Christian Butzke Enology Professor.
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- Russell Cannon
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1 Christian Butzke Enology Professor
2 Emergency Procedures Confined Space and CO 2 Lockout Procedures Ladders/Forklifts Personal Protection Chemicals Compressed Gases and Ozone
3 EMERGENCY PROCEDURES: A. In case of an emergency, call: B. Procedures in case of fire (or explosion) C. Fire protection D. Reporting accidents CONFINED SPACE SAFETY: A. Entry permits B. Tank entry C. Press entry LOCKOUT PROCEDURES: A. Tanks B. Destemmer-crusher C. Bottling line LADDER SAFETY A. General B. Placement C. Securing D. Use PERSONAL PROTECTION A. Eye protection B. Respiratory protection C. Skin and body protection D. Hearing protection E. Safe lifting and back injury prevention CHEMICAL ANALYSIS, HANDLING, STORAGE AND DISPOSAL A. Chemical hygiene plan (Right-to-Know) B. Chemical analysis methods C. Stability test methods D. Material safety data sheets (MSDS) COMPRESSED GASES, HANDLING AND STORAGE
4 Emergency Procedures Confined Space and CO 2 Lockout Procedures Ladders Personal Protection Chemicals Compressed Gases and Ozone
5 Emergency Procedures Leave the area of immediate danger. Be sure that all other people are out. Close the doors. Activate the nearest building fire alarm. Dial Stand by to advise the Fire Department when they arrive. The Fire Department should be advised if chemicals used in the winery are involved in the fire and of the location of the Material Safety Data Sheets (MSDS).
6 When wines are too hot Fire Safety
7 Fire Safety Pure Alcohol Flash point: 52 F Boiling point: 172 F Autoignition: 792 F Vapor Density: 1.6 = heavier than air! Flammable limits in air: 3% ( 60 g/m 3 ) - 19% (370 g/m 3 )
8 T (ºF) Fire Safety Flash Point of Wine 100ºProof %w/w
9 Fire Safety San Francisco April 18,1906
10 Emergency Procedures Confined Space and CO 2 Lockout Procedures Ladders Personal Protection Chemicals Compressed Gases and Ozone
11 Confined Space and CO 2 Carbon Dioxide CO 2 10% CO 2 in air => unconsciousness <19.5% oxygen = oxygen-deficient <18% oxygen => unconsciousness Vapor Density: 1.5 = heavier than air Normal air: 20.9% O 2 and 0.03% CO 2
12 Must CO 2 Confined Space and CO 2
13 Confined Space Labels on EVERY Tank + Press
14 Confined Space
15 Confined Space
16 Confined Space
17 Confined Space Label space with warning signs Measure carbon dioxide and oxygen Lock-out mechanical equipment Sign/time/date entry permit forms Maintain proper ventilation Never enter alone w/out outside guards Wear safety harness on lifeline Do not climb in to rescue
18 Both manholes are fully open. Confined Space Tank Entry A box fan has been placed over the top manhole and is turned on to ventilate the tank by blowing air INTO it and OUT the bottom manhole. The fan has been running for at least five minutes prior to tank entry. The tank shall only be entered and exited through the bottom manhole. The person entering the tank is wearing a safety harness and lanyard/lifeline connected to it. Two people are present in the immediate outside area of the tank to pull the person inside to safety if necessary. No second person is allowed to enter the tank even in case of an emergency.
19 Confined Space CO 2 + O 2 Harness + Lifeline
20
21 Press = Confined Space
22 Emergency Procedures Confined Space and CO 2 Lockout Procedures Ladders Personal Protection Chemicals Compressed Gases and Ozone
23 Lockout Procedures
24 Lockout Procedures
25 Emergency Procedures Confined Space and CO 2 Lockout Procedures Ladder/Forklift Personal Protection Chemicals Compressed Gases
26 Ladders unsecured
27 Ladders secured
28 Emergency Procedures Confined Space and CO 2 Lockout Procedures Ladders Personal Protection Chemicals Compressed Gases and Ozone
29 Eye Protection
30
31 Emergency shut-off Destemmer-Crusher
32 Repetitive Motion Disorders
33 Personal Protection Ouch! Thanks for OSHA!
34 Fork Lift Safety
35 Fork Lift Safety
36 Fork Lift Safety
37 Personal Protection
38 Personal Protection Employee Training
39 Personal Protection
40 Emergency Procedures Confined Space and CO 2 Lockout Procedures Ladders Personal Protection Chemicals Compressed Gases and Ozone
41 Chemicals Material Safety Data Sheet (MSDS)
42 WINERY SAFETY MANUAL SAKONNET VINEYARDS Material Safety Data Sheets Chemicals Material Safety Data Sheets (MSDS) + Right-to-Know Ascorbic Acid Bentonite Bi-Brite Buffer ph 4 Buffer ph 7 Citric Acid Copper Sulfate Cupric Sulfate Enoferm Alpha Ethyl Alcohol Hydrochloric Acid Instant Dry Yeast Iodine Potassium Bitartrate Potassium Carbonate Potassium Hydrogen Phthalate Potassium Metabisulfide Potassium Sorbate Reagent Alcohol Sanitary Spray Lube Sodium Thiosulfate Starch Indicator Sulfuric Acid Tartaric Acid ZEP I-DINE ZEP MW Grease ZEP Super Penetrant ZEP Trifoam
43 Chemicals Container labeling
44 Emergency Procedures Confined Space and CO 2 Lockout Procedures Ladders Personal Protection Chemicals Compressed Gases and Ozone
45 Compressed Gases Chained to wall Chained to cart Move unchained only with cap on X
46 Ozone O O Colorless toxic gas Very powerful oxidizing agent Irritant via inhalation and to skin/eyes Odor threshold ppm Half life: "20 minutes" only in water but 3 days in air Vapor density: 1.6 = heavier than air Solubility in water: 10 32ºF 1 to 5 mg/l against wine microbes? O
47 Ozone Terms such as "energized oxygen" or "fresh air smell" suggest that ozone is a healthy kind of oxygen. Ozone is a toxic gas with vastly different chemical and toxicological properties from oxygen.
48 Ozone RECOMMENDED RESPIRATOR: When working with this chemical, wear a NIOSH-approved full face positive pressure supplied-air respirator or a self-contained breathing apparatus (SCBA).
49 No SCUBA in the Chambourcin!
50 Ozone
51 Ozone High concentrations of ozone can cause: Shortness of breath Coughing Wheezing Headaches Nausea Eye and throat irritation Lung damage Reduced athletic performance Weakened immune system
52 Ozone What is the American Conference of Governmental Industrial Hygienists' (ACGIH) recommended exposure limit for ozone? TIME-WEIGHTED AVERAGE (TLV-TWA): Heavy work 0.05 ppm 0.10 mg/m 3 Moderate work 0.08 ppm 0.16 mg/m 3 Light work 0.10 ppm 0.20 mg/m 3
53 Ozone The National Institute of Occupational Safety and Health (NIOSH) recommends an upper limit of 0.10 ppm NOT to be exceeded at ANY time
54 Ozone Canadian Centre for Occupational Health and Safety (CCOHS) Is the odor of ozone reliable as a warning? NOT RELIABLE - variations in the detection range reported and olfactory fatigue occurs.
55 Ozone What ozone levels are considered by the U.S. Environmental Protection Agency (EPA) to be "unhealthful" and to exceed the National Ambient Air Quality Standard? ppm for 1 hour ppm for 8 hours
56 Ozone Materials damaged by ozone: Rubber Cotton Nylon Dyes & paint
EMERGENCY PHONE: or (651) (24 hours)
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Safety Data Sheet. Revision Date: December, 18 th 2017 Issue Date: May 28, Product and Company Identification
1. Product and Company Identification Product Name: S-5425A Product Description: Bar Compound All Types Company Address: Contact Information: Schaffner Manufacturing Co. Inc. Telephone: 412-761-9902 21
SAFETY DATA SHEET. P.O. Box 4272 CHEMTREC: (800) Houston, TX KRONOS: (800) Customer Service: (800)
2. PRODUCT COMPOSITION Product Classification: Chemical Intermediate. Component(s) C.A.S. No. Percent Sulfuric Acid Titanium Dioxide 7664-93-9 13463-67-7 3 29 3. HAZARD IDENTIFICATION Warning: Contact
MATERIAL SAFETY DATA SHEET
Natural Fiber Cleaner Liquid Date Revised: 07-09-2004 SECTION 1 MATERIAL AND MANUFACTURER IDENTIFICATION Product Identifier: Natural Fiber cleaner liquid MANUFACTURER CTI (Chemical Technologies International
EUCON CIA - BULK GALLONS Version 2. Print Date 09/13/2008 REVISION DATE: 09/12/2008
SECTION 1 - PRODUCT IDENTIFICATION Trade name : Product code : 019C 99 COMPANY : Euclid Chemical Company 19218 Redwood Road Cleveland, OH 44110 Telephone : 1-800-321-7628 Emergency Phone: : U.S. only:
SIG SOUTHERN INDUSTRIAL GAS SDN BHD
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EMERGENCY PHONE: or (651) (24 hours)
Material Safety Data Sheet Copyright, 2010, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1)
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Trade Names. No information on significant adverse effects. No information on significant adverse effects
Material Safety Data Sheet 5%, Balance Arcet, Inc 1700 CHAMBERLAYNE AVE RICHMOND, VA 23222 phone: (804) 644-4521 fax: (804) 788-8904 http://www.arcet.com Section 1: Product and Company Identification Arcet,
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Page Number: 1 of 5 SECTION 1 - PRODUCT AND COMPANY INFORMATION Product Name: Rockspin 22 CAS Number N/A - Mixture Hazard Rating: Health: 1 Fire: 1 Reactivity: 0 PPI: Company Identification: Rock Valley
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Material Safety Data Sheet For: Die Set Lube MSDS I.D. #135 P/N Quart Size. MSDS I.D. #136 P/N Gallon Size
Material Safety Data Sheet For: Die Set Lube 2696 MSDS I.D. #135 P/N 390001520 Quart Size MSDS I.D. #136 P/N 390002520 Gallon Size MSDS I.D. #137 P/N 390002522 15 Gallon Size MSDS I.D. >#138 P/N 390002521
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REVISION DATE: 04/17/2012 DATE PRINTED: 04/17/2012 1. CHEMICAL PRODUCT PRODUCT NAME: PRODUCT CODE: 118083 MATERIAL SAFETY DATA SHEET ULTRA STRIP NFPA/HMIS HAZARD CODES(minimal=0; slight=1; moderate=2;
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MATERIAL SAFETY DATA SHEET Artisan Penetrating Stone Sealer & Oil Repellent SECTION 1 PRODUCT NAME AND COMPANY IDENTIFICATION
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SECTION 1 - PRODUCT IDENTIFICATION Trade name : Product code : 157W 55 COMPANY : Euclid Chemical Company 19218 Redwood Road Cleveland, OH 44110 Telephone : 1-800-321-7628 Emergency Phone: : U.S. only:
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Ingredient CAS Number Weight % ACGIH TLV PEL STEL Calcium Hypochlorite % Not Established Not Established
Page 1 of 5 MSDS Document Product 1. Chemical Product and Company Identification Product Manufacturer Haviland Consumer Products, Inc. 421 Ann Street N.W. Grand Rapids, MI 49504 Phone Number (616) 361-6691
CLEARSEAL WB 150 Version 2.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012
SECTION 1 - PRODUCT IDENTIFICATION Trade name : Product code : THCWB150D55 COMPANY : Euclid Chemical Company 19218 Redwood Road Cleveland, OH 44110 Telephone : 1-800-321-7628 Emergency Phone: : U.S. only:
Material Safety Data Sheet acc. to ISO/DIS Printing date 09/30/2003 Reviewed on 09/30/2003
Page 1/6 1 Identification of substance Product details Application of the substance / the preparation: Soldering flux Manufacturer/Supplier: Northrop Grumman Kester Tel.(847) 297-1600 515 E. Touhy Ave.
HAZARDOUS INGREDIENTS CAS No. W?W % OSHA PEL LD50 LC50
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Material Safety Data Sheet
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