Material Safety Data Sheet

Transcription

1 Page: 1 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Company Name Colgate-Palmolive Pty Ltd (ABN ) Address Australia: Level 14, 34 George Street, Sydney NSW 2000 Australia Emergency Tel. AUS , NZ: Telephone/Fax Number Tel: AUS (02) NZ: Fax: AUS (02) , NZ: Recommended Use Hand dishwashing liquid. Other Names Name Other 2. HAZARDS IDENTIFICATION Hazard Classification Safety Phrase(s) PALMOLIVE ULTRA GENTLE CARE DRY SKIN PALMOLIVE ULTRA GENTLE CARE VITAMIN E PALMOLIVE ULTRA POMEGRANATE New Zealand Address: Level 4, 4 Knights Road, Lower Hutt. Product Code NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. Hazard classification according to the criteria NOHSC. Dangerous goods classification according to the Australia Dangerous Goods Code. S2 Avoid contact with eyes. 3. COMPOSITION/INFORMATION ON INGREDIENTS on A mixture water and additives including those listed below. Composition Ingredients Name CAS Proportion Hazard Symbol Risk Phrase Sodium laureth <30 % sulfate Sodium xylene < % sulphonate Sodium chloride < % Myristamidopropyl < % amine oxide Lauramidopropyldi < % methylamine oxide Perfume Mixture <1 % Free Oil <1 % (unreacted) Tetrasodium EDTA <1 % Xi R38, R41 Formaldehdye <0.01 % T, C R23/24/2, R34, R40(3), R43 Other ingredients To 100% determined not to be hazardous 4. FIRST AID MEASURES Inhalation If breathing is affected, remove source contamination or affected person to fresh air. If irritation persists, seek medical attention. Ingestion Do NOT induce vomiting. Wash out mouth with water. If symptoms develop or persist, seek medical attention. Skin Remove all clothing from affected area. Wash skin with running water and mild soap. Wash removed clothing before reuse or discard. If irritation develops, seek medical attention. Eye If in eyes, hold eyelids apart and flush the eyes continuously with running

2 Page: 2 First Aid Facilities Advice to Doctor Other water. Continue flushing for several minutes until all contaminants are washed f completely. If irritation develops seek medical attention. Eye wash and normal washroom facilities. Treat symptomatically. For advice in an emergency, contact a Poisons Centre (Phone Australia ; New Zealand 0800 POISON / ) or a doctor at once.. FIRE FIGHTING MEASURES Suitable Use extinguishing media suitable for surrounding environment. Extinguishing Media Hazards from Under fire conditions this product may emit toxic and/or irritating fumes and Combustion gases including carbon monoxide, carbon dioxide, oxides sulphur and oxides Products nitrogen. Specific Hazards Non-flammable. However under fire conditions, once the aqueous component has been driven f the dried residue may burn. Fire-exposed containers may Precautions in connection with Fire rupture/explode. Fire-fighters should wear full protective clothing and self contained breathing apparatus (SCBA) operated in positive pressure mode. Water spray may be used to keep fire exposed containers cool. 6. ACCIDENTAL RELEASE MEASURES Emergency Slippery when spilt. Avoid accidents, clean up immediately. Procedures Small spill: Mop up and wash residue to drain with copious amounts water. Large spill: Contain and place absorbent material onto spillage. Collect and place into a suitable labelled container. Clean area with water, collect residue and place into the same container. Dispose waste according to the applicable local and national regulations. If contamination sewers or waterways occurs inform the local water and waste management authorities in accordance with local regulations. 7. HANDLING AND STORAGE Precautions for Safe Handling Conditions for Safe Storage Corrosiveness Avoid eye contact. Prevent the build-up vapours or mist in the working atmosphere. Ensure ventilation is adequate. Keep containers closed when not in use. Practice good personal hygiene, that is, always wash hands after handling, and before eating, drinking, smoking or using the toilet facilities. Store in a cool, dry place, out direct sunlight. Avoid contact with incompatible materials such as strong oxidising agents. Protect from frost. Not corrosive 8. EXPOSURE CONTROLS/PERSONAL PROTECTION National Exposure Standards No exposure standards have been established for the mixture by the National Occupational Health & Safety Commission (NOHSC), Australia. The available exposure limits for the ingredients are listed below: Australian National Occupational Health And Safety Commission (NOHSC) Exposure Standards: Substance TWA STEL NOTES ppm mg/m³ ppm mg/m³ Formaldehyde Sen National Industrial Chemicals Notification and Assessment Scheme (NICNAS), Australia recommends that NOHSC lower the current exposure standard for formaldehyde to the following: Substance TWA STEL NOTICES ppm mg/m³ ppm mg/m³ Formaldehyde Sen TWA (Time Weighted Average): The average airborne concentration a particular substance when calculated over a normal eight-hour working day, for a five-day week.

3 Page: 3 Biological Limit Values Engineering Controls Respiratory Protection Eye Protection Hand Protection Footwear Body Protection STEL (Short Term Exposure Limit): The average airborne concentration over a 1 minute period which should not be exceeded at any time during a normal eight-hour workday. 'Sen' Notice: The substance may cause sensitisation by skin contact or by inhalation. No biological limit allocated. No special engineering controls required. However, under industrial applications, provide sufficient ventilation to keep airborne levels below the exposure limits. Where vapours or mists are generated and exposure standards are exceeded, the use respiratory protection, or a local exhaust ventilation system is recommended. Not required under normal conditions use. However for industrial applications, if engineering controls are not effective in keeping airborne concentrations below exposure limit, then an approved respirator with a replaceable vapour/mist filter should be used. Reference should be made to Australian/New Zealand Standard AS/NZS 171, Selection, Use and Maintenance Respiratory Protective Devices; and AS/NZS 1716, Respiratory Protective Devices, in order to make any necessary changes for individual circumstances. Not required under normal conditions use. However, avoid eye contact. Industrial Applications: The use safety glasses as appropriate when handling large quantities. Refer to Australian/New Zealand Standard AS/NZS Eye Protectors for Industrial Applications. Wear gloves impervious material, e.g. PVC, nitrile or laminated film. Reference should be made to Australian/New Zealand Standard AS/NZS : Occupational protective gloves - Selection, use and maintenance. Not required under normal conditions use. Industrial Applications: Safety boots with non-slip soles as required. Refer to Australian Standard AS Safety footwear. Not required under normal conditions use. Industrial Applications: Suitable protective work wear, e.g. cotton overalls buttoned at neck and wrist is recommended. Chemical resistant apron is recommended where large quantities are handled. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Milky pink, clear purple or clear red liquid. Odour Melting Point Boiling Point Solubility in Water Soluble Specific Gravity to 1.00 ph Value 7.0 to 7. Vapour Pressure Vapour Density (Air=1) Viscosity 30 to 60 cps at 2 C Flash Point Not applicable Flammability Non-flammable, however if involved in a fire may release toxic gases. Auto-Ignition Temperature Flammable Limits - Not applicable Lower Flammable Limits - Not applicable Upper 10. STABILITY AND REACTIVITY Chemical Stability Stable under normal conditions storage, handling and use.

4 Page: 4 Incompatible Materials Hazardous Decomposition Products Hazardous Polymerization Strong oxidising agents. Thermal decomposition may result in the release toxic and/or irritating fumes and gases including oxides carbon, nitrogen and sulphur. Will not occur. 11. TOXICOLOGICAL INFORMATION Toxicology Inhalation Ingestion Skin Eye Chronic Effects No toxicity data is available for this specific product, however the data available for the ingredients are as follows: Formaldehyde: LD0 (Oral, Rat): 00 mg/kg LC0 (Inhalation, Rat): 20 ppm/4h Inhalation mist may result in respiratory irritation. Ingestion this product may irritate the gastric tract, causing possible nausea and vomiting. May cause irritation to individuals with sensitive skin. May cause irritation in contact with the eyes, including redness, stinging and tearing. 12. ECOLOGICAL INFORMATION Ecotoxicity Persistence / Degradability Mobility Environ. Protection Do not discharge product into waterways. 13. DISPOSAL CONSIDERATIONS Disposal Considerations 14. TRANSPORT INFORMATION Transport The disposal the spilled or waste material must be done in accordance with applicable local and national regulations. Australia Not classified as Dangerous Goods according to the Australian Code for the Transport Dangerous Goods by Road and Rail (ADG Code). Marine Transport (IMO/IMDG): Not classified as Dangerous Goods by the criteria the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea. Air Transport (ICAO/IATA): Not classified as Dangerous Goods by the criteria the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air. 1. REGULATORY INFORMATION Regulatory Poisons Schedule Australia: Not classified as Hazardous according to criteria National Occupational Health & Safety Commission (NOHSC), Australia. Not classified as a Scheduled Poison according to the Standard for the Uniform Scheduling Medicines and Poisons (SUSMP). Not Scheduled 16. OTHER INFORMATION Date preparation MSDS Created: December 2011 or last revision MSDS

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