Safety Data Sheet. Classified as hazardous

Transcription

1 Page: 1 1. Identification GHS Product Identifier Product Code Company Name Address Telephone/Fax Number Emergency phone number Recommended use the chemical and restrictions on use Other COLGATE OPTIC WHITE TOOTHPASTE B Colgate-Palmolive Pty Ltd (ABN ) Australia: Level 14, 34 George Street, Sydney NSW 2000 Australia Tel: AUS (02) NZ: Fax: AUS (02) , NZ: AUS , NZ: Cleaning and whitening toothpaste. New Zealand Address: Level 4, 4 Knights Road, Lower Hutt. 2. Hazard Identification GHS classification the substance/mixture Signal Word (s) Hazard Statement (s) Pictogram (s) Classified as Hazardous according to the Globally Harmonised System Classification and labelling Chemicals (GHS) including Work, Health and Safety regulations, Australia. Not classified as Dangerous Goods according to the Australian Code for the Transport Dangerous Goods by Road and Rail. (7th edition) Skin Corrosion/Irritation: Category 2 Eye Damage/Irritation: Category 2A Warning H31 Causes skin irritation. H319 Causes serious eye irritation. Exclamation mark statement Prevention statement Response statement Disposal P101 If medical advice is needed, have product container or label at hand. P102 Keep out reach children. P103 Read label before use. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. EYES: P30+P31+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. SKIN: P302+P32 IF ON SKIN: Wash with plenty soap and water. P332+P313 If skin irritation occurs: Get medical advice/ attention. P362 Take f contaminated clothing and wash before re-use. P01 Dispose contents/container to an approved waste disposal plant. 3. Composition/information on ingredients Ingredients Name CAS Proportion Calcium Pyrophosphate Oxirane, methyl-, polymer with oxirane Propylene glycol Hydrogen peroxide % % % <3 %

2 Page: 2 Ingredients 4. First-aid measures Inhalation Ingestion Skin Eye contact First Aid Facilities Advice to Doctor Other. Fire-fighting measures Suitable extinguishing media Hazards from Combustion Products Specific hazards arising from the chemical Decomposition Temp. Precautions in connection with Fire Name CAS Proportion Orthophosphoric acid Ingredients determined not to be hazardous <1 % Balance If inhaled, remove affected person from contaminated area. Keep at rest until recovered. If symptoms persist seek medical attention. Do not induce vomiting. Wash out mouth thoroughly with water. Seek medical attention. Remove all contaminated clothing immediately. Wash affected area thoroughly with soap and water. Wash contaminated clothing before reuse or discard. Seek medical attention. If in eyes, hold eyelids apart and flush the eyes continuously with running water. Remove contact lenses. Continue flushing for several minutes until all contaminants are washed out completely. Seek medical attention. Eyewash and normal washroom facilities. Treat symptomatically. For advice in an emergency, contact a Poisons Centre (Phone Australia ; New Zealand 0800 POISON / ) or a doctor at once. Use extinguishing media suitable for surrounding environment. Under fire conditions this product may emit toxic and/or irritating fumes and gases including carbon monoxide and carbon dioxide. Non-flammable material. 6. Accidental release measures Emergency Procedures 7. Handling and storage Precautions for Safe Handling Conditions for safe storage, including any incompatabilities 8. Exposure controls/personal protection Occupational exposure limit values Fire fighters should wear Self-Contained Breathing Apparatus (SCBA) operated in positive pressure mode and full protective clothing to prevent exposure to vapours or fumes. Water spray may be used to cool down heat-exposed containers. Wear appropriate personal protective equipment and clothing to minimise exposure. Increase ventilation. If possible contain the spill. Place inert absorbent material onto spillage. Collect the material and place into a suitable labelled container. Do not dilute material but contain. Dispose waste according to the applicable local and national regulations. If contamination sewers or waterways occurs inform the local water and waste management authorities in accordance with local regulations. Not required under normal conditions use. For industrial applications: Use only in a well ventilated area. Keep containers sealed when not in use. Prevent the build up mists or vapours in the work atmosphere. Avoid inhalation vapours and mists, and skin or eye contact. Maintain high standards personal hygiene i.e. Washing hands prior to eating, drinking, smoking or using toilet facilities. Store in a cool, dry, well-ventilated area, out direct sunlight. Store in suitable, labelled containers. Keep containers closed when not in use. For industrial applications: Ensure that storage conditions comply with applicable local and national regulations. No exposure value assigned for this material by Safe Work, Australia. However, the available exposure limits for ingredients are listed below:

3 Page: 3 Biological Limit Values Appropriate engineering controls Respiratory Protection Eye Protection Hand Protection Body Protection 9. Physical and chemical properties Appearance Odour Decomposition Temperature Melting Point Boiling Point Solubility in Water Specific Gravity ph Vapour Pressure Vapour Density (Air=1) Evaporation Rate Odour Threshold Safe Work, Australia Exposure Standards: Substance TWA STEL NOTICES ppm mg/m³ ppm mg/m³ Hydrogen peroxide Orthoposphoric acid TWA (Time Weighted Average): The average airborne concentration a particular substance when calculated over a normal eight-hour working day, for a five-day week. STEL (Short Term Exposure Limit): The average airborne concentration over a 1 minute period which should not be exceeded at any time during a normal eight-hour workday. No biological limit allocated. Not required under normal conditions use, natural ventilation should be sufficient. For industrial applications: Provide sufficient ventilation to keep airborne levels below the exposure limits. Where vapours or mists are generated, particularly in enclosed areas, and natural ventilation is inadequate, a local exhaust ventilation system is required. Not required under normal conditions use. For industrial applications: If engineering controls are not effective in controlling airborne exposure then an approved respirator with a replaceable mist/dust filter should be used. Reference should be made to Australian/New Zealand Standards AS/NZS 171, Selection, Use and Maintenance Respiratory Protective Devices; and AS/NZS 1716, Respiratory Protective Devices, in order to make any necessary changes for individual circumstances. Not required under normal conditions use, avoid eye contact. For industrial applications: Safety glasses with side shields or chemical goggles should be worn. Final choice appropriate eye/face protection will vary according to individual circumstances. Eye protection devices should conform with Australian/New Zealand Standard AS/NZS Eye Protectors for Industrial Applications. Not required under normal conditions use. However, under industrial applications, the use PVC or nitrile rubber gloves recommended. Final choice appropriate gloves will vary according to individual circumstances i.e. methods handling or according to risk assessments undertaken. Reference should be made to AS/NZS : Occupational protective gloves - Selection, use and maintenance. Not required under normal conditions use. For industrial applications: Suitable protective work wear, e.g. cotton overalls buttoned at neck and wrist is recommended. Chemical resistant apron is recommended where large quantities are handled. White paste Mint odour Soluble 1.46 (2 C) 8.2

4 Page: 4 Viscosity Partition Coefficient: n-octanol/water Flash Point Flammability Auto-Ignition Temperature Flammable Limits - Lower Flammable Limits - Upper 10. Stability and reactivity Reactivity Chemical Stability Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Hazardous Polymerization 11. Toxicological Toxicology Ingestion Inhalation Skin Eye Respiratory sensitisation Skin Sensitisation Germ cell mutagenicity Carcinogenicity Reproductive Toxicity STOT-single exposure STOT-repeated exposure Aspiration Hazard 12. Ecological information Ecotoxicity Persistence and degradability Mobility Not flammable Reacts with incompatibles. Stable under normal conditions storage and handling. Extremes temperature and direct sunlight. Strong oxidizing agents. Thermal decomposition may result in the release toxic and/or irritating fumes and gases including carbon monoxide and carbon dioxide. Will not occur. No toxicology data available for this product. Ingestion this product may irritate the gastric tract causing nausea and vomiting. Inhalation product vapours may cause irritation the nose, throat and respiratory system. Causes skin irritation. Skin contact will cause redness, itching and swelling. Repeated exposure may cause skin dryness and cracking and may lead to dermatitis. Causes serious eye irritation. On eye contact this product will cause tearing, stinging, blurred vision, and redness. Not expected to be a respiratory sensitiser. Not expected to be a skin sensitiser. Not considered to be a mutagenic hazard. Not considered to be a carcinogenic hazard. Not considered to be toxic to reproduction. Not expected to cause toxicity to a specific target organ. Not expected to cause toxicity to a specific target organ through prolonged or repeated exposure. Not expected to be an aspiration hazard. No ecological data are available for this material.

5 Page: Bioaccumulative Potential Environmental Protection 13. Disposal considerations Disposal Considerations 14. Transport information Transport IMDG Marine pollutant 1. Regulatory information Regulatory Poisons Schedule 16. Other Date preparation or last revision SDS Contact Person/Point Prevent this material entering waterways, drains and sewers. The disposal the spilled or waste material must be done in accordance with applicable local and national regulations. Road and Rail Transport: Not classified as Dangerous Goods according to the Australian Code for the Transport Dangerous Goods by Road and Rail. (7th edition) Marine Transport (IMO/IMDG): Not classified as Dangerous Goods by the criteria the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea. Air Transport (ICAO/IATA): Not classified as Dangerous Goods by the criteria the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air. No Classified as Hazardous according to criteria National Occupational Health & Safety Commission (NOHSC), Australia. Not classified as a Scheduled Poison according to the Standard for the Uniform Scheduling Medicines and Poisons (SUSMP). Not Scheduled SDS Created: November Hr Emergency Response Australia New Zealand End Of MSDS... Copyright ACOHS Pty Ltd Copyright in the source code the HTML, PDF, XML, XFO and any other electronic files rendered by an Infosafe system for Infosafe MSDS displayed is the intellectual property Acohs Pty Ltd. Copyright in the layout, presentation and appearance each Infosafe MSDS displayed is the intellectual property Acohs Pty Ltd. The compilation MSDS's displayed is the intellectual property Acohs Pty Ltd. Copying any MSDS displayed is permitted for personal use only and otherwise is not permitted. In particular the MSDS's displayed cannot be copied for the purpose sale or licence or for inclusion as part a collection MSDS without the express written consent Acohs Pty Ltd.