Ion Exchange resin, Strong acid cation

Transcription

1 SECTION 1: PRODUCT AND COMPANY INFORMATION PRODUCT TYPE: Ion Exchange resin, Strong acid cation PRODUCT NAME: C-211 family, including C-211, C-211 XRR, C-211 UPS, C-211 C, C-211 PSMB, and C-211PSMBC COMPANY ID: Evoqua Water Technologies LLC 181 Thorn Hill Drive, Warrendale, PA TELEPHONE NUMBER: INFORMATION: CORPORATE MEDICAL EMERGENCY: CHEMTREC TRANSPORTATION EMERGENCY: CHEMTREC DATE PREPARED: May 8, 2015 REVISION: 0 SECTION 2: HAZARD(S) IDENTIFICATION HMIS RATINGS NFPA RATINGS GUIDE HEALTH 1 4 EXTREME/SEVERE 1 3 HIGH/SERIOUS FLAMMABILITY 1 2 MODERATE SLIGHT PHYSICAL HAZARD 0 0 MINIMUM W WATER REACTIVE OX - OXIDIZER PERSONAL PROTECTION E PICTOGRAM SIGNAL WORD HAZARD STATEMENT Warning Causes serious eye irritation. PRECAUTIONARY STATEMENT(S) PREVENTION Wear eye protection/ face protection. RESPONSE STORAGE IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Not applicable. OTHER HAZARDS SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS PERCENT BY WEIGHT COMMON NAME (Ingredient / Component) 35-65% Sulfonated polymer of styrene, ethylstyrene and divinylbenzene in CAS NO. IMPURITIES

2 the sodium form 35-65% Water SECTION 4: FIRST-AID MEASURES NECESSARY FIRST AID INSTRUCTIONS INHALATION FIRST AID Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur. SKIN CONTACT FIRST AID EYE CONTACT FIRST AID INGESTION FIRST AID: Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur. DESCRIPTION OF MOST IMPORTANT SYMPTOMS No specific data RECOMMENDATIONS FOR IMMEDIATE MEDICAL CARE No known significant effects or critical hazards SECTION 5: FIRE-FIGHTING MEASURES SUITABLE EXTINGUISHING MEDIA Water spray (fog), foam or dry chemical. UNSUITABLE EXTINGUISHING MEDIA SPECIFIC HAZARDS PERSONAL PROTECTIVE EQUIPMENT None known. No specific fire or explosion hazard. Decomposition products may include the following: carbon dioxide, carbon monoxide, metal oxide/oxides Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. SECTION 6: ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES PERSONAL PRECAUTIONS No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. Hazard of slipping on spilled product. ENVIRONMENTAL PRECAUTIONS Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Resin C-211 Family Date 5/8/15 Rev: 0 Pages 2 of 6

3 CONTAINMENT AND CLEAN-UP OTHER INFORMATION Move containers from spill area. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Prevent entry into sewers, water courses, basements or confined areas. SECTION 7: HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING Remove contaminated clothing and protective equipment before entering eating areas. Workers should wash hands and face before eating, drinking and smoking. Put on appropriate personal protection equipment. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. CONDITIONS FOR SAFE STORAGE Store between the following temperatures: -20 to 40 C (-4 to 104 F). Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Empty containers or liners may retain some product residues. It is recommended to store ion exchange resins at temperatures above the freezing point of water. If the resin should become frozen, the resin should not be mechanically handled and should be left to thaw out gradually at ambient temperature. It must be completely thawed before handling or use. No attempt should be made to accelerate the thawing process. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS Good general ventilation should be sufficient to control worker exposure to airborne contaminants. RESPIRATORY PROTECTION SKIN PROTECTION EYE/FACE PROTECTION EXPOSURE LIMITS/GUIDELINES Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Wear suitable protective clothing and gloves. Suitable protective footwear. If contact with product is possible, wear safety glasses with side shields. No exposure limit value known. PARTICULATES NOT OTHERWISE REGULATED (PNOR) PARTICULATES NOT OTHERWISE CLASSIFIED (PNOC) RESULT N/A N/A OSHA 8 HR mg/m 3 ACGIH TLV 8 HR mg/m 3 Resin C-211 Family Date 5/8/15 Rev: 0 Pages 3 of 6

4 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES COLOR Brown MOLECULAR WEIGHT Not available. ODOR Translucent ODOR THERSHOLD Odorless ph VALUE Not Available VAPOR PRESSURE Not available. MELTING POINT >204 C (1013 hpa) VAPOR DENSITY Not available. FREEZING POINT Not available. RELATIVE DENSITY 600 to 700 kg/m³ INITIAL BOILING POINT Not available. SOLUBILITY Insoluble in the following materials: cold water FLASHPOINT Not available. PARTITION COEFFICEINT Not available. EVAPORATION RATE Not available. AUTO IGNITION TEMP. >500 C (>932 F) FLAMMABILITY Not available. DECOMP. TEMP. Not available. UEL Not available. VISCOSITY Not available. LEL Not available. SECTION 10: STABILITY AND REACTIVITY REACTIVIVITY No specific test data related to reactivity available for this product or its ingredients. CHEMICAL STABILITY The product is stable. POSSIBILITY OF HAZARDOUS Under normal conditions of storage and use, hazardous REACTIONS reactions will not occur. CONDITIONS TO AVOID HAZAROUS DECOMPOSITION PRODUCTS Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: TOXICOLOGICAL INFORMATION INHALATION ACUTE CHRONIC SKIN ACUTE CHRONIC EYE ACUTE INGESTION ACUTE CHRONIC LD50 LC50 ACUTE TOXICITY ESTIMATE CARCINOGENICITY/MUTAGENICITY REPRODUCTIVE EFFECTS NEUROTOXICITY OTHER EFFECTS TARGET ORGANS >5000 mg/kg Oral (rat) Not applicable. Not available. SECTION 12: ECOLOGICAL INFORMATION The material, in its original state, is not harmful to the environment SECTION 13: DISPOSAL CONSIDERATIONS Resin C-211 Family Date 5/8/15 Rev: 0 Pages 4 of 6

5 SPILL/LEAK PROCEDURES CLEANUP REGULATORY REQUIREMENTS DISPOSAL Isolate spill area to prevent falls as material can be a slipping hazard. Avoid contact with eyes and skin. Material is heavier than water and has limited water solubility. It will collect on the lowest surface. Clean up floor area. Sweep up. Avoid generation of dust. If discarded in its purchased form, this product would not be a hazardous waste either by listing or by characteristic. However, under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product or derived from the product should be classified as a hazardous waste. (40 CFR ) The generation of waste should be avoided or minimized wherever possible. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal should be in accordance with existing federal state, provincial and or local environmental controls laws. SECTION 14: TRANSPORT INFORMATION LAND DOT UN/NA IDENTIFICATION NUMBER: UN-PROPER SHIPPING NAME: TRANSPORT HAZARD CLASS: PACKING GROUP: MARINE POLLUTANT: HAZARD CLASS: WATER IMO/IMDG UN/NA IDENTIFICATION NUMBER: UN-PROPER SHIPPING NAME: TRANSPORT HAZARD CLASS: PACKING GROUP: MARINE POLLUTANT: AIR ICAO/IATA For product quantities less than 0.5 Kg UN/NA IDENTIFICATION NUMBER: UN-PROPER SHIPPING NAME: TRANSPORT HAZARD CLASS: PACKING GROUP: MARINE POLLUTANT: SECTION 15: REGULATORY INFORMATION OSHA OSHA CAA CERCLA SARA SARA HAZARD Not applicable CATEGORIES 311/312 TSCA Resin C-211 Family Date 5/8/15 Rev: 0 Pages 5 of 6

6 SECTION 16: OTHER INFORMATION DISCLAIMER: The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of these data or the results to be obtained from the user thereof. It is the buyer s responsibility to ensure that its activities comply with federal, state, provincial and local laws. REVISION INDICATOR: Revision 0: (This SDS replaces the former MSDS for this product pursuant to OSHA (g) Appendix D. The MSDS for this product should be considered obsolete). Resin C-211 Family Date 5/8/15 Rev: 0 Pages 6 of 6