Safety Data Sheet. Classified as hazardous. Website: Emergency Telephone Number: Kidde Australia (03) ,
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1 Page: 1 1. Identification GHS Product Identifier Company Name Address Telephone/Fax Number Recommended use the chemical and restrictions on use Other 2. Hazard Identification GHS classification the substance/mixture Signal Word (s) Hazard Statement (s) Pictogram (s) CHUBB AFFF 6% KIDDE AUSTRALIA (ABN ) A UTC Fire & Security Company 314 Boundary Rd Dingley Victoria 3172 Australia Tel: Fire fighting foam concentrate. Website: Emergency Telephone Number: Kidde Australia (03) , Classified as Hazardous according to the Globally Harmonised System Classification and labelling Chemicals (GHS) including Work, Health and Safety regulations, Australia. Not classified as Dangerous Goods according to the Australian Code for the Transport Dangerous Goods by Road and Rail. (7th edition) Eye Damage/Irritation: Category 2A Warning H319 Causes serious eye irritation. AUH019 May form explosive peroxides. Exclamation mark Precautionary statement Prevention Precautionary statement Response P264 Wash skin thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P30+P31+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. 3. Composition/information on ingredients Ingredients 4. First-aid measures Inhalation Ingestion Skin Eye contact First Aid Facilities Name CAS Proportion Diethylene glycol monobutyl ether Ingredients determined not to be hazardous, including water <20 % Balance If inhaled, remove affected person from contaminated area. Keep at rest until recovered. If symptoms persist seek medical attention. Do not induce vomiting. Wash out mouth thoroughly with water. Seek medical attention. Wash affected area thoroughly with soap and water. Remove contaminated clothing and wash before reuse or discard. If symptoms develop seek medical attention. If in eyes, hold eyelids apart and flush the eyes continuously with running water. Remove contact lenses. Continue flushing for several minutes until all contaminants are washed out completely. Seek medical attention. Eyewash and normal washroom facilities.
2 Page: 2 Advice to Doctor Treat symptomatically.. Fire-fighting measures Suitable extinguishing media Hazards from Combustion Products Specific hazards arising from the chemical Decomposition Temp. Precautions in connection with Fire Product is an extinguishing media. Use appropriate fire extinguisher for surrounding environment. Under fire conditions this product may emit toxic and/or irritating fumes and gases including carbon monoxide and carbon dioxide. Combustible liquid. This product will readily burn under fire conditions. 6. Accidental release measures Emergency Procedures 7. Handling and storage Precautions for Safe Handling Conditions for safe storage, including any incompatabilities Other 8. Exposure controls/personal protection Occupational exposure limit values Biological Limit Values Appropriate engineering controls Respiratory Protection Fire fighters should wear Self-Contained Breathing Apparatus (SCBA) and full protective clothing to prevent exposure to vapours, fumes or products combustion. Water spray may be used to cool down heat-exposed containers. Wear appropriate personal protective equipment and clothing to prevent exposure. Extinguish or remove all sources ignition and stop leak if safe to do so. Increase ventilation. Evacuate all unprotected personnel. If possible contain the spill. Place inert absorbent, non-combustible material onto spillage. Use clean non-sparking tools to collect the material and place into suitable labelled containers for subsequent recycling or disposal. Dispose waste according to the applicable local and national regulations. If contamination sewers or waterways occurs inform the local water and waste management authorities in accordance with local regulations. Use only in a well ventilated area. Keep containers sealed when not in use. Prevent the build up mists or vapours in the work atmosphere. Avoid inhalation vapours and mists, and skin or eye contact. Do not use near ignition sources. Do not pressurise, cut, heat or weld containers as they may contain hazardous residues. Maintain high standards personal hygiene i.e. Washing hands prior to eating, drinking, smoking or using toilet facilities. Store in a cool, dry, well-ventilated area away from sources ignition, oxidising agents, strong acids, foodstuffs, and clothing. Keep containers closed when not in use and securely sealed and protected against physical damage. Inspect regularly for deficiencies such as damage or leaks. Have appropriate fire extinguishers available in and near the storage area. Take precautions against static electricity discharges. Use proper grounding procedures. For information on the design the storeroom, reference should be made to Australian Standard AS The storage and handling flammable and combustible liquids. Reference should also be made to all applicable local and national regulations. The substance accumulates peroxides which may become hazardous only if it evaporates or is distilled or otherwise treated to concentrate the peroxides. The substance may concentrate around the container opening for example. No exposure standards have been established for this material by Safe Work, Australia. However, over-exposure to some chemicals may result in enhancement pre-existing adverse medical conditions and/or allergic reactions and should be kept to the least possible levels. No biological limit allocated. Use with good general ventilation. If mists or vapours are produced, local exhaust ventilation should be used. If engineering controls are not effective in controlling airborne exposure then an approved respirator with a replaceable organic vapour filter may be necessary. Reference should be made to Australian Standards AS/NZS 171, Selection, Use and maintenance Respiratory Protective Devices; and AS/NZS 1716, Respiratory Protective Devices, in order to make any necessary changes
3 Page: 3 Eye Protection Hand Protection Body Protection 9. Physical and chemical properties Appearance Odour Decomposition Temperature Melting Point Boiling Point Solubility in Water Specific Gravity ph Vapour Pressure Vapour Density (Air=1) Evaporation Rate Odour Threshold Viscosity Partition Coefficient: n-octanol/water Flash Point Flammability Auto-Ignition Temperature Flammable Limits - Lower Flammable Limits - Upper Kinematic Viscosity Dynamic Viscosity for individual circumstances. Safety glasses with side shields or chemical goggles should be worn. Final choice appropriate eye/face protection will vary according to individual circumstances. Eye protection devices should conform with Australian/New Zealand Standard AS/NZS Eye Protectors for Industrial Applications. Wear gloves impervious material, such as PVC. Final choice appropriate gloves will vary according to individual circumstances i.e. methods handling or according to risk assessments undertaken. Reference should be made to AS/NZS : Occupational protective gloves - Selection, use and maintenance. Suitable workwear, e.g. cotton overalls buttoned at neck and wrist should be worn. Clear pale yellow liquid Organic odour -2 C 100 C Miscible >98 C 10. Stability and reactivity Reactivity Chemical Stability Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Not flammable Reacts with incompatible materials. Stable under normal conditions storage and handling. Heat, flames and other sources ignition. Strong oxidising agents. Thermal decomposition may result in the release toxic and/or irritating fumes, including oxides carbon.
4 Page: 4 Possibility hazardous reactions Hazardous Polymerization 11. Toxicological Toxicology Acute Toxicity - Oral Acute Toxicity - Dermal Ingestion Inhalation Skin Eye Respiratory sensitisation Skin Sensitisation Germ cell mutagenicity Carcinogenicity Reproductive Toxicity STOT-single exposure STOT-repeated exposure Aspiration Hazard 12. Ecological information Ecotoxicity Persistence and degradability Mobility Bioaccumulative Potential Environmental Protection 13. Disposal considerations Disposal Considerations 14. Transport information Transport Glycol ethers may form peroxides under certain conditions. In the presence strong bases or the salts strong bases, at elevated temperatures, the potential exists for runaway reactions. Will not occur. No toxicity data available for this material. The available acute toxicity data for the ingredients is given below: Diethylene glycol monobutyl ether: LD0(rat): 660 mg/kg Diethylene glycol monobutyl ether: LD0(rabbit): 4120 mg/kg Ingestion may cause irritation to the gastric tract, with stomach pain, nausea and vomiting. Inhalation product vapours may cause irritation the nose, throat and respiratory system. May be irritating to skin. The symptoms may include redness, itching and swelling. Causes serious eye irritation. On eye contact this product will cause tearing, stinging, blurred vision, and redness. Repeated or prolonged exposure to irritants may produce conjunctivitis. Not expected to be a respiratory sensitiser. Not expected to be a skin sensitiser. Not considered to be a mutegenic hazard. Not considered to be a carcinogenic hazard. Not considered to be toxic to reproduction. Not considered to cause toxicity to a specific target organ. Not considered to cause toxicity to a specific target organ through prolonged or repeated exposure. Not expected to be an aspiration hazard. No ecological data are available for this material. Prevent this material entering waterways, drains and sewers. Dispose waste according to applicable local and national regulations. Road and Rail Transport (ADG Code): Not classified as Dangerous Goods according to the Australian Code for the Transport Dangerous Goods by Road and Rail (ADG Code) (7th edition). Marine Transport (IMO/IMDG): Not classified as Dangerous Goods by the criteria the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea.
5 Page: IMDG Marine pollutant 1. Regulatory information Regulatory Poisons Schedule 16. Other Date preparation or last revision SDS Contact Person/Point Air Transport (ICAO/IATA): Not classified as Dangerous Goods by the criteria the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air. No Classified as Hazardous according to the Globally Harmonised System Classification and labelling Chemicals (GHS) including Work, Health and Safety regulations, Australia. Classified as a Scheduled Poison according to the Standard for the Uniform Scheduling Medicines and Poisons (SUSMP). S SDS Created: November 2012 COMPANY CONTACT AUSTRALIAN POISONS INFORMATION CENTRE 24 HOUR SERVICE: POLICE, FIRE BRIGADE OR AMBULANCE: 000 NEW ZEALAND POISONS INFORMATION CENTRE 24 HOUR SERVICE: NZ EMERGENCY SERVICES:111...End Of MSDS... Copyright ACOHS Pty Ltd Copyright in the source code the HTML, PDF, XML, XFO and any other electronic files rendered by an Infosafe system for Infosafe MSDS displayed is the intellectual property Acohs Pty Ltd. Copyright in the layout, presentation and appearance each Infosafe MSDS displayed is the intellectual property Acohs Pty Ltd. The compilation MSDS's displayed is the intellectual property Acohs Pty Ltd. Copying any MSDS displayed is permitted for personal use only and otherwise is not permitted. In particular the MSDS's displayed cannot be copied for the purpose sale or licence or for inclusion as part a collection MSDS without the express written consent Acohs Pty Ltd.
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