SAFETY DATA SHEET according to Regulation 1907/2006

Transcription

1 Section 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name 3201 Moxi 1.2. Relevant identified uses of the substance or mixture and uses advised against Use Automotive care products Uses advised against 1.3. Details of the supplier of the safety data sheet Manufacturer SILCO, D.O.O. Šentrupert 5 a, 3303 Gomilsko, Slovenia Tel: Fax: n.cvilak@silcoautomotive.com 1.4. Emergency telephone number Emergency 112 Supplier Section 2. Hazards identification 2.1. Classification of the substance or mixture: Classification according to Reg. 1272/2008 This mixture is not classified as hazardous according to Regulation (EC) No. 1272/ Label elements : Classification according to Reg. 1272/2008 Contains 1,2Benzisothiazol3(2H)one. May produce an allergic reaction. Safety data sheet available on request Other hazards: 1/10

2 Section 3. Composition/information on ingredients 3.1. Substances For mixtures see Mixtures CAS No Chemical name Quantity ES No Index No REACH No aliphatic hydrocarbons, C11C13, isoalkanes, (<0,1 % Benzene) 10 < 15 % Asp. Tox. 1; H304 EUH white mineral oil ( petroleum ) 1 < 5 % Asp. Tox. 1; H304 Full text of H and EUH statements: see section 16. Section 4. First aid measures 4.1. Description of first aid measures Inhalation Remove patient to fresh airmove out of dangerous area. If difficulties with breathing do not stop, search for medical help. Skin contact After contact with skin, wash immediately with polyethylene glycol, followed by plenty of water. Take off immediately all contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention Eye contact Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Check for and remove any contact lenses. If irritation does not stop, seek professional medical treatment! Ingestion Rinse mouth immediately and drink plenty of water Most important symptoms and effects, both acute and delayed available 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically 2/10

3 Section 5. Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Coordinate firefighting measures to the fire surroundings Special hazards arising from the substance or mixture Nonflammable 5.3. Advice for firefighters Protective actions In case of fire or heating do not breathe fumes/vapours. Cool exposed containers with water spray. Special protective equipment for firefighters Firefighters should wear appropriate protective clothing for firefighters (including helmets, protective boots and gloves) (EN 469) and selfcontained breathing apparatus (SCBA) with a full facepiece (EN 137). Additional information Contaminated firefighting water must be disposed of in accordance with the regulations; do not allow to reach the sewage system. Section 6. ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Use personal protective equipment Environmental precautions Do not allow product to reach water/drains/sewage systems or permeable soil. If accidental entry into water or ground occurs, inform responsible authorities Methods and material for containment and cleaning up Take up mechanically. Treat the recovered material as prescribed in the section on waste disposal Reference to other sections Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section 13 6 Section 7. Handling and storage 7.1. Precautions for safe handling No special measures are necessary 3/10

4 7.2. Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep tightly closed. Advice on storage compatibility No speacial measures are necessary 7.3. Specific end use(s) Automotive car products Section 8. Exposure controls/personal protection 8.1. Control parameters Exposure limits (EH40) CAS No Substance ppm mg/m 3 Fibres/ml Category Origin Aluminium oxides, respirable dust Glycerol, mist 4 10 TWA (8h) STEL (15 min) TWA (8h) STEL (15min) white mineral oil ( petroleum ) 5 Consumer DNEL, long term Inhalation Systemic 160mg/m glycerol Consumer DNEL, longterm Inhalation Local 33mg/m Exposure controls WEL WEL WEL WEL Protective and hygiene measures Take off contaminated clothing. Wash hands before breaks and after work. When using do not eat or drink. Eye and face protection Wear safety glasses with side shields (EN 166) against possible splashes into the eyes. Hand protection Protective gloves (EN 374). The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. Follow the manufacturer s instructions for use, storage, maintenance and glove changing. In case of damage or at the first signs of wear and tear, change the gloves immediately. 4/10

5 Skin protection Wear suitable protective clothing. Respiratory protection In case of inadequate ventilation wear respiratory protection. Section 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Physical state: Paste Colour: white Odour: characteristic Important health, safety and environmental information ph 7,8 at 20 C Melting point Boiling point/boiling range 100 C Flashpoint > 61 C Ignition temperature >200 C Explosion limits (vol%) Vapour pressure 23 hpa at 20 C Vapour density Density Density: 1,07 g/cm 3 at 20 C Solubility Water: 367 g/l Partition coefficient n octanol/water (log Kow) Autoignition temperature Decomposition temperature Viscosity (20 C) dynamic: mpas Explosive properties Product is not self igniting. Product is not explosive. Oxidising properties 9.2. Other information Solid content Not determined 5/10

6 Section 10. STABILITY AND REACTIVITY Reactivity Chemical stability Product is stable under normal conditions according to handling and storage Possibility of hazardous reactions The product is stable under recommended storage and handling conditions Conditions to avoid Incompatible materials Hazardous decomposition products No known hazardous decomposition products. Section 11. Toxicological information Information on toxicological effects Acute toxicity CAS No Chemical name Exposure routes Method dose Species Source Aliphatic hydrocarbons, C11C13, isoalkanes (<0,1 % Benzene) Oral LD50 Rat OECD mg/kg Dermal LD mg/kg Rat OECD 402 Inhalative (4h) vapour LD Rat OECD White mineral oil (petroleum) Oral LD50 Rat ECHA >5000mg/kg Dermal LD50 >5000mg/kg Rabbit ECHA Inhalative (4h) vapour LD50 >5,09 Rat ECHA Irritation and corrosivity 6/10

7 Sensitising effects STOTsingle exposure Severe effects after repeated or prolonged exposure Carcinogenic/mutagenic/toxic effects for reproduction Aspiration hazard Additional information on tests This mixture is classified as not hazardous according to regulation (EC) 1272/2008 [CLP]. Section 12. Ecological information Toxicity The product is not: Ecotoxic. CAS No Chemical name Aquatic toxicity Method Dose [h] / [d] Species Source Aliphatic hydrocarbons, C11C13, isoalkanes (<0,1 % Benzene) Acute fish toxicity LC50 >1000 Acute algae toxicity ErC50 >1000 Acute crustacea toxicity EC50 >1000 Algea toxicity NOEC 1000 White mineral oil (petroleum) Acute fish toxicity LC50 >1000 Acute crustacea toxicity EC50 >100 Algea toxicity NOEC >= h Oncorhynchus mykiss (rainbow trout) 72 h Pseudokirchneriella subcapitata 48 h Daphnia magna (Big water flea) 3 d Pseudokirchneriella subcapitata 96 h Leuciscus idus (golden orfe) 48 h Daphnia magna (Big water flea) 72 d Pseudokirchneriella subcapitata ECHA dossier ECHA dossier ECHA dossier ECHA dossier ECHA dossier Persistence and degradability The product has not been tested 7/10

8 CAS No Chemical name Method Value d source Evalvaciji Aliphatic hydrocarbons, C11C13, isoalkanes (<0,1 % Benzene) OECD 301 F 31,3 % 28 ECHA Evidence for inherent biodegradability White mineral oil (petroleum) OECD 301 F 31 % 28 ECHA Not readily biodegradable (according to OECD criteria) Bioaccumulative potential The product has not been tested CAS No Chemical name Log Pow White mineral oil (petroleum) > Mobility in soil Known or predicted distribution to environmental compartments Surface tension Adsorption/Desorption Results of PBT and vpvb assessment No evaluation Other adverse effects Additional information For product Harmful to aquatic life with long lasting effects. Do not allow to enter ground water, water course or sewage system. Section 13. Disposal considerations Waste treatment methods Product / Packaging disposal Waste chemical Disposal must be made according to official regulations: to leave it to authorized collector/remover/transformer of hazardous waste. Do not dispose together with household garbage. Do not allow product to reach drans/sewage systems. 8/10

9 Packaging Completely emptied containers leave to approved waste disposal authorities in charge. Handle contaminated packages in the same way as the substance itself. Section 14. Transport information UN number not applicable UN proper shipping name Not dangerous according to transport regulations Transport hazard class(es) not applicable Packing group not applicable Environmental hazards NO Special precautions for user not applicable Transport in bulk according to Annex II of Marpol and the IBC Code not applicable Section 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Chemical Safety Assessment No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier. 9/10

10 Section 16. Other information Abbreviations and acronyms ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service LC50: Lethal concentration, 50% LD50: Lethal dose, 50% Relevant H and EUH statements (number and full text) May be fatal if swallowed and enters airways. Repeated exposure may cause skin dryness or cracking. Contains 1,2Benzisothiazol3(2H)one. May produce an allergic reaction. Safety data sheet available on request. The information of this SDS is based on the present state of our knowledge and meets the requirements of EU and nationallaws. The user s working conditions however, are beyond our knowledge and control. The product is not to be used for purposesother than those specified under section 1 without a written permission. It remains the responsibility of the user to ensure thatthe necessary steps are taken to meet the laws and regulations. Handling of the product may only be done by people above 18 years of age, who are satisfactorily informed of how to do the work, the hazardous properties and necessary safety precautions.the information given in this SDS is to describe the product only in terms of health and safety requirements and should not,therefore, be construed as guaranteeing specific properties. 10/10