MODEL 131/132 GAS CHROMATOGRAPH

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1 MODEL 131/132 GAS CHROMATOGRAPH Envent Engineering Ltd. Model 131/132 Gas Chromatographs are rugged, versatile and reliable online natural gas analyzers. They are robustly designed by engineers and experienced field technicians to operate reliably in remote areas with dirty samples, unreliable power, no instrument air and limited maintenance. The Model 131/132 Gas Chromatographs provide accurate and reliable analysis of gas composition and other vital parameters to ensure quality of the product. Custody transfer energy measurement applications are also supported with an extensive library of physical property calculations in accordance with all applicable AGA and ISO natural gas standards. Application Flexibility With multiple calibration tables available for multi-stream applications application flexibility is assured. The GC oven can operate over a wide temperature range with equally wide carrier pressure settings. This allows for applications to be developed based on stream specific measurements using the same hardware platform. In multi-stream applications diverse stream compositions can be measured in the same GC. For example: C3/C4 Natural Gas Liquids (NGLs) combined with natural gas sour plant inlets and sales/residue gas OR high (>1200) low (<1020) BTU applications Typical Applications C6+ Analysis for Natural Gas processing plant inlets and outlets. C6+ Analysis for Natural Gas BTU Energy measurement C3/C4 Liquids C5+ Natural Gas Liquids (NGL) analysis C6+ or C7+ natural gas analysis with light ends (O2, N2, CO) Combinations of the above for multi-stream analysis Features Benefits ± 0.2 Deg C. oven temperature hysteresis Provides stable base line and greater component sensitivity Less than 40 watts nominal power consumption Unit can operate on solar power or thermal electric generators Low Helium consumption months between costly and time consuming Helium bottle replacement Thermistor based Thermal Conductivity Detectors No risk of damage to sensor on loss of carrier gas Approved for Class 1, Div1 or Div 2 Gr B,C,D Flexibility in applications and installations Common electronic platform to Envent H2S analyzers Time proven reliability Industry standard Valves and detectors Long term reliability and availability of spares Field replaceable GC Module (valve and column set) Allows for fast application changes and field repair Integrated Configuration Environment (ICE) Provides data collection, storage, reporting, configuration & applications flexibility 12/24 DC or VAC power supplies Site flexibility Ethernet and serial Modbus capable Remote Data Acquisition and control with Envents ICE software

2 Electronics and Software Platform The ARM 7 based CPU board and Windows TM based software work together to provide a superior analyzer platform for the H2S/Total Sulfur analyzers and the GC. This common electronics platform is equipped with low noise/high resolution 28 bit A/Ds to improve raw signal. With the same electronics platform operating in over 900 installations worldwide it's field proven in some of the harshest production environments anywhere. The primary measurement interface is via modbus protocol to a flow computer or PLC. The primary diagnostic/operational interface is via serial/ethernet interface to a laptop running ICE TM software onsite or remote via cell modem to an IP address assigned to the GC. Access for wiring to all power and signal I/O is from the left side of the electronics enclosure For GC applications several advanced functions are embedded into the GC operating system to function as companion diagnostics when troubleshooting with the windowstm based software (ICE). These advanced functions improve diagnostics capability to increase reliability AND improve measurement performance. The improved sensitivity allows for measurement of trace impurities such as H2S (below 50 ppm) in standard C6+ Natural Gas BTU applications. ICE provides all user configuration, diagnostic, and reporting functions and acts as the primary user interface to the GC. The result is a very rugged, easy-to-use, GC with the accuracy/repeatability required for custody transfer energy measurement applications. Total Natural Gas Quality Measurement There are typically three primary analytical measurements required in the field to meet Natural Gas contract specifications. They are Energy Content (BTU), water content (#/MMSCF) and H2S content (ppm). By designing the hardware and software platform with common packaging to support installations in hazardous areas all three primary gas quality measurements can be combined into one system with a single software interface. The three gas quality analyzers can operate together with common sample systems, identical modbus protocol and a common software interface. Training requirements are reduced and a single vendor can take full responsibility for support of the total gas measurement system. Envent's Gas Chromatograph packaging uses the same design as the H2S analyzers. The result is a family of Natural Gas analyzers all designed for mounting in either Division I or II rated hazardous locations and capable of operating on AC or DC power. The Model 131 GC is approved for Class I Div I Gr B,C&D areas while the 132 GC is approved for Class I Div II Gr B,C&D areas. In both models the GC oven and electronics enclosures are completely separated to eliminate the potential for sample to come in contact with electrical components. In sour gas or liquids applications this is very important.

3 INTEGRATED CONFIGURATION ENVIRONMENT (ICE) Integrated Configuration Environment (ICE) ICE (Windows TM based user interface) is Envent's software developed specifically for set up, configuration and troubleshooting analyzers. Advanced diagnostics were developed within ICE to match the high end capability of the GC electronic platform for trace component analysis or multi-component analysis. Several advanced functions such as Chromatogram overlay, zoom, and best-fit are particularly useful for GC operations. A single Chromatogram file may contain hundreds of sequential chromatograms for use by technicians in either Live mode or Simulated Analysis mode. Simulated Analysis provides the advanced diagnostic tools to senior level technicians and supervisors to optimize GC operations off-site with simple attachments or direct communications to the GC. Measurement accuracy can be maintained in custody transfer applications as a result because designated specialists can use Simulated Analysis to manipulate actual Raw Data from the field and apply corrective action until optimal results are achieved offline. This empowers the specialist with innovative tools to optimize GC operations for numerous installations without actually going to the field. Data Storage and Reports Eight fully configurable archives are available with up to 4 MB data storage. Users can customize reports from Archives or use the standard Report format for analysis results, raw data, configuration and calibrations.

4 SAMPLE CONDITIONING SYSTEMS The Model 131/132 GC uses minimal carrier consumption for both columns and valve actuation. A single bottle of carrier gas can provide over 12 months of operation on 1 standard size 247 ft 3 Helium bottle. Field service is simplified with industry standard components and special tools are not required. Sample system components are available locally or off the shelf from Envent. If liquid carryover should pass through the sample system in dirty gas production applications the entire GC Module (columns,valves with configuration and calibration data) can be replaced with a standby GC module in less than an hour or rebuilt in the field. No need to send it back to the factory as the user has the choice of rebuilding it themselves. Standard sample system components consists of 316SS for all wetted parts with Swagelock TM fittings used throughout (other fittings are available upon request). Block valves are provided on sample inlets with regulating valves on bypass and liquid sweeps from coalescing or membrane filters. Second stage pressure regulation is included on each process stream as a standard feature for convenience and to minimize JT effect when reducing pressures at multiple locations. This improves accuracy in high BTU applications and reduces set up time in multi-stream applications. Optimal performance depends on pressure balancing between individual streams and this process is simplified when pressure regulation is provided on each stream. Downstream pressure indication is provided along with a common sample rotameter to easily validate sample flow to the GC oven. Stream switching solenoids are available standard in multi-stream applications with optional pneumatic double block and bleed stream selectors as an alternate when stream compositions are diverse or the application requires a heated sample system oven. The net benefit to users is out-of-box start up, simplified operations and long term reliability in remote harsh environments.. The outdoor mounting option for high BTU applications has all sample conditioning AND CALIBRATION GAS mounted together in a heated lower sample system oven with temperature control to 112F (40C). This design reduces installation costs in moderate climates as the need for a dedicated analyzer buildings is eliminated. Measurement integrity is assured in C9+ high BTU custody transfer installations by ensuring that calibration gas integrity is maintained to prevent C6+ drop-out. Alternate solutions would require a building or similar heated enclosures. The same heated sample system oven is used for Natural Gas Liquids (NGL) applications with external liquid calibration standards for C3/C4 analysis. GC OVEN DESIGN- FIELD REPLACEABLE MODULE GC valves (6 port or 10 port) diaphragm type Single 10-port valve design for most applications simplifies troubleshooting 1/16 micro-packed or capillary columns TCD based detectors ( Measurement & Reference) Airless heat-sink design Digital temperature indication and PID control Oven Temperature Control +/- 0.2ºC in 18ºC to + 55ºC ambient temperature environments GC module for easy field retrofit (valve column assembly) Full open door oven design allows for easy field service. GC module can be completely replaced to re-app the GC or valve/columns/detectors can be replaced or rebuilt if spare GC modules are not available

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6 SPECIFICATIONS HARDWARE Detector GC Oven Carrier Gas Sample Flow Columns GC Valves Power Electronics Sensor inputs Area Classifcaton Outputs Display Weight & Dimensions Ambient Temperature Thermal Conductvity Detector (TCD) Thermistor Type Heat Sink design, temperature programmed from ICE. Temperature Range is 105º to 212ºF (40ºC to 100ºC) Isothermal operaton +/- 0.2ºC. (No instrument air required) UHP He 7-20 cc/min at psig ( Bar) cc/min. 50 cc/min typical micro-packed 1/16 stainless steel std. Other sizes per applicaton requirements 10-port and 6-port pneumatc pressure in energized state, mechanical pressure in de-energized state (up to 4 max) 120/220 VAC standard, VDC optonal 50 wats start-up, 40 wats average ambient temperature 70 ºF (20ºC) Envent designed ARM7 CPU based Analyzer platorm 2 sensor inputs, 28 bit A/D low noise Class 1, Div1 Grps C&D certfed to CSA standards (Model 131) Class 1, Div2 Grps C&D certfed to CSA standards (Model 132) Dual isolated 2 wire 4-20 ma, (4-wire standard, loop powered One (1) RS-232 Modbus Serial Port for Laptop Diagnostcs and Confguraton with ICE Three (3) RS485 serial Ports (Modbus Protocol) One (1) Ethernet Port (ICE Confguraton or TCIP Modbus) Four (4) 3 amp SPDT alarm relays (one dedicated to Analyzer Status) Four (4) solid state solenoid drivers ( auto cal, stream switching, valve actuator) 2x16 character LCD with back lightng Menu is scrolled by internal buton or external magnetc switch (Class 1, Div1) Menu includes component values, Heatng values (BTU or other units), specifc gravity, Wobbe Index, Compressibility, specifc heat ratos Including Standard backpan - Model 131 (Div I) 65 lbs (mounted on 24" X 36" panel), Model 132 (Div II) 40 lbs (mounted on 24" X 36" panel) GC only- Model 131 (Div I) 37.5 H X 21 W X 10 D Model 132 (Div I) 32 H X 19 W X 7.5 D 0-130ºF (-18 to +55C) MEASUREMENT Measurement Range Accuracy Repeatability Streams Calibraton Tables Archives Reports Calibraton Analysis Time 0-35 parts per million H2S with heart cut applicaton using back-fush to vent % range in mult component applicatons. Max 20 components per stream Component measurement.2% of full scale +/- 1 BTU on Single Valve Applicaton +/-.5 Btu on Dual Valve Applicaton 7 maximum plus 1 auto Calibraton stream or 6 maximum with 2 auto calibraton streams 2 standard with 1 component table and one tmed event table each 4 Meg standard for 8 fully confgurable archives Analysis, Calibraton, Raw Data standard with user confgurable text descriptors IE user confgurable language) Auto Manual or forced calibraton. Auto Calibraton tme based or from external switch Natural Gas minutes on single valve Natural Gas C6+ 5 minutes with dual valve Natural Gas C9+ with Hydrocarbon Dew point calculaton minutes Acid Gas ( C02/H2S ) 90 seconds C5+ Natural Gas Liquids (NGL) analysis 4-5 mins C6+ Natural Gas Analysis with light ends (Oxygen, Nitrogen, Carbon Monoxide) minutes SAMPLE CONDITIONING SYSTEMS Mountng Standard-Mounted on common back pan suitable for wall mountng Optonal outdoor mountng package for high BTU applicatons- Mounted below GC in lower heated oven to 40C for outdoor mountng with BTU calibraton standard inside Optonal NGL package- Heated sample system oven mounted below GC on common uni-strut foor stand Optonal NGL package- Heated sample system oven mounted separate from GC & designed for mountng on outside wall of analyzer building (user to supply heat traced sample lines to GC mounted indoors) ENVENT ENGINEERING LTD.7060E FARRELL RD S.E. CALGARY ALBERTA CANADA T2H 0T2 (403) OFFICE (403) FAX

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