H, C-211C H, C-211 SG H, C-211 PSMB H, and C-211 PSMBSG H COMPANY ID: Evoqua Water Technologies LLC 181 Thorn Hill Drive, Warrendale, PA TELEPHONE NUMBER: INFORMATION: CORPORATE MEDICAL EMERGENCY: CHEMTREC TRANSPORTATION EMERGENCY: CHEMTREC DATE PREPARED: May 11, 2015 REVISION: 0 SECTION 2: HAZARD(S) IDENTIFICATION HMIS RATINGS NFPA RATINGS GUIDE HEALTH 1 4 EXTREME/SEVERE 1 3 HIGH/SERIOUS FLAMMABILITY 1 2 MODERATE SLIGHT PHYSICAL HAZARD 1 0 MINIMUM W WATER REACTIVE OX - OXIDIZER PERSONAL PROTECTION E PICTOGRAM SIGNAL WORD HAZARD STATEMENT Danger Causes serious eye damage. PRECAUTIONARY STATEMENT(S) PREVENTION Wear eye/face protection. Wash hands thoroughly after handling. RESPONSE IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. STORAGE OTHER HAZARDS Not applicable. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS PERCENT BY WEIGHT COMMON NAME (Ingredient / Component) 35-70% Sulfonated polymer of styrene, ethylstyrene and divinylbenzene in the hydrogen form CAS NO. IMPURITIES

2 52-58% Benzene, diethenyl-, polymer with ethenylbenzene and ethenylethylbenzene, sulfonated Balance Water SECTION 4: FIRST-AID MEASURES NECESSARY FIRST AID INSTRUCTIONS INHALATION FIRST AID Get medical attention immediately. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. If not breathing, if breathing is irregular or respiratory arrest occurs, provide artificial respiration, or oxygen by a trained professional, using a pocket type respirator. SKIN CONTACT FIRST AID In case of contact, flush skin with plenty of water for at least 30 minutes. Get medical attention immediately. Immediately remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Wash clothing before reuse. Clean shoes thoroughly before reuse. EYE CONTACT FIRST AID INGESTION FIRST AID: Get medical attention immediately. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. In case of contact with eyes, flush eyes with plenty of water for at least 30 minutes. Chemical burns must be treated promptly by a physician. Get medical attention immediately. Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. DESCRIPTION OF MOST IMPORTANT SYMPTOMS RECOMMENDATIONS FOR IMMEDIATE MEDICAL CARE Treat symptomatically. No specific treatment. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. SECTION 5: FIRE-FIGHTING MEASURES SUITABLE EXTINGUISHING MEDIA Water spray (fog), foam or dry chemical. Resin C-211 H family Date 5/11/15 Rev: 0 Pages 2 of 6

3 UNSUITABLE EXTINGUISHING MEDIA SPECIFIC HAZARDS PERSONAL PROTECTIVE EQUIPMENT None known. Toxic and irritating gases/fumes may be given off during burning or thermal decomposition. Water runoff from firefighting may be corrosive. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. SECTION 6: ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES PERSONAL PRECAUTIONS Without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Hazard of slipping on spilled product. ENVIRONMENTAL PRECAUTIONS CONTAINMENT AND CLEAN-UP OTHER INFORMATION Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Move containers from spill area. Approach release from upwind. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Prevent entry into sewers, water courses, basements or confined areas. SECTION 7: HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING Do not get in eyes or on skin or clothing. Do not ingest. Use only with adequate ventilation. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Remove contaminated clothing and protective equipment before entering eating areas. Workers should wash hands and face before eating, drinking and smoking. Put on appropriate personal protection equipment. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. CONDITIONS FOR SAFE STORAGE Store between the following temperatures: -20 to 40 C (-4 to 104 F). Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Empty containers retain product residue and can be hazardous. Do not reuse container. It is recommended to store ion exchange resins at temperatures above the freezing point of water. If the resin Resin C-211 H family Date 5/11/15 Rev: 0 Pages 3 of 6

4 should become frozen, the resin should not be mechanically handled and should be left to thaw out gradually at ambient temperature. It must be completely thawed before handling or use. No attempt should be made to accelerate the thawing process. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. RESPIRATORY PROTECTION SKIN PROTECTION EYE/FACE PROTECTION Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Wear suitable protective clothing and gloves. Suitable protective footwear. safety glasses with side-shields EXPOSURE LIMITS/GUIDELINES No exposure limit value known. PARTICULATES NOT OTHERWISE REGULATED (PNOR) PARTICULATES NOT OTHERWISE CLASSIFIED (PNOC) RESULT N/A N/A OSHA 8 HR mg/m 3 ACGIH TLV 8 HR mg/m 3 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES COLOR yellow to brown MOLECULAR WEIGHT Not available. ODOR Odorless. ODOR THERSHOLD Not available. ph VALUE 1 [Conc. (% w/w): VAPOR PRESSURE Not available. 10%] MELTING POINT Not available. VAPOR DENSITY Not available. FREEZING POINT Not available. RELATIVE DENSITY 760 kg/m³ INITIAL BOILING POINT Not available. SOLUBILITY Insoluble in cold water FLASHPOINT Not available. PARTITION COEFFICEINT Not available. EVAPORATION RATE Not available. AUTO IGNITION TEMP. >250 C FLAMMABILITY Not available. DECOMP. TEMP. Not Available UEL Not available. VISCOSITY Not Available LEL Not available. SECTION 10: STABILITY AND REACTIVITY REACTIVIVITY No specific test data related to reactivity CHEMICAL STABILITY Available for this product or its ingredients. POSSIBILITY OF HAZARDOUS The product is stable. Under normal conditions of storage REACTIONS and use, hazardous reactions will not occur. CONDITIONS TO AVOID HAZAROUS DECOMPOSITION PRODUCTS Strong oxidants, e.g. nitric acid, can cause violent reactions if they come into contact with ion exchange resins. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Resin C-211 H family Date 5/11/15 Rev: 0 Pages 4 of 6

5 SECTION 11: TOXICOLOGICAL INFORMATION INHALATION ACUTE CHRONIC SKIN ACUTE CHRONIC EYE ACUTE Corrosive with symptoms of reddening, tearing, swelling, burning and possible permanent damage. INGESTION ACUTE CHRONIC LD50 LC50 ACUTE TOXICITY ESTIMATES CARCINOGENICITY/MUTAGENICITY REPRODUCTIVE EFFECTS NEUROTOXICITY OTHER EFFECTS TARGET ORGANS >5000 mg/kg Oral (rat) Not applicable. Not available. SECTION 12: ECOLOGICAL INFORMATION The material in its original state, is not harmful to the environment. SECTION 13: DISPOSAL CONSIDERATIONS SPILL/LEAK Isolate spill area to prevent falls as material can be a slipping hazard. Avoid PROCEDURES contact with eyes and skin. Material is heavier than water and has limited water solubility. It will collect on the lowest surface. CLEANUP REGULATORY REQUIREMENTS DISPOSAL Clean up floor area. Sweep up. Avoid generation of dust. If discarded in its purchased form, this product would not be a hazardous waste either by listing or by characteristic. However, under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product or derived from the product should be classified as a hazardous waste. (40 CFR ) The generation of waste should be avoided or minimized wherever possible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal should be in accordance with existing federal state, provincial and or local environmental controls laws. SECTION 14: TRANSPORT INFORMATION LAND DOT UN/NA IDENTIFICATION NUMBER: UN-PROPER SHIPPING NAME: TRANSPORT HAZARD CLASS: PACKING GROUP: MARINE POLLUTANT: HAZARD CLASS: Resin C-211 H family Date 5/11/15 Rev: 0 Pages 5 of 6

6 WATER IMO/IMDG UN/NA IDENTIFICATION NUMBER: UN-PROPER SHIPPING NAME: TRANSPORT HAZARD CLASS: PACKING GROUP: MARINE POLLUTANT: SAFETY DATA SHEET AIR ICAO/IATA For product quantities less than 0.5 Kg UN/NA IDENTIFICATION NUMBER: UN-PROPER SHIPPING NAME: TRANSPORT HAZARD CLASS: PACKING GROUP: MARINE POLLUTANT: SECTION 15: REGULATORY INFORMATION OSHA OSHA CAA CERCLA SARA SARA HAZARD Immediate (acute) health hazard CATEGORIES 311/312 TSCA SECTION 16: OTHER INFORMATION DISCLAIMER: The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of these data or the results to be obtained from the user thereof. It is the buyer s responsibility to ensure that its activities comply with federal, state, provincial and local laws. REVISION INDICATOR: Revision 0: (This SDS replaces the former MSDS for this product pursuant to OSHA (g) Appendix D. The MSDS for this product should be considered obsolete). Resin C-211 H family Date 5/11/15 Rev: 0 Pages 6 of 6