Material Safety Data Sheet

Transcription

1 1. Chemical Product and Company Identification 1.1 Chemical Product Identification Product name BI-OFFICE White Board Cleaner 1.2. Relevant identified uses of the substance or mixture and uses advised against Uses: Product suitable for white board cleaning Uses advised against: Currently, there are no uses advised against 1.3. Details of the supplier of the safety data sheet Supplier: CTEQ - Centro Técnico de Estudos Químicos, SA Address: Rua da Nova Industria, Nº Santo Tirso cteq.qualidade@arbo.pt Phone: Fax: Distributed by: Bi-Silque, SA Address: P.O. Box 43, 3885 Esmoriz - Portugal Phone: CIAV: Hazards Identification 2.1 Classification of the substance or mixture Classified accordingly to EU 67/548/CE or 1999/45/CE norms 2.2. Label elements Danger symbols:. R-Phrases:. Pág.: 1 / 9

2 S-Phrases: S2 Keep out of the reach of children S46 If swallowed, seek medical advice immediately and show this container or label Contains among other ingredients: 3. Composition/information on ingredients Composition: Aqueous solution of anionic surfactants. Hazardous substances or exposure limits set by European legislation: Propan-2-ol < 2.5% CAS: ; EINECS no.: ; Index no.: ; REACH no.: Classification (67/548/CEE) Symbols and R-Phrases: F; Xi; R11; R36; R67 Classification (CE Regulation) nº: 1272/2008) Danger Classes / Danger Categories: Flam Liq.2; Eye Irrit. 2; STOT SE 3 Danger warnings: H225; H319; H336 Ethanol < 2.5% CAS: ; EINECS no.: ; Index no.: ; REACH no.: Classification (67/548/CEE) Symbols and R-Phrases: F; R11 Classification (CE Regulation) nº: 1272/2008) Danger Classes / Danger Categories: Flam Liq.2 Danger warnings: H225 Alcohols, C12-14, Ethoxylated, Sulfates, sodium salts < 0.1% CAS no.: ; EINECS No.: ; Index no.: ---; REACH No.: Classification (67/548/CEE) Symbols and R-Phrases: Xi; R38, R41 Classification (CE Regulation) nº: 1272/2008) Danger Classes / Danger Categories: Skin Irrit. 2; Eye Dam. 1 Danger warnings: H315; H318 Additional warnings: Danger indications texts may be consulted on chapter 16 th. Pág.: 2 / 9

3 4. First Aid Measures 4.1. First aid measures description: In case of contact with eyes: Gently flush eyes with plenty of water for at least 15 minutes, lifting both upper and lower eyelids. Apply physiological saline solution, if available. Seek for medical attention if symptoms persist. In case of ingestion: Do not induce vomiting. Rinse out mouth with water. In case of inhalation:. In case of contact with skin: Remove contaminated clothes. Wash with plenty of soap and water Most important symptoms and effects, both acute and delayed There are no known effects and / or specific symptoms Indication of any immediate medical attention and special treatment needed Treat accordingly to symptoms. No further information available. 5. Fire-fighting measures 5.1. Extinguishing Media In case of fire use: foam, dry chemical dust and CO2. Do not use water directly Special hazards arising from the substance or mixture As a combustion or thermal decomposing action s consequence it may appear reactive byproducts (CO 2, CO, NO x,...) that may become highly toxic and therefore present themselves as a high risk for health Advice for fire-fighters Depending on fire s dimension, it may be necessary to use special protective clothing and selfcontained breathing apparatus. 6. Accidental release measures 6.1. Personal Precautions Use suitable personal protection (see Section 8) Environmental Precautions Do not empty into waterways, drains and sewers. Pág.: 3 / 9

4 6.3. Methods and material for containment and cleaning up Ensure adequate ventilation. Remove all ignition sources. Control and recover the spilled liquid with an inert product and place it in containers for elimination according to local / national regulations (see section 13). 7. Handling and Storage 7.1. Precautions for safe handling Safe handling information: Handle accordingly to Health and Safety notions. Hygiene Measures: Remove contaminated clothes. Keep away from food and beverage. Do not smoke, eat or drink while handling the product Conditions for safe storage, including any incompatibilities Mandatory storage and container indications: Keep away from heat and ignition sources. Keep in a cool, dry and well ventilated place. Keep product in its original container Specific end use(s) Regarding this product indications and specifications, there are no special recommendations regarding this product s use. 8. Exposure controls/personal protection 8.1. Control parameters There s no experimental data regarding this mixture 8.2. Exposure controls Individual protection: Breathing protection: Advise: no need for special protection if the product is used correctly. Hand protection: Advise: no need for special protection if the product is used correctly. Eye protection: Advise: avoid contact with eyes Body and skin protection: Advise: Advise: no need for special protection if the product is used correctly. 9. Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance: Liquid Colour: Colourless Pág.: 4 / 9

5 Odour: Specific Volatility: Boiling temperature at atmospheric pressure: Non relevant* Vapour pressure at 20ºC: Non relevant * Vapour Pressure at 50ºC: Non relevant * Evaporation rate at 20ºC: Non relevant * Product characteristics: Density at 20ºC: 995Kg/m 3 Relative density at 20ºC: Dynamic viscosity at 20ºC: Non relevant * Kinematic viscosity at 20ºC: Non relevant * Kinematic viscosity at 40ºC: Non relevant * Concentration: Non relevant * ph: 8.0 ± 2.0 Vapour density at 20ºC: Non relevant * Partition coefficient: n-octanol/water: Non relevant * Water solubility at 20ºC: Fully soluble Solubility properties: Not determined Decomposing temperature: Non relevant * Flammability: Flammability temperature: Not determined Self-ignition temperature: Not determined. Lower flammability limit: Not determined Higher flammability limit: Not determined 9.2. Other information: Superficial tension at 20ºC: Non Relevant* Refractive index: Non Relevant* Non relevant* Due to product s nature 10. Stability and reactivity 10.1 Reactivity There are no expected dangerous reactions. Pay attention to chemical product s storage technical instructions (see section 7) Pág.: 5 / 9

6 10.2 Chemical stability Chemically stable under normal storage, handling and use conditions 10.3 Possibility of hazardous reactions Unknown possibility of reactions, regarding the product s specified use Conditions to avoid Unknown possibility of reactions, regarding the product s specified use Incompatible materials Avoid direct contact with oxidising materials and fuels Hazardous decomposition products Carbon monoxide and other organic compounds can be formed during combustion. 11. Toxicological information 11.1 Information on toxicological effects There s no experimental data regarding this mixture Specific substance s toxicological information: Propan-2-ol; CAS nº: ; EINECS nº: LD50 Oral: 5280mg/Kg (Mouse) LD50 Skin: 12800mg/Kg (Mouse) LC50 Inhaling: 726mg/L (Mouse) 12. Ecological information 12.1 Toxicity There s no experimental data regarding this mixture Substance s toxicity: Propan-2-ol; CAS nº: ; EINECS nº: LC50: 9640mg/L (96h) (Pimephales promelas: Fish) EC50: 13299mg/L (48h) (Daphnia aeruginosa: Crustacean) EC50: 1000mg/L (72h) (Scenedesmus subspicatus: Algae) Pág.: 6 / 9

7 12.2 Persistence and degradability There s no experimental data regarding this mixture. Degradability and substance s persistence: Propan-2-ol; CAS nº: ; EINECS nº: Degradability: DBO5: 1.19 g O 2/g DQO: 2.23g O 2/g DBO5/DQO: 0.53 Biodegradability: Concentration: 100mg/L Conc. Fungi: 30mg/L % DBO degraded: 86% All surfactants used on this preparation meet the biodegradability criteria according to CE Regulation no. 648/2004, March 31 st, regarding detergents (ultimate aerobic biodegradability > 60% mineralization on 28 days) Bioaccumulative potential There s no experimental data regarding this mixture. Substance s bioaccumulation potential: Propan-2-ol; CAS nº: ; EINECS nº: BCF: 3 Log POW: 0.05 Potential: Low 12.4 Mobility in soil There s no experimental data regarding this mixture Results of PBT and vpvb assessment 12.6 Other adverse effects Non-descript. 13. Disposal considerations 13.1 Waste treatment methods Wastes resulting from the use of this product should be managed in accordance with the legislation in force, particularly in waste disposal / recovery duly authorized for the purpose. Package s elimination: Package recycling (Ecoponto Amarelo). Pág.: 7 / 9

8 14. Transport information Non-hazardous cargo for ADR, RID e IMDG 14.1 UN number 14.2 UN proper shipping name 14.3 Transport hazard class(es) 14.4 Packing group 14.5 Environmental hazards 14.6 Special precautions for user 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture (CE Regulation) 1907/2006 (REACH) Classified accordingly to EU directives 67/548/CE or 1999/45/CE. R-Phrases S-Phrases: S2 Keep out of the reach of children S46 If swallowed, seek medical advice immediately and show this container or label Contains, among other ingredients: Chemical Safety Assessment Currently there is no information available from the supplier. Pág.: 8 / 9

9 16. Other information To the best of our knowledge, the information contained herein is accurate. However, CTEQ S. A. does not assume any liability whatsoever for the accuracy or completeness of the information contained herein. Complete R-Phrases Texts (referring to chapter 3): R11: Highly flammable R36: Irritating to eyes R38: Irritating to skin R41: Risk of serious damage to eyes R67: Vapours may cause drowsiness and dizziness H315: Causes skin irritation H318: Causes serious eye damage H319: Causes serious eye irritation H225: Highly flammable liquid and vapour H336: May cause drowsiness or dizziness Main sources cited: Pág.: 9 / 9