NS Series Retarder Safety Data Sheet
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1 Date of issue: 2016/12/16 Revision date: 2017/02/14 Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixtures Product name : NS Series Retarder Product code : N665 S Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Use of the substance/mixture : Professional use : Retarder Uses advised against 1.3. Details of the supplier of the safety data sheet GL Specialized Inks (Pty) Ltd 8 Hawthorne Place Mahogany Ridge Westmead Durban Telephone: +27 (0) Fax: +27 (0) After hours: (Jay) (Julie) jay@gl-inks.com 1.4. Emergency telephone number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Acute toxicity (dermal), Category 4 H312 Full text of H statements : see section 16 Adverse physicochemical, human health and environmental effects Harmful in contact with skin Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) GHS07 : Warning : 2-butoxyethyl acetate, butylglycol acetate : H312 - Harmful in contact with skin : P280 - Wear eye protection, protective clothing, protective gloves P302+P352 - IF ON SKIN: Wash with plenty of soap and water P312 - Call a POISON CENTER or doctor if you feel unwell P362+P364 - Take off contaminated clothing and wash it before reuse P501 - Dispose of contents/container to hazardous or special waste collection point, in 2017/03/06 EN (English) 1/6
2 accordance with local, regional, national and/or international regulation 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] 2-butoxyethyl acetate, butylglycol acetate (CAS-No.) (EC-No.) (EC Index-No.) Full text of H-statements: see section 16 >= 80 Acute Tox. 4 (Inhalation), H332 Acute Tox. 4 (Dermal), H312 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Call a poison center or a doctor if you feel unwell. : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. Take off contaminated clothing. : Rinse eyes with water as a precaution. : Call a poison center or a doctor if you feel unwell Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide Special hazards arising from the substance or mixture Hazardous decomposition products in case of : Toxic fumes may be released. fire 5.3. Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Ventilate spillage area. Avoid contact with skin, eyes and clothing. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up : Take up liquid spill into absorbent material. Other information : Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section /03/06 EN (English) 2/6
3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Do not get in eyes, on skin, or on clothing. Wear personal protective equipment. : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 2-butoxyethyl acetate, butylglycol acetate ( ) : Store in a well-ventilated place. Keep cool. EU Local name 2-Butoxyethyl acetate EU IOELV TWA (mg/m³) 133 mg/m³ EU IOELV TWA (ppm) 20 ppm EU IOELV STEL (mg/m³) 333 mg/m³ EU IOELV STEL (ppm) 50 ppm EU Notes Skin United Kingdom Local name 2-Butoxyethyl acetate United Kingdom WEL TWA (mg/m³) 133 mg/m³ United Kingdom WEL TWA (ppm) 20 ppm United Kingdom WEL STEL (mg/m³) 332 mg/m³ United Kingdom WEL STEL (ppm) 50 ppm United Kingdom Remark (WEL) Sk (Can be absorbed through the skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity) 8.2. Exposure controls Appropriate engineering controls: Ensure good ventilation of the work station. Personal protective equipment: Avoid all unnecessary exposure. Protective goggles. Gloves. Protective clothing. Hand protection: Protective gloves Eye protection: Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment Environmental exposure controls: Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : Colourless. Odour : Fruity. slight. 2017/03/06 EN (English) 3/6
4 Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point : 0,03 2-butoxyethyl acetate : Auto-ignition temperature : 340 C Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Lower explosive limit (LEL) Upper explosive limit (UEL) 9.2. Other information SECTION 10: Stability and reactivity Reactivity : 192,25 C 2-butoxyethyl acetate : 70,85 (70,85-87,85) C 2-butoxyethyl acetate : : 0,05 kpa 2-butoxyethyl acetate : 5,5 2-butoxyethyl acetate : 0,942 g/cm³ 2-butoxyethyl acetate : Not miscible. Soluble in water. : 0,88 vol % 2-butoxyethyl acetate : 8,54 vol % 2-butoxyethyl acetate The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Dermal: Harmful in contact with skin. ATE CLP (dermal) 1157,895 mg/kg bodyweight 2-butoxyethyl acetate, butylglycol acetate ( ) LD50 oral 1600 mg/kg bodyweight LD50 dermal Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity 1480 mg/kg bodyweight Reproductive toxicity STOT-single exposure STOT-repeated exposure 2017/03/06 EN (English) 4/6
5 Aspiration hazard SECTION 12: Ecological information Toxicity Ecology - general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment. 2-butoxyethyl acetate, butylglycol acetate ( ) LC50 fish 1 80 mg/l EC50 other aquatic organisms 1 37 mg/l EC50 waterflea (48 h) EC50 other aquatic organisms 2 > 500 mg/l IC50 algea (72 h) mg/l Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods Ecology - waste materials SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN : Dispose of contents/container in accordance with licensed collector s sorting instructions. : Avoid release to the environment. ADR IMDG IATA ADN RID UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards No supplementary information available Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport 2017/03/06 EN (English) 5/6
6 - Rail transport Transport in bulk according to Annex II of Marpol and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Germany VwVwS Annex reference 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling Denmark Class for fire hazard Store unit Classification remarks Recommendations Danish Regulation : Water hazard class (WGK) 1, low hazard to waters (Classification according to VwVwS, Annex 4) : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) : Class III-1 : 50 liter : Flammable according to the Danish Ministry of Justice; Emergency management guidelines for the storage of flammable liquids must be followed : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Full text of H- and EUH-statements: Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 H312 Harmful in contact with skin H332 Harmful if inhaled SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 2017/03/06 EN (English) 6/6
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