Lion Oil Company. SDS No. LO0011 Date of Preparation: Section 1 - Chemical Product and Company Identification

Transcription

1 Product: Propane Lion Oil Company Revision No.8 SDS No. LO0011 Date of Preparation: Section 1 - Chemical Product and Company Identification Product/Chemical Name: Propane Chemical Formula: Petroleum Hydrocarbon CAS Number: Material Use: Fuel Synonyms: n-propane, L.P.G. Description: Colorless gas with a natural gas odor. Manufacturer or Distributor: Lion Oil Co., 1000 McHenry St., El Dorado, AR 71730; (870) hr Emergency Phone Number: FOR CHEMICAL EMERGENCY Spill, Leak, Fire, Exposure or Accident CALL CHEMTREC Day or Night SDS CONTACT: Beverly McFarland Section 2 - Hazards Identification Emergency Overview HMIS DANGER! Health H Extremely Flammable Gas Flammability F Vapors may cause flash fire Physical Haz. PH Contents under pressure Keep away from ignition sources. Vapors are heavier than air and may travel some distance to an ignition source and flash back. Liquid may cause eye and skin injury, or frostbite. Gas is an asphyxiant, reduces oxygen available for breathing. Potential Health Effects Primary Entry Routes: Inhalation, Skin and/or Eye contact with liquid. Target Organs: Central Nervous System Carcinogenicity: Propylene IARC- 3 Unclassified as to carcinogenicity to humans Inhalation: Vapors may cause dizziness or asphyxiation without warning. May be irritating if inhaled at high concentrations. Eye: Eye contact can cause freezing of tissues (frostbite) Skin: Liquid can cause burns and frostbite. Gas is not an irritant. Ingestion: Not likely to occur PPE Sec. 8 GHS CLASSIFICATION Hazard Class Hazard Category Hazard Statement Gas (Liquefied gas) Pressure H280 Extremely Flammable gas Category 1 H220 Hazards Not Otherwise Classified (HNOC): Static accumulator - Static accumulating flammable materials can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite material and vapor may cause flash fire (or explosion). Can cause frost bite if person is in contact with liquid.

2 LABEL ELEMENTS Pictograms: Signal Word: Danger Physical Hazard Statements: H220: Extremely flammable gas. H280: Contains gas under pressure may explode if heated. Health Hazard Statements: Not classified as a Health hazard under GHS. Environmental Hazard Statements: No classified hazards. Precautionary Statements: Prevention: P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P243: Take precautionary measures against static discharges. Response: P377: Leaking gas fire: Do not extinguish, unless leak can be stopped safely. P381: Eliminate all ignition sources if safe to do so. Storage: P410+P403: Protect from sunlight. Store in a well ventilated place. Disposal: This material is a gas and would not typically be managed as a waste. Section 3 - Composition / Information on Ingredients Ingredient Name CAS Number % vol Propane Propylene Section 4 - First Aid Measures Inhalation: Move to fresh air. If overcome by vapor, remove from exposure and call a physician immediately. If breathing is irregular or has stopped, start resuscitation. If breathing difficulties develop, administer oxygen by qualified personnel. Seek medical attention. Eye Contact: If contact with liquid, flush with water for 15 minutes. Seek medical attention. Skin Contact: Remove any contaminated clothing, and warm skin with lukewarm water. If clothing frozen to the skin, thaw in lukewarm water before removing. Seek medical attention. Ingestion: Not likely to occur. After first aid, get appropriate in-plant, paramedic, or community medical support. Page 2 of 6

3 Flash Point: -156 F Flash Point Method: TCC Autoignition Temperature: 842 F LEL: 2.1 % UEL: 9.5 % Flammability Classification: No Data Section 5 - Fire-Fighting Measures Extinguishing Media: Dry chemical, CO 2, water fog. Cool containers with flooding quantities of water. Unusual Fire or Explosion Hazards: Keep away from heat, sources of ignition and strong oxidizers. Contents under pressure, heated containers may rupture violently. Hazardous Combustion Products: Fumes, smoke, carbon monoxide, sulfur oxides, aldehydes and other decomposition products, in the case of incomplete combustion Special Fire-Fighting Procedures: Extremely flammable - Vapors can readily form explosive mixtures with air. Heavier than air vapors can flow along surfaces to ignition sources and flash back. Cool exposed tanks with water. Heated containers may rupture violently. Do not extinguish fire until leak can be stopped. Use water fog to contain vapors. Use self-contained breathing apparatus in enclosed areas. Section 6 - Accidental Release Measures FOR CHEMICAL EMERGENCY Spill, Leak, Fire, Exposure or Accident CALL CHEMTREC Day or Night Spill /Leak Procedures: Danger, Flammable, eliminate all ignition sources, (No Smoking, Flares, sparks or flames in immediate area). Evacuate area. Large Spills: Isolate the hazard area and restrict access, keep upwind and use water fog to reduce vapor cloud. Shut off source of leak only if it can be done so safely. Water fog may be useful to divert vapor cloud drift. Prevent spreading of vapors through sewers, ventilation systems and confined areas. Wear appropriate respirator and protective clothing. Section 7 - Handling and Storage Handling Precautions: Contents under pressure. Do not get in eyes, on skin or on clothing, may cause frostbite. Do not breathe vapors, mists or fumes. Wear protective equipment described in section 8 if exposure conditions warrant. Use only with adequate ventilation. Storage Requirements: Keep away from open flame, high temperatures, sparks, pilot lights, static electricity, open flames and other sources of ignition. Store in well ventilated area. Store in tightly closed containers approved for LPG. Bond and ground containers during transfer. Post area No smoking or open flame. Storage areas must conform to OSHA, DOT, and NFPA requirements. Section 8 - Exposure Controls / Personal Protection NFPA rating H 1 F 4 R 0 OSHA PEL ACGIH TLV NIOSH REL NIOSH Ingredient TWA STEL TWA STEL TWA STEL IDLH Propane 1000 Simple ppm ppm asphyxiant ppm Propylene Simple asphyxiant Engineering Controls Ventilation: Provide explosion proof ventilation to meet TLV requirements in enclosed work areas. Protective Clothing/Equipment Gloves: Use thermal resistant gloves to prevent frostbite. Goggles: Wear chemical goggles if eye contact is likely. Respiratory: Use organic vapor cartridge respirators for exposures over TLV up to 1000 ppm. Use fresh air or self contained breathing equipment for unknown or high concentrations. Page 3 of 6

4 Section 9 - Physical and Chemical Properties Physical State: Colorless Gas Appearance and Odor: Clear with natural gas odor. Odor Threshold: No Data Vapor Pressure: F Vapor Density (Air=1): 1.55 Formula Weight: 44.1 Density: No Data Specific Gravity (H2O=1, at 4 C): ph: NA Section 10 - Stability and Reactivity Water Solubility: Negligible Other Solubilities: No Data Boiling Point: F Freezing/Melting Point: NA Viscosity: No Data Refractive Index: No Data Surface Tension: No Data % Volatile: 100% Evaporation Rate: >1 (Butyl Acetate = 1) Stability: This Material is Stable. Polymerization: Hazardous Polymerization will not occur. Chemical Incompatibilities: Keep away from Oxidizing agents. Conditions to Avoid: Keep away from open flame, high temperatures, and other sources of ignition. Hazardous Decomposition Products: Combustion can produce smoke, carbon monoxide, and carbon dioxide. Section 11- Toxicological Information Acute Toxicity: Suffocation (asphyxiant) hazard - if allowed to accumulate to concentrations that reduce oxygen below Acute safe breathing levels. Exposure to rapidly expanding gas or vapourizing liquid may cause frostbite ("cold burn"). Skin corrosion/irritation: Serious eye damage/eye irritation: Respiratory sensitization: Skin sensitization: Not available. Germ cell mutagenicity: Carcinogenicity: Reproductive toxicity: Specific target organ toxicity -single exposure: Section 12 - Ecological Information Environmental Fate: This material is volatile and is expected to partition to air. Section 13 - Disposal Considerations Disposal: Local, state and federal disposal regulations must be followed. Container Cleaning and Disposal: Empty Container Warning: Empty containers retain product residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Page 4 of 6

5 Section 14 - Transport Information DOT Transportation Data (49 CFR ): The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous Goods Regulations, for additional description information. DOT Shipping Name: Liquefied Petroleum Gas DOT Hazard Class: 2.1 DOT ID No.: UN1075 DOT Packing Group: N/A Hazard Label: Flammable Gas Section 15 - Regulatory Information EPA Regulations CERCLA Reportable Quantity (RQ) (40 CFR 302.4): None Compound CAS Number RQ SARA 311/312 Codes (40 CFR 370 / 29 CFR ): Fire YES Pressure YES Reactivity NO Immediate (acute) NO Delayed (chronic) NO SARA Toxic Chemical (40 CFR 372) Section 313: Compound CAS Number Concentration % Propylene SARA EHS (Extremely Hazardous Substance) (40 CFR 355): Not listed TSCA (40 CFR 710): This product, or its components are listed on the Toxic Substance Control Act (TSCA) Chemical Substance Inventory. State Regulations: The following chemicals are specifically listed by individual states, for details on each states regulatory requirements you should contact the appropriate agency in that state. Compound CAS Number States Propane NJ, Propylene FL, NJ, PA NJ NEW JERSEY RIGHT TO KNOW HAZARDOUS SUBSTANCE FL FLORIDA TOXIC SUBSTANCE LIST PA PENNSYLVANIA HAZARDOUS SUBSTANCE LIST Prepared By: Lion Oil Control Lab Revision Notes: Updated with GHS Swapped sections 2 and 3 SECTION 16 - Other Information Page 5 of 6

6 Disclaimer: LION OIL COMPANY PROVIDES THIS INFORMATION FOR THE USER'S CONSIDERATION. LION OIL COMPANY BELIEVES THIS INFORMATION IS ACCURATE, BUT NOT ALL INCLUSIVE IN ALL CIRCUMSTANCES. USER SHOULD ENSURE THAT USER HAS CURRENT DATA RELEVANT FOR ITS PURPOSES. NO WARRANTY, EXPRESSED OR IMPLIED, INCLUDING MERCHANTABILITY, FITNESS OR OTHERWISE IS GIVEN. Reference and research: (1) The International Chemical Safety Card - (2) NIOSH Pocket Guide to Chemical Hazards - (3) 2007 Guide to Occupational Exposure Values Compiled by ACGIH (4) 2008 Emergency Response Guidebook - (5) Sax s Dangerous Properties of Industrial Materials, 9th Edition; Edited by Richard J. Lewis, Sr.; Version 1.6; Copyright 1997 by John Wiley & Sons, Inc. (6) Touchstone Environmental, Inc.; Chemcheck Handbook (educational resource) (7) Hawley s Condensed Chemical Dictionary, 13 th Edition; Edited by Richard J. Lewis, Sr.; Version 1.1 Copyright 1997 by John Wiley & Sons, Inc. (8) Environmental Contaminant Reference Databook; VOLUMES I, II and III; by Jan. C. Prager; Version 2.0; Copyright 1997 by John Wiley & Sons, Inc. (9) Fire Protection Guide to Hazardous Materials, Twelfth Edition; National Fire Protection Association (NFPA 325) Guide to Hazardous Chemical Properties of Flammable Liquids, Gases, and Volatile Solids edition. (10) Hazardous Materials Handbook; Richard P. Pohanish and Stanley A. Greene, Version 1.3 Copyright 1997 by Richard P. Pohanish and Stanley A. Greene Page 6 of 6