MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET SANTOWEB DX 44B/2200S RHEIN CHEMIE CORPORATION 145 Parker Court Chardon, OH TRANSPORTATION EMERGENCY NON-TRANSPORTATION CALL CHEMTREC... : (800) RCC EMERGENCY PHONE : (440) INTERNATIONAL... : (703) RCC INFORMATION PHONE: (800) Section 1: Product and Company Identification Product Name: SANTOWEB DX 44B/2200S Article Number: Section 2: Composition/Information on Ingredients HAZARDOUS INGREDIENTS Ingredient Name/ Concentration CAS Number Exposure Limits Min. Max. Cellulose Exposure limit for: Cellulose Distillates, Petroleum, Solvent-Dewaxed Heavy Paraffinic Exposure limit for: Oil mist, mineral Carbon Black OSHA (PEL): 5.00 mg/m3 TWA Respirable Fraction mg/m3 TWA Total Dust ACGIH (TLV): mg/m3 TWA OSHA (PEL): 5.00 mg/m3 TWA ACGIH (TLV): mg/m3 STEL 5.00 mg/m3 TWA OSHA (PEL): 3.50 mg/m3 TWA ACGIH (TLV): 3.50 mg/m3 TWA 60% 100% 10% 30% 1% 5% 1 of 8

2 Section 3: Hazards Identification EMERGENCY OVERVIEW CAUTION! Color: Black Form: Solid Semi-Loose Coated Fibers Odor: Slight Odor, Distinct odor May cause slight skin and eye irritation. May cause slight skin irritation. May cause slight eye irritation. Contains material which may cause cancer. Toxic gases/fumes are given off during burning or thermal decomposition. POTENTIAL HEALTH EFFECTS Route(s) of Entry: Eye Contact, Skin Contact HUMAN EFFECTS AND SYMPTOMS OF OVEREXPOSURE Inhalation Hazards Acute Inhalation Hazards: Skin Hazards Acute Skin Hazards: Eye Hazards Acute Eye Hazards: Ingestion Hazards Acute Ingestion Hazards: Carcinogenic Effects: Carcinogenic Components: NTP: IARC: OSHA: Medical Conditions Aggravated by Exposure: Exposure to high vapor concentrations may cause respiratory tract irritation, sore throat, severe cough, shortness of breath, and chest pain. May be harmful if inhaled. This product may cause skin irritation. May cause some redness of the affected area, with itching and swelling possible. Fumes of this material may cause irritation to the eyes. Not expected to be harmful if swallowed. Epidemiological studies of workers in the carbon black producing industry have shown no significant health effects due to occupational exposure to carbon black. In addition, studies in rats have shown effects due only to the prolonged exposure from the accumulation of nontoxic dust in the pulmonary system including chronic inflammation, lung fibrosis, and lung tumors. Carbon Black: Not listed Carbon Black: Classified as IARC Possible Human Carcinogen (Group 2B) - "The chemical or group of chemicals is possibly carcinogenic for humans." Carbon Black: Not regulated May aggravate existing eye, skin or respiratory conditions. 2 of 8

3 Section 4: First Aid Measures First Aid for Eye: First Aid for Skin: First Aid for Inhalation: First Aid for Ingestion: Note to Physician: In case of contact, flush eyes with large quantities of water for at least 15 minutes. Get medical attention if irritation develops or persists. Immediately remove contaminated clothing and shoes. In case of skin contact, wash affected areas with soap and water. Wash clothing and clean shoes before reuse. Get medical attention. If inhaled, remove to fresh air. Seek medical attention if irritation develops or persists. If breathing is difficult, give oxygen. If material is ingested, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Call a physician. Treat symptomatically. Section 5: Fire Fighting Measures Flash Point: Flammable Limits: Upper Explosion Limit (UEL %): Lower Explosion Limit (LEL %): Auto-ignition Temperature: Extinguishing Media: Suitable: Special Fire Fighting Procedures: Unusual Fire/Explosion Hazards: 350 F (176 C) Pensky-Martens Open Cup Not Established Not Established 368 F (187 C) Carbon Dioxide, Dry Chemical, Foam, Water spray for large fires. Full emergency equipment with self-contained breathing apparatus and full protective clothing should be worn by firefighters. During a fire, irritating and toxic gases may be generated by thermal decomposition or combustion. Thermal decomposition of this product may produce irritating and toxic gases. Section 6: Accidental Release Measures Spill or Leak Procedures: Collect for disposal. Cover spill with absorbent material, such as sand, sweeping compound or diatomaceous earth; collect material for disposal. Utilize protective clothing and equipment. Contain and collect spill for approved disposal. 3 of 8

4 Section 7: Handling and Storage Storage Temperature: Store at ambient conditions Minimum: 2 C Maximum: 35 C Handling/Storage Precautions: Other Notes: Do not get on skin or clothing. Do not get in eyes. Do not taste or swallow. Do not breath dust, vapors or mist. Avoid inhalation and skin or eye contact with processing fumes. Use local exhaust ventilation above processing equipment. Keep container tightly closed when not in use. Use with adequate ventilation. Store in a cool, dry place. Handle in accordance with good industrial hygiene and safety practices. Do not store or consume food, drink or tobacco in area where they may become contaminated with this material. Protect from freezing. Section 8: Exposure Controls/Personal Protection Personal Protection Equipment Eye Protection Requirements: Skin Protection Requirements: Ventilation Requirements: Additional Protective Measures: Safety glasses with side shields or goggles are recommended. Wear appropriate chemical resistant gloves and clothing., Chemically resistant gloves recommended (neoprene). Use local exhaust ventilation if dusting or misting is a problem, to maintain air levels below the recommended exposure limit. Engineering controls should be sufficient to ensure airborne levels do not approach or exceed the exposure limits listed in Section 2. Standard reference sources regarding industrial ventilation (i.e., ACGIH Industrial Ventilation) should be consulted forguidance about adequate ventilation. Emergency showers and eye wash stations should be available. Section 9: Physical and Chemical Properties Physical Form: Solid Appearance: Semi-Loose Coated Fibers Color: Black Odor: Slight Odor, Distinct odor Boiling Point: Not Applicable Melting/Freezing Point: No Data Available Solubility in Water: Insoluble Bulk Density: 500 kg/m3 Percent Volatile by Volume: of 8

5 Section 10: Stability and Reactivity Stability: Hazardous Polymerization: Substances to Avoid: Conditions to Avoid: Decomposition Products: Stable Will not occur None Known Avoid heat, flames, sparks and other sources of ignition., Avoid contact with water and high temperatures. Oxides of carbon, Sulfur Dioxide Section 11: Toxicological Information Toxicity Data for SANTOWEB DX 44B/2200S Acute oral toxicity: LD50 = 11,000 mg/kg (Rat) Acute dermal toxicity: Eye Irritation: Skin Irritation: Toxicity Data for Cellulose Acute oral toxicity: Acute dermal toxicity: LD50 = 7,940 mg/kg (Rabbit) Slightly irritating Slightly irritating LD50 = > 5 g/kg (Rat) LD50 = > 2 g/kg (Rabbit) LD50 = > 31,600 mg/kg (Rat) Intraperitoneal Acute inhalation toxicity: > 5,800 mg/m3, 4 hrs, (Rat) Toxicity Data for Distillates, Petroleum, Solvent-Dewaxed Heavy Paraffinic Toxicity Note: No data available for this component. Toxicity Data for Carbon Black Acute oral toxicity: LD50 = > 10 g/kg (Rat) LD50 = > 15,400 mg/kg (Rat) Acute dermal toxicity: Carcinogenicity: LD50 = > 3 g/kg (Rabbit) Several inhalation studies involving carbon black in female rats have shown increases in benign and malignant lung tumors. Although a large body of data on possible mechanisms of carcinogenicity in rats was considered by the IARC Working Group, it was not possible to state with confidence that the mechanisms of carcinogenicity in rats correlate to exposure in humans. Tumors have not been observed in other animal species (i.e. mouse and hamster) under similar circumstances and study conditions. 5 of 8

6 Section 12: Ecological Information Ecological Data for SANTOWEB DX 44B/2200S Ecological Note: No data available for this product. Ecological Data for Cellulose Ecological Note: No data available for this component. Ecological Data for Distillates, Petroleum, Solvent-Dewaxed Heavy Paraffinic Ecological Note: No data available for this component. Ecological Data for Carbon Black Ecological Note: No data available for this component. Section 13: Disposal Considerations Waste Disposal Method: Empty Container Precautions: Other Disposal Notes: Disposal must be in compliance with federal, state and local environmental control regulations. Do not reuse empty container. Label precautions also apply to this container when empty. Recondition or dispose of empty container in accordance with government regulations. Rhein Chemie requires that CHEMTREC be immediately notified ( ) when this product is unintentionially released from its container during its course of distribution, regardless of the amount released. Distribution includes transportation, storage incidental to transportation, loading and unloading. Such notification must be immediate and made by the person having knowledge of the release. Section 14: Transportation Information Domestic Surface Transportation (DOT) Hazard Class or Division: Non-Regulated Marine Transportation (IMO / IMDG) Hazard Class Division Non-Regulated Number: Air Transportation (ICAO / IATA) Hazard Class Division Non-Regulated Number: Section 15: Regulatory Information 6 of 8

7 United States Federal Regulations OSHA Hazcom Standard Rating: TSCA Inventory List: Hazardous On TSCA Inventory CERCLA Hazardous Substance: Component(s) None Reportable Quantity SARA Title III SARA Section 302 Extremely Hazardous Substances: Component(s)/ Concentration CAS Number Min. Max. None SARA Section 311/312 Hazard Categories: Immediate Health Hazard, Delayed Health Hazard SARA Section 313 Toxic Chemicals: Component(s)/ CAS Number None Reporting Concentration Threshold Min. Max. RCRA Status: If discarded in its purchased form, this product would not be a hazardous waste either by listing or by characteristic. However, under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product or derived from the product should be classified as a hazardous waste. (40 CFR ) The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections of the MSDS may also be applicable for state requirements. For details on your regulatory requirements you should contact the appropriate agency in your state. State Right-to-Know Information Component(s)/ Concentration CAS Number State Code Min. Max. Cellulose PA-N, NJ-N 60% 100% Distillates, Petroleum, Solvent-Dewaxed Heavy PA-H, NJ-H, MA-H 10% 30% Paraffinic Butadiene-Styrene Copolymer PA-N, NJ-N 7% 13% Carbon Black PA-H, NJ-H, MA-H 1% 5% The following component(s) are listed under California Proposition 65: Carbon Black CA-C 1% 5% State Code Translation Table PA-N = Pennsylvania Non-hazardous PA-H = Pennsylvania Hazardous Substance List 7 of 8

8 NJ-N = New Jersey Other - includes predominant ingredients NJ-H = New Jersey Hazardous Substance List MA-H = Massachusetts Hazardous Substance List CA-C = Warning! This chemical is known to the State of California to cause cancer. Section 16: Other Information NFPA 704M Rating Health 1 Flammability 1 Reactivity 0 Other 0=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme HMIS Rating Health * 1 Flammability 1 Reactivity 0 0=Minimal 1=Slight 2=Moderate 3=Serious 4=Severe *=Chronic Health Hazard RHEIN CHEMIE CORPORATION s method of hazard communication is comprised of Product Labels and Material Safety Data Sheets. HMIS and NFPA ratings are provided by RHEIN CHEMIE CORPORATION as a customer service. Contact: HES Dept. Phone: (440) MSDS Number: Version Date: 05/06/2011 MSDS Version: 1.0 This information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of RHEIN CHEMIE CORPORATION. The data on this sheet relates only to the specific material designated herein. RHEIN CHEMIE CORPORATION assumes no legal responsibility for use or reliance upon these data. Indicates Relevant Change Made. 8 of 8