Page: 1/16 BASF Safety data sheet according to Regulation (EC) No. 1907/2006 Date / Revised: Version: 1.0 Product: Versamid Pur 1010

Transcription

1 Safety data sheet Page: 1/16 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Versamid Pur Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: resin 1.3. Details of the supplier of the safety data sheet Company: BASF SE Ludwigshafen GERMANY Contact address: BASF plc PO Box 4, Earl Road, Cheadle Hulme, Cheadle, Cheshire SK8 6QG, UNITED KINGDOM Telephone: address: 1.4. Emergency telephone number International emergency number: Telephone: SECTION 2: Hazards Identification 2.1. Classification of the substance or mixture According to Regulation (EC) No 1272/2008 [CLP] Flam. Liq. 2 Eye Dam./Irrit. 1 STOT SE 3 (Vapours may cause drowsiness and dizziness.)

2 Page: 2/16 According to Directive 67/548/EEC or 1999/45/EC Possible Hazards: Risk of serious damage to eyes. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. Highly flammable. For the classifications not written out in full in this section the full text can be found in section Label elements Globally Harmonized System, EU (GHS) Pictogram: Signal Word: Danger Hazard Statement: H318 H225 H336 Causes serious eye damage. Highly flammable liquid and vapour. May cause drowsiness or dizziness. Precautionary Statements (Prevention): P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P280f Wear protective gloves and eye/face protection. P271 Use only outdoors or in a well-ventilated area. P243 Take precautionary measures against static discharge. P241 Use explosion-proof electrical/ventilating/lighting/equipment. P260i Do not breathe dust/gas/mist/vapours. P240 Ground/bond container and receiving equipment. P242 Use only non-sparking tools. Precautionary Statements (Response): P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P370 + P In case of fire: Use water spray, dry powder, foam or carbon dioxide for extinction. Precautionary Statements (Storage):

3 Page: 3/16 P233 Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection point. Labeling of special preparations (GHS): Repeated exposure may cause skin dryness or cracking. May produce an allergic reaction. Contains: ISOPHORONEDIAMINE According to Directive 67/548/EEC or 1999/45/EC EEC Directives Hazard symbol(s) F Highly flammable. Xi Irritant. R-phrase(s) R11 R41 R66 R67 Highly flammable. Risk of serious damage to eyes. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. S-phrase(s) S7 Keep container tightly closed. S16 Keep away from sources of ignition - No smoking. S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28.2 After contact with skin, wash immediately with plenty of water. S37/39 Wear suitable gloves and eye/face protection. 67 Vapours may cause drowsiness and dizziness. The product contains: ISOPHORONEDIAMINE May produce an allergic reaction Other hazards According to Regulation (EC) No 1272/2008 [CLP] No specific dangers known, if the regulations/notes for storage and handling are considered.

4 Page: 4/16 If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture. SECTION 3: Composition/Information on Ingredients 3.1. Substances Not applicable 3.2. Mixtures Chemical nature Polymer solution in organic solvent of: polyurethane Hazardous ingredients (GHS) according to Regulation (EC) No. 1272/2008 propan-1-ol; n-propanol Content (W/W): >= 20 % - <= 30 % CAS Number: EC-Number: REACH registration number: INDEX-Number: Flam. Liq. 2 Eye Dam./Irrit. 1 STOT SE 3 (drowsiness and dizziness) H225, H318, H336 propyl acetate Content (W/W): >= 30 % - <= 50 % CAS Number: EC-Number: REACH registration number: INDEX-Number: Flam. Liq. 2 Eye Dam./Irrit. 2 STOT SE 3 (drowsiness and dizziness) H225, H319, H336 3-aminomethyl-3,5,5-trimethyl-cyclohexylamine Content (W/W): <= 0.2 % CAS Number: EC-Number: REACH registration number: INDEX-Number: Acute Tox. 4 (oral) Acute Tox. 4 (dermal) Skin Corr./Irrit. 1B Skin Sens. 1 Aquatic Chronic 3 H314, H312, H302, H317, H412 Hazardous ingredients according to Directive 1999/45/EC

5 Page: 5/16 propan-1-ol; n-propanol Content (W/W): >= 20 % - <= 30 % CAS Number: EC-Number: REACH registration number: INDEX-Number: Hazard symbol(s): F, Xi R-phrase(s): 11, 41, 67 propyl acetate Content (W/W): >= 30 % - <= 50 % CAS Number: EC-Number: REACH registration number: INDEX-Number: Hazard symbol(s): F, Xi R-phrase(s): 11, 36, 66, 67 3-aminomethyl-3,5,5-trimethyl-cyclohexylamine Content (W/W): <= 0.2 % CAS Number: EC-Number: REACH registration number: INDEX-Number: Hazard symbol(s): C R-phrase(s): 21/22, 34, 43, 52/53 For the classifications not written out in full in this section, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, the full text is listed in section 16. SECTION 4: First-Aid Measures 4.1. Description of first aid measures Remove contaminated clothing. If inhaled: If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention. On skin contact: Wash thoroughly with soap and water. On contact with eyes: Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. On ingestion: Rinse mouth and then drink plenty of water.

6 Page: 6/ Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known Indication of any immediate medical attention and special treatment needed Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. SECTION 5: Fire-Fighting Measures 5.1. Extinguishing media Suitable extinguishing media: dry powder, foam 5.2. Special hazards arising from the substance or mixture harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire Advice for fire-fighters Special protective equipment: Wear a self-contained breathing apparatus. Further information: The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations. SECTION 6: Accidental Release Measures 6.1. Personal precautions, protective equipment and emergency procedures Use personal protective clothing. Breathing protection required Environmental precautions Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater Methods and material for containment and cleaning up For large amounts: Pump off product. For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations Reference to other sections Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.

7 Page: 7/16 SECTION 7: Handling and Storage 7.1. Precautions for safe handling Ensure thorough ventilation of stores and work areas. Protection against fire and explosion: Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy Conditions for safe storage, including any incompatibilities Further information on storage conditions: Stir before use. Avoid direct sunlight. Keep away from heat. Protect from temperatures above: 40 C 7.3. Specific end use(s) For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed. SECTION 8: Exposure Controls/Personal Protection 8.1. Control parameters Components with occupational exposure limits : propyl acetate STEL value 250 ppm (WEL/EH 40 (UK)) General Prohibitions/Restrictions: 849 mg/m3 ; 200 ppm (WEL/EH 40 (UK)) : propan-1-ol; n-propanol TWA value 500 mg/m3 ; 200 ppm (WEL/EH 40 (UK)) STEL value 625 mg/m3 ; 250 ppm (WEL/EH 40 (UK)) Skin Designation (WEL/EH 40 (UK)) The substance can be absorbed through the skin Exposure controls Personal protective equipment Respiratory protection: Suitable respiratory protection for higher concentrations or long-term effect: Gas filter for gases/vapours of organic compounds (boiling point >65 C, e. g. EN Type A) Hand protection: Chemical resistant protective gloves (EN 374) Suitable materials short-term contact and/or splashes (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN 374) butyl rubber (butyl) mm coating thickness nitrile rubber (NBR) mm coating thickness Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.

8 Page: 8/16 temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing. Manufacturer's directions for use should be observed because of great diversity of types. Eye protection: Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield. General safety and hygiene measures Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is recommended. SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Form: Colour: Odour: Odour threshold: liquid colourless solvent-like Not determined due to potential health hazard by inhalation. ph value: not applicable Freezing point: not determined boiling temperature: approx. 97 C (1,013 hpa) Flash point: 13 C Evaporation rate: not determined Flammability: Highly flammable. Lower explosion limit: Ignition temperature: Vapour pressure: Density: Relative density: 0.9 Relative vapour density (air): For liquids not relevant for classification and labelling., The lower explosion point may be 5-15 C below the flash point. not determined 390 mbar approx. 0.9 g/cm3 (25 C) not determined Solubility in water: partly soluble Solubility (qualitative) solvent(s): organic solvents soluble Partitioning coefficient n-octanol/water (log Kow): not applicable for mixtures

9 Page: 9/16 Self ignition: not self-igniting The product has not been tested. Test type: Spontaneous selfignition at room-temperature. The statement has been derived from substances/products of a similar structure or composition. Thermal decomposition: not determined Viscosity, dynamic: , mpa*s (25.0 C) Explosion hazard: Based on the chemical structure there is no indicating of explosive properties. Fire promoting properties: not fire-propagating 9.2. Other information (N-114; Viskosität nach Brookfield) Hygroscopy: Surface tension: Grain size distribution: Non-hygroscopic not applicable The substance / product is marketed or used in a non solid or granular form. SECTION 10: Stability and Reactivity Reactivity No hazardous reactions if stored and handled as prescribed/indicated Chemical stability The product is stable if stored and handled as prescribed/indicated Possibility of hazardous reactions Reacts with strong oxidizing agents Conditions to avoid Avoid all sources of ignition: heat, sparks, open flame Incompatible materials Substances to avoid: strong oxidizing agents, strong bases, strong acids Hazardous decomposition products Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. SECTION 11: Toxicological Information Information on toxicological effects

10 Page: 10/16 Acute toxicity Experimental/calculated data: LD50 (oral): > 5,000 mg/kg The product has not been tested. The statement has been derived from the properties of the individual components. LC50 rat (by inhalation): 4 h not determined LD50 rat (dermal): not determined Irritation Experimental/calculated data: Skin corrosion/irritation rabbit: non-irritant The product has not been tested. The statement has been derived from the properties of the individual components. Serious eye damage/irritation rabbit: Irritant. The product has not been tested. The statement has been derived from the properties of the individual components. Respiratory/Skin sensitization Experimental/calculated data: Germ cell mutagenicity Assessment of mutagenicity: No data available concerning mutagenic effects. Carcinogenicity Assessment of carcinogenicity: Reproductive toxicity Assessment of reproduction toxicity: Developmental toxicity Assessment of teratogenicity: Specific target organ toxicity (single exposure)

11 Page: 11/16 Assessment of STOT single: Possible narcotic effects (drowsiness or dizziness). Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: Aspiration hazard No aspiration hazard expected. SECTION 12: Ecological Information Toxicity Toxicity to fish: LC50 > mg/l The product has not been tested. The statement has been derived from the properties of the individual components. Aquatic invertebrates: LC50 (48 h), daphnia not determined Aquatic plants: EC50 (72 h), algae not determined Chronic toxicity to fish: Chronic toxicity to aquatic invertebrates: Assessment of terrestrial toxicity: No data available concerning terrestrial toxicity Persistence and degradability Assessment biodegradation and elimination (H2O): Readily biodegradable (according to OECD criteria). Elimination information: The organic component of the product is biodegradable Bioaccumulative potential

12 Page: 12/16 Assessment bioaccumulation potential: The product has not been tested Mobility in soil Assessment transport between environmental compartments: Results of PBT and vpvb assessment According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH): The product does not contain a substance fulfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vpvb (very persistent/very bioaccumulative) criteria Other adverse effects Additional information Add. remarks environm. fate & pathway: Treatment in biological waste water treatment plants has to be performed according to local and administrative regulations. SECTION 13: Disposal Considerations Waste treatment methods Must be disposed of or incinerated in accordance with local regulations. The UK Environmental Protection (Duty of Care) Regulations (EP) and amendments should be noted (United Kingdom). This product and any uncleaned containers must be disposed of as hazardous waste in accordance with the 2005 Hazardous Waste Regulations and amendments (United Kingdom) The UK Environmental Protection (Duty of Care) Regulations (EP) and amendments should be noted (United Kingdom). This product and any uncleaned containers must be disposed of as hazardous waste in accordance with the 2005 Hazardous Waste Regulations and amendments (United Kingdom) Contaminated packaging: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents. SECTION 14: Transport Information

13 Page: 13/16 Land transport ADR UN number UN1993 UN proper shipping name: FLAMMABLE LIQUID, N.O.S. (contains N-PROPANOL, PROPYL ACETATE) Transport hazard class(es): 3 Packing group: II Environmental hazards: no Special precautions for user: Tunnel code: D/E SP 640 D RID UN number UN1993 UN proper shipping name: FLAMMABLE LIQUID, N.O.S. (contains N-PROPANOL, PROPYL ACETATE) Transport hazard class(es): 3 Packing group: II Environmental hazards: no Special precautions for SP 640 D user: Inland waterway transport ADN UN number UN1993 UN proper shipping name: FLAMMABLE LIQUID, N.O.S. (contains N-PROPANOL, PROPYL ACETATE) Transport hazard class(es): 3 Packing group: II Environmental hazards: no Special precautions for SP 640 D user: Transport in inland Not evaluated waterway vessel: Sea transport IMDG UN number: UN 1993 UN proper shipping name: FLAMMABLE LIQUID, N.O.S. (contains N-PROPANOL, PROPYL ACETATE) Transport hazard class(es): 3 Packing group: II Environmental hazards: no Marine pollutant: NO Special precautions for None known user:

14 Page: 14/16 Air transport IATA/ICAO UN number: UN 1993 UN proper shipping name: FLAMMABLE LIQUID, N.O.S. (contains N-PROPANOL, PROPYL ACETATE) Transport hazard class(es): 3 Packing group: II Environmental hazards: No Mark as dangerous for the environment is needed Special precautions for None known user: UN number See corresponding entries for UN number for the respective regulations in the tables above UN proper shipping name See corresponding entries for UN proper shipping name for the respective regulations in the tables above Transport hazard class(es) See corresponding entries for Transport hazard class(es) for the respective regulations in the tables above Packing group See corresponding entries for Packing group for the respective regulations in the tables above Environmental hazards See corresponding entries for Environmental hazards for the respective regulations in the tables above Special precautions for user See corresponding entries for Special precautions for user for the respective regulations in the tables above Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Regulation: Not evaluated Shipment approved: Not evaluated Pollution name: Not evaluated Pollution category: Not evaluated Ship Type: Not evaluated Further information This product is subject to the most recent edition of "The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations" and their amendments (United Kingdom).

15 Page: 15/16 SECTION 15: Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture If other regulatory information applies that is not already provided elsewhere in this safety data sheet, then it is described in this subsection. The data should be considered when making any assessment under the Control of Substances Hazardous to Health Regulations (COSHH), and related guidance, for example, 'COSHH Essentials' (United Kingdom). This product is classified under the Chemicals (Hazard Information and Packaging) Regulations, (CHIP) (United Kingdom). This product may be subject to the Control of Major Accident Hazards Regulations (COMAH), and amendments if specific threshold tonnages are exceeded (United Kingdom) Chemical Safety Assessment Chemical Safety Assessment not yet performed due to registration timelines SECTION 16: Other Information Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, if mentioned in section 2 or 3: F Highly flammable. Xi Irritant. C Corrosive. 11 Highly flammable. 41 Risk of serious damage to eyes. 67 Vapours may cause drowsiness and dizziness. 36 Irritating to eyes. 66 Repeated exposure may cause skin dryness or cracking. 21/22 Harmful in contact with skin and if swallowed. 34 Causes burns. 43 May cause sensitization by skin contact. 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Flam. Liq. Flammable liquid Eye Dam./Irrit. Serious eye damage/eye irritation STOT SE Specific target organ toxicity single exposure Acute Tox. Acute toxicity Skin Corr./Irrit. Skin corrosion/irritation Skin Sens. Skin sensitization Aquatic Chronic Hazardous to the aquatic environment - chronic H225 Highly flammable liquid and vapour. H318 Causes serious eye damage. H336 May cause drowsiness or dizziness. H319 Causes serious eye irritation. H314 Causes severe skin burns and eye damage.

16 Page: 16/16 H312 Harmful in contact with skin. H302 Harmful if swallowed. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. If you have any queries relating to this MSDS, it's contents or any other product safety related questions, please write to the following address: The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed. Vertical lines in the left hand margin indicate an amendment from the previous version.