SAFETY DATA SHEET ARDEX RG Cleaner

Transcription

1 SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Cleaning agent Details of the supplier of the safety data sheet Supplier Contact Person ARDEX GmbH Friedrich-Ebert-Strasse 45 D Witten-Annen Tel.: 0049 (0)2302/664-0 Fax: 0049 (0)2302/ sicherheitsdatenblatt@ardex.de Herr Matthey, Abt. QSU 1.4. Emergency telephone number +49 (0) 761 / (Vergiftungs-Informations-Zentrale Freiburg, D) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Physical and Chemical Hazards Met. Corr. 1 - H290 Human health Skin Corr. 1A - H314 Environment Not classified. Classification (1999/45/EEC) C;R35. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section Label elements Contains Potassiumhydroxide SODIUM HYDROXIDE Label In Accordance With (EC) No. 1272/2008 Signal Word Danger Hazard Statements H290 H314 Precautionary Statements P102 P501 Supplementary Precautionary Statements P280 P260 May be corrosive to metals. Causes severe skin burns and eye damage. Keep out of reach of children. Dispose of contents/container in accordance with local regulations. Dispose of contents/container in accordance with regional regulations. Dispose of contents/container in accordance with national regulations. Dispose of contents/container in accordance with international regulations. Wear protective gloves/protective clothing/eye protection/face protection. Do not breathe vapour/spray. 1 / 7

2 P P IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Other hazards SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures Potassiumhydroxide > 2 - > 5 % CAS-No.: EC No.: Registration Number: xxxx Met. Corr. 1 - H290 Acute Tox. 4 - H302 Skin Corr. 1A - H314 C;R35 Xn;R22 PROPAN-2-OL > 1- > 5 % CAS-No.: EC No.: Registration Number: xxxx Flam. Liq. 2 - H225 Eye Irrit. 2 - H319 STOT SE 3 - H336 F;R11 Xi;R36 R67 quartäres C12-14 alkylmethylaminethoxylatmethychlorid 1-3 % CAS-No.: EC No.: Acute Tox. 4 - H302 Skin Irrit. 2 - H315 Xi;R41. SODIUM HYDROXIDE > 1 - > 2 % CAS-No.: EC No.: Registration Number: xxxx Met. Corr. 1 - H290 Skin Corr. 1A - H314 C;R35 Trinatriumnitriltriacetat > 1 - > 5 % CAS-No.: EC No.: Xi;R41. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 2 / 7

3 4.1. Description of first aid measures General information Get medical attention if any discomfort continues. Inhalation Provide rest, warmth and fresh air. Place unconscious person on the side in the recovery position and ensure breathing can take place. Ingestion Get medical attention immediately! Rinse mouth thoroughly. Do not induce vomiting. Do not give victim anything to drink if he is unconscious. Skin contact Wash skin thoroughly with soap and water for several minutes. Immediately remove contaminated clothing. Eye contact Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyelids widely. If irritation persists: Seek medical attention and bring along these instructions Most important symptoms and effects, both acute and delayed General information The severity of the symptoms described will vary dependant of the concentration and the length of exposure Indication of any immediate medical attention and special treatment needed Treat Symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Water spray, foam, dry powder or carbon dioxide. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire Special hazards arising from the substance or mixture Hazardous combustion products Fire or high temperatures create: Carbon monoxide (CO). Carbon dioxide (CO2) Advice for firefighters Protective equipment for fire-fighters Use air-supplied respirator, gloves and protective goggles. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet Environmental precautions Do not discharge into drains, water courses or onto the ground Methods and material for containment and cleaning up Absorb spillage with suitable absorbent material Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet. Collect and dispose of spillage as indicated in section 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Avoid eating, drinking and smoking when using the product Conditions for safe storage, including any incompatibilities Store in closed original container at temperatures between 5 C and 25 C. Storage Class Storage Class: 8A 3 / 7

4 7.3. Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Name STD TWA - 8 Hrs STEL - 15 Min Notes Potassiumhydroxide WEL 2 mg/m3 PROPAN-2-OL WEL 400 ppm 999 mg/m3 500 ppm 1250 mg/m3 SODIUM HYDROXIDE WEL 2 mg/m3 WEL = Workplace Exposure Limit. DIPROPYLENE GLYCOL MONOMETYL ETHER (CAS: ) DNEL Consumer Dermal Long Term Systemic Effects 15 mg/kg/day Consumer Inhalation. Long Term 37, 2 mg/m3 Industry Dermal Long Term Systemic Effects 65 mg/kg/day Industry Inhalation. Long Term Systemic Effects 310 mg/m3 PNEC Freshwater 19 mg/l Marinewater 1, 9 mg/l Sediment (Freshwater) 70, 2 mg/kg Sediment (Marinewater) 7, 02 mg/kg STP 4168 mg/l 8.2. Exposure controls Protective equipment Engineering measures Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not exceeded. Respiratory equipment Wear respiratory protection with combination filter (dust and gas filter). Hand protection Protective gloves and goggles must be used if there is a risk of direct contact or splash. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Gloves of nitrile rubber, PVA or Viton are recommended. Eye protection Wear tight-fitting goggles or face shield. Hygiene measures When using do not eat, drink or smoke. Skin protection Protection suit must be worn. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Liquid Colour Yellow. Odour No characteristic odour. Initial boiling point and boiling range ( C) Melting point ( C) Relative density 1, 1 20 C 4 / 7

5 Bulk Density Vapour pressure 3000 hpa 50 C Evaporation rate ph-value, Conc. Solution 14 Flash point ( C) 61 C 9.2. Other information SECTION 10: STABILITY AND REACTIVITY Reactivity Chemical stability Stable under normal temperature conditions and recommended use Possibility of hazardous reactions Not available Conditions to avoid No specific conditions are likely to result in a hazardous situation Incompatible materials Hazardous decomposition products None under normal conditions. SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Skin contact Corrosive. Prolonged contact causes serious tissue damage. Eye contact Risk of serious damage to eyes. Toxicological information on ingredients. Potassiumhydroxide (CAS: ) PROPAN-2-OL (CAS: ) SODIUM HYDROXIDE (CAS: ) DIPROPYLENE GLYCOL MONOMETYL ETHER (CAS: ) Acute toxicity: Acute Toxicity (Oral LD50) 5135 mg/kg Rat Acute Toxicity (Dermal LD50) > mg/kg Rabbit Acute Toxicity (Inhalation LC50) > 500 mg/l (vapours) Rat quartäres C12-14 alkylmethylaminethoxylatmethychlorid Trinatriumnitriltriacetat (CAS: ) SECTION 12: ECOLOGICAL INFORMATION Toxicity 5 / 7

6 Ecological information on ingredients. LC 50, 96 Hrs, Fish mg/l > EC 50, 48 Hrs, Daphnia, mg/l 1919 IC 50, 72 Hrs, Algae, mg/l > 969 DIPROPYLENE GLYCOL MONOMETYL ETHER (CAS: ) Persistence and degradability Degradability No data available Bioaccumulative potential Mobility in soil Mobility: No data available Results of PBT and vpvb assessment This product does not contain any PBT or vpvb substances Other adverse effects Not available. SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Waste Class SECTION 14: TRANSPORT INFORMATION UN number UN No. (ADR/RID/ADN) 1719 UN No. (IMDG) 1719 UN No. (ICAO) UN proper shipping name Proper Shipping Name CAUSTIC ALKALI LIQUID, N.O.S. (Potassiumhydroxide, SODIUM HYDROXIDE) Transport hazard class(es) ADR/RID/ADN Class 8 ADR/RID/ADN Class Class 8: Corrosive substances. ADR Label No. 8 IMDG Class 8 ICAO Class/Division 8 Transport Labels CORROSIVE Packing group 6 / 7

7 ADR/RID/ADN Packing group IMDG Packing group ICAO Packing group II II II Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user EMS Emergency Action Code F-A, S-B 2R Hazard No. (ADR) 80 Tunnel Restriction Code (E) Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Chemical Safety Assessment SECTION 16: OTHER INFORMATION Revision Comments This is first issue. Issued By Herr Matthey, Abt. QSU Manager für Sicherheit, Gesundheitsschutz und Umwelt Date 11/06/2016 Risk Phrases In Full R11 R22 R35 R36 R41 R67 Hazard Statements In Full H318 H319 H314 H315 H302 H225 H290 H336 Highly flammable Harmful if swallowed. Causes severe burns. Irritating to eyes. Risk of serious damage to eyes. Vapours may cause drowsiness and dizziness. Causes serious eye damage. Causes serious eye irritation. Causes severe skin burns and eye damage. Causes skin irritation. Harmful if swallowed. Highly flammable liquid and vapour. May be corrosive to metals. May cause drowsiness or dizziness. 7 / 7