Material Safety Data Sheet

Transcription

1 Page: 1 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Product Name Company Name Address Emergency Tel. Telephone/Fax Number Recommended Use 2. HAZARDS IDENTIFICATION Hazard Classification Risk Phrase(s) Safety Phrase(s) CLEANING AGENT LP 163/93 SURTECO AUSTRALIA PTY LTD 7-11 Penelope Crescent Arndell Park NSW 2148 Australia (02) (9-pm) Tel: (02) Fax: (02) Cleaning furniture/doors and carcases/boxes. DANGEROUS GOODS. NON-HAZARDOUS SUBSTANCE. Dangerous goods classification according to the Australian Dangerous Goods Code. Hazard classification according to the criteria NOHSC. R11 Highly flammable. S1 Keep away from heat. S21 When using do not smoke. S23 Do not breathe gas/fumes/vapour/spray 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients 4. FIRST AID MEASURES Inhalation Ingestion Skin Eye First Aid Facilities Advice to Doctor Other Name CAS Proportion Ethyl Alcohol Acetone Other ingredients determined not be hazardous. FIRE FIGHTING MEASURES Suitable Extinguishing Media Hazards from Combustion Products Specific Hazards Hazchem Code Precautions in connection with Fire >8 % <10 % Not required Balance If inhaled, remove affected person from contaminated area. Keep at rest until recovered. If symptoms persist seek medical attention. Do not induce vomiting. Wash out mouth thoroughly with water. If symptoms develop seek medical attention. Wash affected area thoroughly with soap and water. If symptoms develop seek medical attention. If in eyes, hold eyelids apart and flush the eyes continuously with running water. Continue flushing for several minutes until all contaminants are washed out completely. If symptoms develop and persist seek medical attention. Eye wash and normal washroom facilities. Treat symptomatically. For advice in an emergency, contact a Poisons Centre (Phone Australia ) or a doctor at once. Use carbon dioxide, dry chemical or foam. Alcohol resistant foam is preferred. If not available normal foam can be used. Under fire conditions this product may emit toxic and/or irritating fumes and gases including carbon monoxide and carbon dioxide. Highly flammable liquid and vapour. Vapour/air mixtures may ignite explosively. Flashback along the vapour trail may occur. Runf to sewer may create fire or explosion hazard. 3YE Fire fighters should wear full protective clothing and self-contained breathing apparatus (SCBA) operated in positive pressure mode. In case fire Print Date: 18/06/2012

2 Page: 2 the product may be violently or explosively reactive. Use water spray to disperse vapours. This product should be prevented from entering drains and watercourses. 6. ACCIDENTAL RELEASE MEASURES Emergency Procedures 7. HANDLING AND STORAGE Handling and Storage Conditions for Safe Storage Recommended Materials Wear appropriate personal protective equipment and clothing to prevent exposure. Extinguish or remove all sources ignition and stop leak if safe to do so. Increase ventilation. Evacuate all unprotected personnel. If possible contain the spill. Place inert absorbent, non-combustible material onto spillage. Use clean non-sparking tools to collect the material and place into suitable labelled containers for subsequent recycling or disposal. Dispose waste according to the applicable local and national regulations. If contamination sewers or waterways occurs inform the local water and waste management authorities in accordance with local regulations. Wear appropriate protective clothing and equipment to prevent inhalation, skin and eye exposure. Handle and use the material in a well-ventilated area, away from sparks, flames and other ignition sources. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Work from suitable, labelled, fire-resistant containers. Open containers carefully as they may be under pressure. Keep containers closed when not in use. Flamepro equipment is necessary in areas where the product is being used. Take precautionary measures against static discharges. Earth or bond all equipment. Do not empty into drains. Ensure a high level personal hygiene is maintained when using this product, that is, always wash hands before eating, drinking, smoking or using the toilet facilities. Store in a cool, dry, well-ventilated area away from sources ignition, oxidising agents, strong acids, foodstuffs, and clothing. Keep containers closed when not in use and securely sealed and protected against physical damage. Inspect regularly for deficiencies such as damage or leaks. Have appropriate fire extinguishers available in and near the storage area. Take precautions against static electricity discharges. Use proper grounding procedures. For information on the design the storeroom, reference should be made to Australian Standard AS The storage and handling flammable and combustible liquids. Reference should also be made to all applicable local and national regulations. Keep product in the original drums at all times. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION National Exposure Standards No exposure value assigned for this specific material by Safe Work, Australia. However, the available exposure limits for ingredients are listed below: Safe Work, Australia Exposure Standards: Substance TWA STEL NOTICES ppm mg/m³ ppm mg/m³ Ethyl Alcohol Acetone Biological Limit Values Engineering Controls TWA (Time Weighted Average): The average airborne concentration a particular substance when calculated over a normal eight-hour working day, for a five-day week. STEL (Short Term Exposure Limit): The average airborne concentration over a 1 minute period which should not be exceeded at any time during a normal eight-hour workday. Biological Exposure Indice (BEI) from American Conference Industrial Hygienists (ACGIH) for ingredients are as follows: Determinant Sampling Time Biological Exposure Indice (BEI) Acetone End shift 0mg/L Provide sufficient ventilation to keep airborne levels below the exposure limits. Where vapours or mists are generated, particularly in enclosed areas, and natural ventilation is inadequate, a flamepro exhaust ventilation system is required. Refer to AS The storage and handling flammable and combustible liquids and AS/NZS :2009 Explosive atmospheres - Print Date: 18/06/2012

3 Page: 3 Respiratory Protection Eye Protection Hand Protection Body Protection Classification areas - Explosive gas atmospheres, for further information concerning ventilation requirements. If engineering controls are not effective in controlling airborne exposure then an approved respirator with a replaceable organic vapour filter should be used. Reference should be made to Australian/New Zealand Standards AS/NZS 171, Selection, Use and Maintenance Respiratory Protective Devices; and AS/NZS 1716, Respiratory Protective Devices, in order to make any necessary changes for individual circumstances. Safety glasses with side shields or chemical goggles should be worn. Final choice appropriate eye/face protection will vary according to individual circumstances. Eye protection devices should conform with Australian/New Zealand Standard AS/NZS Eye Protectors for Industrial Applications. Wear gloves impervious material e.g. butyl or fluorine rubber. Final choice appropriate gloves will vary according to individual circumstances i.e. methods handling or according to risk assessments undertaken. Reference should be made to AS/NZS : Occupational protective gloves - Selection, use and maintenance. Suitable protective work wear, e.g. cotton overalls buttoned at neck and wrist is recommended. Chemical resistant apron is recommended where large quantities are handled. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Odour Melting Point Boiling Point Solubility in Water ph Value Vapour Pressure Vapour Density (Air=1) Viscosity Colour Density Flash Point Flammability Auto-Ignition Temperature Flammable Limits - Lower Flammable Limits - Upper Explosion Limit - Upper Explosion Limit - Lower Other Liquid Alcohol like Partly soluble 9 mbar (20 C) 1.19 mpas (20 C) Red g/cm³(20 C) <21 C (DIN 3213) Flammable liquid 42 C 1.0% 3.% Non selfignitable 10. STABILITY AND REACTIVITY Chemical Stability Conditions to Avoid Incompatible Materials Stable under normal conditions storage and handling. Heat, direct sunlight, open flames or other sources ignition. Strong oxidizing agents. Print Date: 18/06/2012

4 Page: 4 Hazardous Decomposition Products Hazardous Polymerization Thermal decomposition may result in the release toxic and/or irritating fumes and gases including carbon monoxide and carbon dioxide. Will not occur. 11. TOXICOLOGICAL INFORMATION Toxicology Inhalation Ingestion Skin Eye Chronic Effects 12. ECOLOGICAL INFORMATION Ecotoxicity Persistence / Degradability Mobility Bioaccumulative Potential Environ. Protection No toxicity data is available for this material. Inhalation product vapours may cause irritation the nose, throat and respiratory system. If vapours are formed inhalation may cause CNS depression with symptoms similar to those seen if product is swallowed. Ingestion this product may irritate the gastric tract causing nausea and vomiting. Ingestion may cause CNS depression with symptoms including drowsiness, dizziness, fatigue, confusion and possible unconsciousness. May be irritating to skin. The symptoms may include redness, itching and swelling. Repeated exposure may cause skin dryness and cracking. May be irritating to eyes. The symptoms may include redness, itching and tearing. Prolonged or repeated skin contact may cause defatting leading to dermatitis. No ecological data are available for this material. 13. DISPOSAL CONSIDERATIONS Waste Disposal 14. TRANSPORT INFORMATION Transport U.N. Number Proper Shipping Name DG Class Hazchem Code Do not discharge this material into waterways, drains and sewers. Dispose waste according to applicable local and national regulations. Labels should not be removed from containers until they have been cleaned. Do not cut, puncture or weld on or near containers. Empty containers may contain hazardous residues. Contaminated containers must not be treated as household waste. Containers should be cleaned by appropriate methods and then re-used or disposed by landfill or incineration as appropriate. Do not incinerate closed containers. Advise flammable nature. This material is a Class 3 - Flammable Liquid according to The Australian Code for the Transport Dangerous Goods by Road and Rail. (7th edition) Class 3 - Flammable Liquids are incompatible in a placard load with any the following: - Class 1, Explosives - Division 2.1, Flammable Gases, (Division 2.1 and Class 3 are incompatible in transport if both are in tanks or other receptacles with a capacity individually exceeding 00 L.) - Division 2.3, Toxic Gases - Division 4.2 Spontaneously Combustible Substances - Division.1 Oxidising Agents and Division.2, Organic Peroxides - Class 6 Toxic or Infectious Substances (where the flammable liquid is nitromethane) - Class 7 Radioactive Substances FLAMMABLE LIQUID, N.O.S. - (CONTAINS ETHANOL) 3 3YE Print Date: 18/06/2012

5 Page: Packing Group EPG Number IERG Number IMDG Marine Pollutant (MP) II 3A1 14 No 1. REGULATORY INFORMATION Regulatory Poisons Schedule Hazard Category 16. OTHER INFORMATION Date preparation or last revision MSDS Not classified as Hazardous according to criteria National Occupational Health & Safety Commission (NOHSC), Australia. Not classified as a Scheduled Poison according to the Standard for the Uniform Scheduling Medicines and Poisons (SUSMP). Not Scheduled Highly Flammable MSDS created: June End Of MSDS... Copyright ACOHS Pty Ltd Copyright in the source code the HTML, PDF, XML, XFO and any other electronic files rendered by an Infosafe system for Infosafe MSDS displayed is the intellectual property Acohs Pty Ltd. Copyright in the layout, presentation and appearance each Infosafe MSDS displayed is the intellectual property Acohs Pty Ltd. The compilation MSDS's displayed is the intellectual property Acohs Pty Ltd. Copying any MSDS displayed is permitted for personal use only and otherwise is not permitted. In particular the MSDS's displayed cannot be copied for the purpose sale or licence or for inclusion as part a collection MSDS without the express written consent Acohs Pty Ltd. Print Date: 18/06/2012