MATERIAL SAFETY DATA SHEET

Transcription

1 MSDS No.: 813 Revision No.: 007 Revision Date: 04/12/00 Page: 1 of 6 Product name: Description: MATERIAL SAFETY DATA SHEET CC 410 EP Epoxy Skidproofer Part A - Polyamide hardener for anti-skid epoxy Supplier: Hilti, Inc. P.O. Box 21148, Tulsa, OK Emergency # (Chem-Trec.): (USA, PR, Virgin Islands, Canada); (other countries) INGREDIENTS AND EXPOSURE LIMITS Ingredients: CAS Number: TLV: PEL: STEL: Tetraethylene pentamine NE NE NE Ethylenediamine ppm 10 ppm NE Pentaethylene hexamine NE NE NE 1-methoxy-2-propanol ppm 100 ppm 150 ppm Diethylene triamine ppm (skin) NE NE Pigment varies with color NA NA NA Abbreviations: PEL = OSHA Permissible Exposure Limit. TLV = ACGIH Threshold Limit Value. STEL = Short Term Exposure Limit. NE = None Established. NA = Not Applicable. A "skin" notation indicates exposure should be controlled for the cutaneous routes including the mucous membranes, eyes, and skin. Airborne exposures as well as direct contact must be considered. PHYSICAL DATA Appearance: Low viscosity liquid. Odor: Amine odor Vapor Density: (air = 1) Not determined Vapor Pressure: Not applicable Boiling Point: 212 F VOC Content: 144 g/l Evaporation Rate: Not applicable Solubility in Water: Emulsifies Specific Gravity: 1.2 ph: Not established FIRE AND EXPLOSION HAZARD DATA Flash Point / Method: >200 F / Seta flash Flammable Limits: Not applicable Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: Carbon Dioxide, Dry Chemical, Foam, Water Fog. A self-contained breathing apparatus should be worn when fighting fires involving chemicals. Thermal decomposition and combustion products can be formed. REACTIVITY DATA Stability: Stable. Hazardous Polymerization: Will not occur. Incompatibility: Decomposition Products: Conditions to Avoid: Strong oxidizers, peroxides, acids. Thermal decomposition can yield CO, CO 2, aldehydes, and acids. Excessive heat for prolonged periods of time. Epoxy resins in uncontrolled amounts. HEALTH HAZARD DATA Known Hazards: Signs and Symptoms of Exposure: Carcinogenicity: Eye, skin, and respiratory irritation. Eye and skin irritation. Respiratory difficulty, nausea, dizziness. No ingredients are classified as a carcinogen by IARC, NTP or OSHA. HILTI is a registered trademark of Hilti Corp.

2 Routes of Exposure: Medical Conditions Aggravated by Exposure: Dermal. Inhalation Eye, skin, and respiratory conditions. EMERGENCY AND FIRST AID PROCEDURES Eyes: Skin: Inhalation: Ingestion: Other: Immediately flush with plenty of water. Call a physician if symptoms occur. Wash with soap and water. Contaminated clothing should be laundered before reuse. Move victim to fresh air. Call a physician is symptoms persist. If conscious, give plenty of water to drink. Seek medical attention. Do not induce vomiting unless directed by a physician. Never give anything by mouth to an unconscious person. Referral to a physician is recommended if there is any question about the seriousness of the injury/exposure. CONTROL MEASURES AND PERSONAL PROTECTIVE EQUIPMENT Ventilation: Eye Protection: Skin Protection: Respiratory Protection: General (natural or mechanically induced fresh air movements). Splash-proof chemical goggles recommended. Safety glasses with side-shields at a minimum. Cloth gloves are suitable; impermeable (neoprene or rubber) gloves recommended. None normally required with adequate ventilation as noted above. Use a NIOSH-approved organic vapor cartridge respirator when working in areas with little or no air movement. Never enter a confined space unless wearing an appropriate air-supplied respirator. PRECAUTIONS FOR SAFE HANDLING AND USE Handling and Storing Precautions: Spill Procedures: Use with adequate ventilation. Avoid contact with eyes, skin, or clothing. Wash thoroughly after handling. Store in a cool dry place. Keep from freezing. Store below 100 F. Keep container closed when not in use. Remove spillage with absorbent material and dispose in accordance with federal, state, and local regulations. REGULATORY INFORMATION Hazard Communication: HMIS Codes: DOT Shipping Name: IATA / ICAO Shipping Name: TSCA Inventory Status: SARA Title III, Section 313: EPA Waste Code(s): Waste Disposal Methods: This MSDS has been prepared in accordance with the federal OSHA Hazard Communication Standard 29 CFR Health 1, Flammability 0, Reactivity 1, PPE B Not regulated Not regulated Chemical components listed on TSCA inventory. This product does not contain any toxic chemicals which are subject to reporting under Section 313 of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. Not regulated by EPA as a hazardous waste. Consult with regulatory agencies or your corporate personnel for disposal methods that comply with local, state, and federal safety, health and environmental regulations. MSDS 813, Page 2 of 6

3 CC 410 EP Epoxy Skidproofer DESCRIPTION: Part B Epoxy resin INGREDIENTS AND EXPOSURE LIMITS Ingredients: CAS Number: TLV: PEL: STEL: Modified diglycidyl ether of Bisphenol A NE NE NE Alkyl glycidyl ether NE NE NE Abbreviations: PEL = OSHA Permissible Exposure Limit. TLV = ACGIH Threshold Limit Value. STEL = Short Term Exposure Limit. NE = None Established. NA = Not Applicable. PHYSICAL DATA Appearance: Low viscosity clear liquid Odor: Slight odor Boiling Point: 200 F Vapor Pressure: Not applicable Vapor Density: Not determined VOC Content: None Evaporation Rate: Not determined Solubility in Water: Nil Specific Gravity: 1.1 ph: Not determined FIRE AND EXPLOSION HAZARD DATA Flash Point / Method: >200 F / Seta flash Flammable Limits: Not applicable Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: Not applicable A self-contained breathing apparatus should be worn when fighting fires involving chemicals. Thermal decomposition and combustion products can be formed. See below. REACTIVITY DATA Stability: Stable. Hazardous Polymerization: Will not occur. Incompatibility: Hazardous Decomposition Products: Conditions to Avoid: Strong oxidizers, peroxides, acids. Thermal decomposition can yield CO, CO 2, aldehydes and acids. Excessive heat for prolonged periods of time. Reactions with some curing agents can generate large amounts of heat. HEALTH HAZARD DATA Known Hazards: Routes of Exposure: Signs and Symptoms of Exposure: Carcinogenicity: Medical Conditions Aggravated by Exposure: Eye and skin irritation. Sensitization. Dermal. Inhalation. Eyes Irritation. Corneal injury is not likely. Skin - Can cause allergic skin reactions (e.g. rash, redness, itching) in susceptible individuals. Inhalation - No effects expected. Heated vapors can cause irritation. No ingredients are classified as a carcinogen by IARC, NTP or OSHA. Eye, skin, and respiratory conditions. EMERGENCY AND FIRST AID PROCEDURES Eyes: Skin: Inhalation: Ingestion: Immediately flush with plenty of water. Call a physician. Wash with soap and water. Launder contaminated clothing before reuse. If ill effects occur, move victim to fresh air. Call a physician if symptoms persist. If conscious, give plenty of water to drink. Seek medical attention. Do not induce vomiting unless directed by a physician. Never give anything by mouth to an unconscious person. MSDS 813, Page 3 of 6

4 Other: Referral to a physician is recommended if there is any question about the seriousness of the injury/exposure. CONTROL MEASURES AND PERSONAL PROTECTIVE EQUIPMENT Ventilation: Eye Protection: Skin Protection: Respiratory Protection: General, i.e. natural or mechanically induced fresh air movements. Splash-proof chemical goggles recommended while mixing. Safety glasses with side shields at a minimum. Gloves recommended. Cotton or impervious (neoprene or rubber). None normally required with adequate ventilation as noted above. Use a NIOSH-approved organic vapor cartridge respirator when working in areas with little or no air movement. Never enter a confined space unless wearing an appropriate air-supplied respirator. PRECAUTIONS FOR SAFE HANDLING AND USE Handling and Storing Precautions: Spill Procedures: Use with adequate ventilation. Avoid contact with eyes, skin, or clothing. Wash thoroughly after handling. Store in a cool dry place. Keep from freezing. Store below 100 F. Keep container closed when not in use. Remove spillage with absorbent material and dispose in accordance with federal, state, and local regulations. REGULATORY INFORMATION Hazard Communication: HMIS Codes: DOT Shipping Name: IATA / ICAO Shipping Name: TSCA Inventory Status: SARA Title III, Section 313: EPA Waste Code(s): Waste Disposal Methods: This MSDS has been prepared in accordance with the federal OSHA Hazard Communication Standard 29 CFR Health 1, Flammability 0, Reactivity 1, PPE B Chemical components listed on TSCA inventory. This product does not contain any toxic chemicals which are subject to reporting under Section 313 of SARA Title III (40 CFR Part 372). Not regulated by EPA as a hazardous waste. Consult with regulatory agencies or your corporate personnel for disposal methods that comply with local, state, and federal regulations. MSDS 813, Page 4 of 6

5 CC 410 EP Epoxy Skidproofer DESCRIPTION: Part C Aggregate for CC 410 EP epoxy mortar INGREDIENTS AND EXPOSURE LIMITS Ingredients: CAS Number: TLV: PEL: STEL: Silicon Dioxide (sand) mg/m 3 (R) 0.1 mg/m 3 (R) NE Abbreviations: PEL = OSHA Permissible Exposure Limit. TLV = ACGIH Threshold Limit Value. STEL = Short Term Exposure Limit. NE = None Established. NA = Not Applicable. (R) indicates as respirable dust. PHYSICAL DATA Appearance: White or tan sand granules. Odor: None. Boiling Point: Not applicable. Vapor Pressure: Not applicable. Vapor Density: Not determined. VOC Content: None. Evaporation Rate: Not applicable. Solubility in Water: Nil. Specific Gravity: 2.6 ph: Not determined. FIRE AND EXPLOSION HAZARD DATA Flash Point: Not applicable. Flammable Limits: Not applicable. Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: Not applicable. None known. None known. REACTIVITY DATA Stability: Stable. Hazardous Polymerization: Will not occur. Incompatibility: Hazardous Decomposition Products: Conditions to Avoid: Strong oxidizing agents. None expected. Contact with powerful oxidizing agents such as fluorine, chlorine trifluoride, manganese trioxide, and oxygen trifluoride. HEALTH HAZARD DATA Known Hazards: Routes of Exposure: Signs and Symptoms of Exposure: Carcinogenicity: Medical Conditions Aggravated by Exposure: None expected from normal use of this product. Excess exposure to dusts by inhalation for extended periods of time can lead to the development of pulmonary diseases including pneumoconiosis such as silicosis. Dermal. Inhalation. Eyes Mechanical injury can occur from rubbing the eyes due to the abrasive nature of sand. Skin - Prolonged and repeated exposure to the hands can lead to drying of the skin and dermatitis. Inhalation - Excessive exposure to dusts can lead to breathing difficulty. IARC classifies crystalline silica (quartz sand) as a Gp I carcinogen based upon evidence among workers in industries where there has been long-term and chronic exposure (via inhalation) to silica dust; e.g. mining, quarry, stone crushing, refractory brick and pottery workers. The use of this product does not pose a cancer risk; however, wearing a NIOSHapproved dust mask in any dusty situations will reduce the potential for exposure to silica. Eye, skin, and respiratory conditions. MSDS 813, Page 5 of 6

6 EMERGENCY AND FIRST AID PROCEDURES Eyes: Skin: Inhalation: Ingestion: Other: Immediately flush with plenty of water. Call a physician. Wash with soap and water. If ill effects occur, move victim to fresh air. Call a physician if symptoms persist. Not normally a route of exposure. Give plenty of water to drink. Seek medical attention. Do not induce vomiting unless directed by a physician. Referral to a physician is recommended if there is any question about the seriousness of the injury/exposure. CONTROL MEASURES AND PERSONAL PROTECTIVE EQUIPMENT Ventilation: Eye Protection: Skin Protection: Respiratory Protection: General, i.e. natural or mechanically induced fresh air movements. Safety glasses with side shields as a minimum. Splash-proof chemical goggles recommended while mixing parts A and B. Cotton gloves recommended to keep hands from defatting (drying out). None normally required with adequate ventilation as noted above. Use a NIOSH-approved dust mask when working in areas where dust is being generated at or near the PEL/TLV. PRECAUTIONS FOR SAFE HANDLING AND USE Handling and Storing Precautions: Spill Procedures: Avoid generating dust. Avoid contact with eyes, skin, or clothing. Wash hands after handling. Store in a dry location. Sweep up and discard. REGULATORY INFORMATION Hazard Communication: HMIS Codes: DOT Shipping Name: IATA / ICAO Shipping Name: TSCA Inventory Status: SARA Title III, Section 313: EPA Waste Code(s): Waste Disposal Methods: This MSDS has been prepared in accordance with the federal OSHA Hazard Communication Standard 29 CFR Health 2, Flammability 0, Reactivity 0, PPE A Chemical components listed on TSCA inventory. This product does not contain any toxic chemicals which are subject to reporting under Section 313 of SARA Title III (40 CFR Part 372). Not regulated by EPA as a hazardous waste. Consult with regulatory agencies or your corporate personnel for disposal methods that comply with local, state, and federal regulations. CONTACTS Customer Service: Technical Service: Health / Safety: Jerry Metcalf (x6704) Emergency # (Chem-Trec): (USA, PR, Virgin Islands, Canada); (Other countries) The information and recommendations contained herein are based upon data believed to be correct; however, no guarantee or warranty of any kind expressed or implied is made with respect to the information provided. MSDS 813, Page 6 of 6