MATERIAL SAFETY DATA SHEET

Transcription

1 PAGE 1/ 5 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME PRODUCT DESCRIPTION UMEGUARD SX HS, BASE Modified Anticorrosive Epoxy Paint COMPANY IDENTIFICATION COMPANY NAME ADDRESS CHUGOKU SAMHWA PAINTS Ltd. 972, Toerae-ri, Hallim-myeon, Gimhae-si, Gyeongnam, Korea EMERGENCY TELEPHONE NUMBER COMPOSITION ON HAZARDOUS INGREDIENTS Chemical Name CAS NO. Wt. (%) Remark Titanium oxide(tio2) Silica. Crystalline.quarz Phenol, 4,4 -(1-methylethylidene)bis-, polymer with(chloromethyl)oxirane Benzene, dimethyl Benzene, ethyl Butanone Pentanone, 4-methyl HAZARDS IDENTIFICATION 1. EMERGENCY OVERVIEW Flammable Coating having solvent odor. May cause eye,skin and respiratory irritation. May cause drowsiness by high vapor concentrations. This product has a mutagenicity hazard. 2. POTENTIAL HEALTH EFFECTS 1) EYE CONTACT: May cause severe eye irritation. 2) SKIN CONTACT: May cause irritation or allergic reaction by prolonged contact 3) INGESTION: Harmful, or fatal if swallowed much. 4) INHALATION : Vapor material may be rapidly absorbed through the lung. Repeated exposure in the vapor may cause damage to liver and kidneys. Overexposure may cause central nervous system depression, including drowsiness and unconsciousness.

2 PAGE 2/ 5 4. FIRST AID MEASURES 1. EYE CONTACT: Immediately flush with water for at least 15 minuets. It is also recommended to have medical personal check your eyes afterwards. 2. SKIN CONTACT: Remove severely contaminated clothing, immediately and Flush skin with large amounts of water until irritation subside. If irritation persists, get medical attention. 3. INHALATION : Remove to fresh air and if not breathing, give mouse to mouse resuscitation. If breathing is difficult, give oxygen. Call a physician. 4. INGESTION : Do not induce vomiting. Keep rest. Get prompt medical attention. 5. FIRE FIGHTING MEASURES Flash Point( ) 24 Ignition Point( ) 529 Flammable Limits LFL(%) 1.1 Flammable Limits UFL(%) GENERAL HAZARD Flammable Liquid; may release flammable vapors when temperatures are at or over the flash point. Toxic gases will form upon combustion. 2. FIRE FIGHTING INSTRUCTIONS Allow fire to burn out under controlled conditions or Fight fire from a safe distance, extinguishing with foam, dry chemical, carbon dioxide or dry sand. Do not use directly WATER to extinguish to avoid the danger of fire spread that may be caused by floating flammable material on the water surface. But if possible to do without hazard, use water spray to cool fire exposed surface and isolate material from heat. 3. EXTINGUISHING MEDIA Carbon dioxide, foam, dry chemical or dry sand 4. FIRE FIGHTING EQUIPMENT Respiratory and eye protection required for fire fighting personnel. Full protective equipment(bunker Gear) and a self-contained breathing apparatus (SCBA) should be used for all indoor fires and significant outdoor fires. For small outdoor fires, which may easily be extinguished with a portable fire extinguisher, use of an SCBA may not be required. 5. HAZARDOUS COMBUSTION PRODUCT Smoke, fumes and oxide of carbon

3 PAGE 3/ 5 6.ACCIDENTAL RELEASE MEASURES 1. Provide maximum ventilation. 2. Personal protection should be used. 3. Remove all sources of ignition. 4. Contain spilled liquid with sand or earth. 5. Avoid runoff into storm sewers and ditches which lead to waterways. 6. Take up spilled material with sawdust, vermiculite or other absorbent material and place in a disposal container. 7. HANDLING AND STORAGE 1. Handling in sufficiently ventilated areas. 2. Handling in closed areas requires local ventilation. 3. Keep container closed. Loosen closure cautiously before opening. 4. Store in a cool, well ventilated place away from incompatible materials. 5. Keep away from heat, sparks and flame. Protect material from direct sunlight. 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION 1. RESPIRATORY PROTECTION : In confined or poorly ventilated areas, use an approved positive pressure self-contained breathing apparatus. 2. SKIN PROTECTION : Use imperishable gloves to this material, such as made from butyl rubber. 3. EYE PROTECTION : Use safety glasses. Wearing goggles is better. 4. EXPOSURE GUIDELINE : Confer No.11 (TOXICOLOGICAL INFORMATION)

4 PAGE 4/ 5 9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE : Liquid Paint ODOR : Solvent Smell PH : None MELTING POINT( ) None BOILING POINT ( ) : SOLUBILITY : Insoluble in water VAPOR PRESSURE(20 ) : 1333 Pa VISCOSITY(25 ) : 60-80Poise SPECIFIC GRAVITY(20/20 ) : DENSITY(Vapor) : Heavy than air MOLECULAR WEIGHT : None Etc. : 10. STABILITY AND REACTIVITY 1. Stability(Conditions to avoid) : This product is considered stable under normal and anticipated storage and handling conditions. But avoid open flame, electrical equipment sparks and other sources of ignition which induce fire. 2. Incompatibility(Specific materials to avoid) : Acid and alkali which contact may cause reaction.(polymerization with heat) 11. TOXICOLOGICAL INFORMATION CHEMICAL NAME TLV LD 50 (Mouth) LD50 (Skin) LC50 (Inhalation) Titanium oxide(tio2) 10mg/m3 None None None Silica. Crystalline.quarz 0.05mg/m3 None None None Phenol, 4,4 -(1-methylethylidene)bis-, polymer with(chloromethyl)oxirane None None 11,400mg/kg None Benzene, dimethyl- 100ppm 4,300mg/kg 5,000mg/kg 3,460ppm Benzene, ethyl- 100ppm 3,500mg/kg 17,800mg/kg None 2-Butanone 200ppm 2,737mg/kg 13,000mg/kg None 2-Pentanone, 4-methyl- 50ppm 2,080mg/kg None 32,000ppm 1. IRRITATION: Skin or eye irritation may be caused by prolonged or repeated contact with this material, or by overexposure of the vaporized materials. 2. CARCINOGENICITY : May be no.

5 PAGE 5/ ECOLOGICAL INFORMATION This has the potential to be toxic in environments. Do not leak or waste in the environments without adequate waste disposal handling. 13. DISPOSAL CONSIDERATION Empty containers and material (including waste thinner for cleaning and flushing of containers or application equipment ) must be disposed in accordance with government and local environmental control regulations. Do not heat or cut empty container with electric or gas torch because due to residue. 14. TRANSPORT INFORMATION For safety of shipping : Flammable liquid (class 3.2) CLASS 3, UN1263, PAINT, PGⅢ 15. REGULATORY INFORMATION 1. Precaution control act for toxic organic solvents 2. Occupational safety and health control act 3. Fire protection act 16. OTHER INFORMATION The information herein is given in good faith, but we cannot guarantee that these are the only hazards which exist. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution.