1. Identification of the substance / preparation and of the company / undertaking

Transcription

1 Jarocol PP 1. Identification of the substance / preparation and of the company / undertaking Identification of the product : Solid. Ref. n : Supplier : KO B.V. rnhemseweg 87, 3832GK Leusden, The Netherlands P.O. Box 205, 3830E, Leusden, The Netherlands Phone: (+31) (0) Fax: (+31) (0) h.vogelezang@aako.nl Use : Hair dye. Emergency phone number : See supplier. ( Telephone number is accessible only during business hours. ) or Call local Poison Control Centre for assistance BE : NL : This service is only available to health professionals. DE : Hazards identification This product is considered to be hazardous. Classification : Classification of the substance according to Directive 67/548/EEC. Indication of danger: Harmful, Dangerous for the environment. Xn; R20/22 N; R50/53 Xn; R68 Classification of the substance according to Regulation (EC) No. 1272/2008. Hazard categories: cute Tox. Oral 4; H302 cute Tox. Inh. 4; H332 Muta. 2; H341 quatic cute 1; H400 quatic Chronic 1; H410 Symptoms relating to use - Inhalation : Cyanosis may occur (lips and fingernails turn blue). May cause sensitization by inhalation. Exposure may produce cough, mucous, shortness of breath, chest tightness or other symptoms indicative of an allergic/sensitization reaction. - Skin contact : Exposure to this material can result in absorption through skin causing some health hazard. - Eye contact : May cause minor eye irritation. 3. Composition / Information on ingredients Substance name Value(s) CS nr / EC nr / EC annex CERTIFICTE minophenol (p-) : > 95 % / / X / Muta. Cat. 3; R68 Xn; R20/22 N; R cute Tox. 4 (inhal) cute Tox. 4 (oral) Muta. 2 quatic cute 1 quatic Chronic 1 See heading 16, where the full text of each relevant R phrase shall be listed. 4. First id measures First aid - Inhalation : Remove victim to fresh air. If not breathing, give artificial respiration. Seek medical advice. Revision nr : 3 Date : 28/7/2010 Supersedes : 26/1/2006 Page : 1

2 Jarocol PP 4. First id measures (continued) - Skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Seek medical advice. - Eye contact : Continue to rinse eye with clean water for 15 minutes, retracting eyelids often. Seek medical attention immediately. - Ingestion : DO NOT INDUCE VOMITING. Rinse mouth with water. Seek medical attention immediately. Note to physician : Give supportive therapy. Treat symptomatically. 5. Fire-Fighting measures Extinguishing media - Suitable : dry chemical, foam, water fog, carbon dioxide - Not to be used : Do not use a heavy water stream. Special exposure hazards : Thermal decomposition generates: carbon oxides, nitrogen oxides Special procedures : Use self-contained breathing apparatus when in close proximity to fire. void (reject) fire-fighting water to enter environment. Use water stream to cool containers. 6. ccidental release measures Personal precautions Environmental precautions fter spillage and/or leakage : void contact with skin and eyes. void ingestion and inhalation. Remove ignition sources. Wear recommended personal protective equipment. See Heading 8. : Prevent entry to sewers and public waters. : Take up large spills with pump or vacuum and finish with dry chemical absorbent. Vacuum with an equipment that avoids ignition risk. Collect spills and put it into appropriated container. 7. Handling and storage General Handling Storage : Dust may form explosive mixture in air. : void contact with skin and eyes. Do not breathe dust. Good ventilation of the workplace required. : Keep container closed when not in use. Store in dry, well-ventilated area. 8. Exposure controls and personal protection Personal protection - Respiratory protection : Where excessive dust may result, wear approved mask. - Hand protection : Wear suitable gloves resistant to chemical penetration. Material : Nitrile gloves. Thickness of the material : 0.4 mm Breakthrough time : 480 min - Skin protection : Wear suitable protective clothing ( long sleeves ) and chemical resistant boots - Eye protection : Chemical goggles or safety glasses. Industrial hygiene Occupational Exposure Limits : Local exhaust is recommended where dust may occur. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. Keep away from food, drink and animal feedingstuffs. : Not established. Revision nr : 3 Date : 28/7/2010 Supersedes : 26/1/2006 Page : 2

3 Jarocol PP 9. Physical and chemical properties Physical state : powder Colour : Whitish. - Brown. Odour : Odourless. ph value : 8.45 (10 g/l ) Melting point [ C] : Solubility in water : 6 g/l (25 C ) 10. Stability and reactivity Stability Hazardous decomposition products Hazardous Polymerization Materials to avoid Conditions to avoid : Stable under recommended storage and handling conditions. : Thermal decomposition generates: carbon oxides, nitrogen oxides : Will not occur. : Oxidizing agents, Strong acids. : Overheating. 11. Toxicological information cute toxicity - Oral : LD50 ( rat ) : 370 mg/kg Dermal irritation (rabbit) : Slight skin irritant Eyes irritation (rabbit) : Slight eye irritant. Sensitization : May cause an allergic skin reaction. Mutagenicity : Category: Ecological information Ecotoxicity : Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 13. Disposal considerations Disposal EWC-Nr. (European waste catalogus): : Dispose in a safe manner in accordance with local/national regulations. : The mentioned EWC codes are recommendations on the basis of the suspected use of this product. Under certain circumstances also other EWC codes can be granted on the basis of the specific use and the facilities for waste treatment at the user other organic solvents, washing liquids and mother liquors 14. Transport information Hazard Label(s) LÉ : 6.1 Proper shipping name UN Number : 2512 H.I. nr : : 60 : UN2512 MINOPHENOLS (O-, M-, P-), 6.1, III, (E) Land transport DR/VLG : Class : 6.1 Packing group : III Limited Quantities : LQ 9 Remarks: Combination packaging: Maximum net quantity per inner packaging: 6 kg; per package: 30 kg. Revision nr : 3 Date : 28/7/2010 Supersedes : 26/1/2006 Page : 3

4 Jarocol PP 14. Transport information (continued) Sea transport IMO - Proper shipping name : UN2512 MINOPHENOLS (O-, M-, P-), 6.1, III, (E) IMO-IMDG code : Class : 6.1 Packing group : III EmS-Nr : F-, S- IMDG-Marine pollution : Yes. 15. Regulatory information European Communities EC Labelling Symbol(s) R Phrase(s) S Phrase(s) êx ên : Harmful, Dangerous for the environment. : R 20/22 : Harmful by inhalation and if swallowed. R 50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R 68 : Possible risk of irreversible effects. : S 2 : Keep out of the reach of children. S 28 : fter contact with skin, wash immediately with plenty of S 36/37 : Wear suitable protective clothing and gloves. S 60 : This material and its container must be disposed of as hazardous waste. S 61 : void release to the environment. Refer to special instructions/safety data sheets. Globally Harmonized System of Classification and Labelling of Chemicals (GHS) Hazard Class and Category Code Health hazards : cute toxicity, Oral - Category 4 cute toxicity, Inhalation - Category 4 Specific Target Organ Toxicity - Single exposure - Category 2 Environmental hazards : Hazardous to the aquatic environment - cute hazard - Category 1 Hazardous to the aquatic environment - Chronic hazard - Category 1 Labelling Hazard pictograms Signal words Hazard statements M MÄ MÅ : Warning : Harmful if swallowed. Harmful if inhaled. May cause damage to organs. Very toxic to aquatic life with long lasting effects. Precautionary statements - Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. void breathing dust, fume, gas, mist, vapours, spray. Use personal protective equipment as required. - Response : IF exposed or concerned : Get medical advice. - Storage : Store locked up. Revision nr : 3 Date : 28/7/2010 Supersedes : 26/1/2006 Page : 4

5 Jarocol PP 16. Other information Full text R phrases under heading 3 : : R 20/22 : Harmful by inhalation and if swallowed. R 50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R 68 : Possible risk of irreversible effects. Literature : European greement concerning the International Carriage of Dangerous Goods by Road (DR) International Maritime Dangerous Goods; 2006 edition; IMO Further information : Changes from previous version - See : Prepared by : HPV h.vogelezang@aako.nl The content and format of the MSDS are in accordance with Regulation (EC) No 1907/2006 and subsequent amendments. DISCLIMER OF LIBILITY The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The above information relates only to the specific material(s) designated herein and may not be valid for such material(s) used in combination with any other materials or in any process or if the material is altered or processed, unless specified in the text. End of document Revision nr : 3 Date : 28/7/2010 Supersedes : 26/1/2006 Page : 5