SAFETY DATA SHEET SANI PRODUCT AND COMPANY IDENTIFICATION 2. HAZARDS IDENTIFICATION
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1 Page: 1 Product Code: Product Name: Company Name: Emergency Contact: Intended Use: 1. PRODUCT AND COMPANY IDENTIFICATION 1500 KIRBY CHEMICAL & RESTAURANT SUPPLY 809 S. EASTMAN RD. LONGVIEW, TX CHEM-TEL, INC. SANITIZER Skin Corrosion/Irritation, Category 1B 2. HAZARDS IDENTIFICATION Phone Number: (903) (800) GHS Signal Word: GHS Hazard Phrases: GHS Precaution Phrases: GHS Response Phrases: GHS Storage and Disposal Phrases: Danger H314 - Causes severe skin burns and eye damage. H400 - Very toxic to aquatic life. P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P264 - Wash hands thoroughly after handling. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P273 - Avoid release to the environment. P IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P363 - Wash contaminated clothing before reuse. P IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P310 - Immediately call a POISON CENTER/doctor/... P321 - Specific treatment see... on this label. P391 - Collect spillage. P405 - Store locked up. P501 - Dispose of contents/container to... Hazard Rating System: HEALTH FLAMMABILITY PHYSICAL PPE E Potential Health Effects (Acute and Chronic): Inhalation: Skin Contact: Eye Contact: Ingestion: May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes skin irritation. Causes eye irritation. Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
2 Page: 2 3. COMPOSITION/INFORMATION ON INGREDIENTS CAS # Hazardous Components (Chemical Name) Concentration Sodium hypochlorite <15.0 % 4. FIRST AID MEASURES Emergency and First Aid Procedures: In Case of Inhalation: In Case of Skin Contact: In Case of Eye Contact: In Case of Ingestion: Note to Physician: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. Treat symptomatically and supportively. 5. FIRE FIGHTING MEASURES Flash Pt: Method Used: Estimate Explosive Limits: LEL: UEL: Autoignition Pt: Fire Fighting Instructions: Flammable Properties and Hazards: Suitable Extinguishing Media: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Substance is noncombustible. Oxidizer. Greatly increases the burning rate of combustible materials. 6. ACCIDENTAL RELEASE MEASURES Steps To Be Taken In Case Material Is Released Or Spilled: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. 7. HANDLING AND STORAGE Precautions To Be Taken in Handling: Precautions To Be Taken in Storing: Avoid breathing dust, mist, or vapor. Keep container tightly closed. Avoid contact with clothing and other combustible materials. Avoid ingestion and inhalation. Use with adequate ventilation. Use only in a chemical fume hood. Discard contaminated shoes. Store in a tightly closed container. Keep refrigerated. 8. EXPOSURE CONTROLS/PERSOL PROTECTION
3 Page: 3 CAS # Partial Chemical Name OSHA TWA ACGIH TWA Other Limits Sodium hypochlorite TLV: 1000 ppm Respiratory Equipment (Specify Type): Eye Protection: Protective Gloves: Other Protective Clothing: Engineering Controls (Ventilation etc.): Follow the OSHA respirator regulations found in 29 CFR or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR or European Standard EN166. Wear appropriate protective gloves to prevent skin exposure. Wear appropriate protective clothing to prevent skin exposure. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical States: [ ] Gas [ X ] Liquid [ ] Solid Appearance and Odor: Appearance: yellow. Liquid. Odor: chlorine-like. Melting Point: Boiling Point: Autoignition Pt: Flash Pt: Method Used: Estimate Explosive Limits: LEL: UEL: Specific Gravity (Water = 1): 1.15 Vapor Pressure (vs. Air or mm Hg): Vapor Density (vs. Air = 1): Evaporation Rate: Solubility in Water: Percent Volatile: ph: Stability: Conditions To Avoid - Instability: 10. STABILITY AND REACTIVITY Unstable [ ] Stable [ X ] Incompatible materials, Light. Incompatibility - Materials To methanol, Metals. Oxidizing agents, Reducing agents, Strong acids, acids (organic, e.g. Avoid: acetic acid, benzoic acid, formic acid, methanoic acid, oxalic acid). Hazardous Decomposition Or Hydrogen chloride, chlorine, sodium oxide. Byproducts: Possibility of Hazardous Reactions: Conditions To Avoid - Hazardous Reactions: Will occur [ ] Will not occur [ X ]
4 Page: TOXICOLOGICAL INFORMATION Toxicological Information: Symptoms related to Toxicological Characteristics: CAS# : Sodium hypochlorite: Other Studies:, TDLo, Oral, Rat, MG/KG, 9 W. Endocrine: Changes in spleen weight. Immunological Including Allergic: Decrease in cellular immune response. Biochemical: Metabolism (Intermediary): Lipids including transport. - Toxicology., Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick Ireland, Vol/p/yr: 44,257, 1987 Acute toxicity, LD50, Oral, Mouse, CVJS. Behavioral: Change in motor activity (specific assay). Gastrointestinal:Other changes. - Shokuhin Eiseigaku Zasshi. Food Hygiene Journal., Nippon Shokuhin Eisei Gakkai, c/o Shokuhin Eisei Senta, Jingumae, Shibuya-ku, Tokyo 150 Japan, Vol/p/yr: 27,553, 1986 Standard Draize Test, Eyes, Species: Rabbit, MG. Effects on Newborn: Stillbirth. Effects on Newborn: Live birth index (# fetuses per litter; measured after birth). Effects on Newborn: Weaning or lactation index (e.g., # alive at weaning per # alive at day {4)}. - Toxicology and Applied Pharmacology, Academic Press, Inc., 1 E. First St., Duluth, MN 55802, Vol/p/yr: 55,501, 1980 Ocular. Skin. Carcinogenicity/Other Information: CAS# : Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS # Hazardous Components (Chemical Name) NTP IARC ACGIH OSHA Sodium hypochlorite n.a. n.a. n.a. n.a. 12. ECOLOGICAL INFORMATION General Ecological Information: Toxic to aquatic life. 13. DISPOSAL CONSIDERATIONS Waste Disposal Method: Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: None listed.
5 Page: 5 LAND TRANSPORT (US DOT): DOT Proper Shipping Name: DOT Hazard Class: UN/ Number: 14. TRANSPORT INFORMATION HYPOCHLORITE SOLUTIONS. 8 CORROSIVE UN1791 Packing Group: III LAND TRANSPORT (Canadian TDG): TDG Shipping Name: This material meets the EPA 'Hazard Categories' defined for SARA Title III Sections 311/312 as indicated: HYPOCHLORITE SOLUTIONS. 15. REGULATORY INFORMATION [ ] Yes [X] No Acute (immediate) Health Hazard [ ] Yes [X] No Chronic (delayed) Health Hazard [ ] Yes [X] No Fire Hazard [ ] Yes [X] No Sudden Release of Pressure Hazard [ ] Yes [X] No Reactive Hazard CAS # Hazardous Components (Chemical Name) Other US EPA or State Lists Sodium hypochlorite TSCA: Inventory Revision Date: Additional Information About This Product: Company Policy or Disclaimer: 16. OTHER INFORMATION 10/31/2013 While the information is believed to be correct, Kirby Chemical Company shall in no event be responsible for any damages whatsoever, either directly or indirectly, resulting from any publication or use of or reliance upon data contained herein. No warranty, either expressed or implied, of merchantability, of fitness for a particular purpose, or of any other nature with respect to the product or to the data, is made herein. The information contained in this Material Safety Data Sheet is supplied pursuant to OSHA's Hazard Communication Standard, 29 CFR Standard must be consulted for specific requirements
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