: BARCOAT ISOLATOR (BAR)

Transcription

1 Date of issue: 7/13/2015 Revision date: 11/24/2017 Supersedes: 6/15/2017 Version: 2.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : BARCOAT ISOLATOR (BAR) Product group : 1K Primer 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec Function or use category : Industrial For professional use only : Primer Uses advised against 1.3. Details of the supplier of the safety data sheet U-POL LIMITED Denington Road, Wellingborough Northants. NN8 2QH - UK T +44 (0) F +44 (0) technical.department@u-pol.com Emergency telephone number Emergency number : CHEMTREC (0) (24 hrs) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Flammable liquids, Category 2 H225 Full text of H statements : see section 16 Adverse physicochemical, human health and environmental effects Highly flammable liquid and vapour Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) : Danger GHS02 : H225 - Highly flammable liquid and vapour. : P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 - Keep container tightly closed. P280 - Wear face protection, protective clothing, protective gloves. P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P403+P235 - Store in a well-ventilated place. Keep cool. P501 - Dispose of contents and container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. 11/24/2017 EN (English) SDS Ref.: BAR 1/8

2 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] propan-2-ol (CAS-No.) (EC-No.) (EC Index-No.) (REACH-no) methanol (CAS-No.) (EC-No.) ; (EC Index-No.) X (REACH-no) butoxyethyl acetate, butylglycol acetate substance with a Community workplace exposure limit Specific concentration limits: (CAS-No.) (EC-No.) (EC Index-No.) (REACH-no) Flam. Liq. 2, H225 Eye Irrit. 2, H319 STOT SE 3, H336 < 5 Flam. Liq. 2, H225 Acute Tox. 3 (Inhalation), H331 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Oral), H301 STOT SE 1, H370 < 5 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation), H332 Name Product identifier Specific concentration limits methanol (CAS-No.) (EC-No.) ; (EC Index-No.) X (REACH-no) Full text of H-statements: see section 16 ( 3 =<C < 10) STOT SE 2, H371 (C >= 10) STOT SE 1, H370 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove person to fresh air and keep comfortable for breathing. : Rinse skin with water/shower. Take off immediately all contaminated clothing. : Rinse eyes with water as a precaution. : Call a poison center or a doctor if you feel unwell Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide Special hazards arising from the substance or mixture Fire hazard Hazardous decomposition products in case of fire : Highly flammable liquid and vapour. : Toxic fumes may be released Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment Emergency procedures : Safety glasses. Protective clothing. Gloves. : Ventilate spillage area. No open flames, no sparks, and no smoking. 11/24/2017 EN (English) SDS Ref.: BAR 2/8

3 For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up For containment Methods for cleaning up Other information 6.4. Reference to other sections For further information refer to section 13. : Contain released substance, pump into suitable containers. Collect spillage. : Take up liquid spill into absorbent material. Notify authorities if product enters sewers or public waters. : Dispose of materials or solid residues at an authorized site. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Flammable vapours may accumulate in the container. Use explosion-proof equipment. Wear personal protective equipment. : Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Storage temperature : < 25 C Storage area Special rules on packaging 7.3. Specific end use(s) : Ground/bond container and receiving equipment. : Store in a well-ventilated place. Keep cool. Keep container tightly closed. : Store in a well-ventilated place. : Keep only in original container. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 2-butoxyethyl acetate, butylglycol acetate ( ) EU Local name 2-Butoxyethyl acetate EU IOELV TWA (mg/m³) 133 mg/m³ EU IOELV TWA (ppm) 20 ppm EU IOELV STEL (mg/m³) 333 mg/m³ EU IOELV STEL (ppm) 50 ppm EU Notes Skin United Kingdom Local name 2-Butoxyethyl acetate United Kingdom WEL TWA (mg/m³) 133 mg/m³ United Kingdom WEL TWA (ppm) 20 ppm United Kingdom WEL STEL (mg/m³) 332 mg/m³ United Kingdom WEL STEL (ppm) 50 ppm United Kingdom Remark (WEL) Sk (Can be absorbed through the skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity) methanol ( ) United Kingdom Local name Methanol United Kingdom WEL TWA (mg/m³) 266 mg/m³ United Kingdom WEL TWA (ppm) 200 ppm United Kingdom WEL STEL (mg/m³) 333 mg/m³ United Kingdom WEL STEL (ppm) 250 ppm United Kingdom Remark (WEL) Sk (Can be absorbed through the skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity) propan-2-ol ( ) United Kingdom Local name Propan-2-ol United Kingdom WEL TWA (mg/m³) 999 mg/m³ 11/24/2017 EN (English) SDS Ref.: BAR 3/8

4 propan-2-ol ( ) United Kingdom WEL TWA (ppm) 400 ppm United Kingdom WEL STEL (mg/m³) 1250 mg/m³ United Kingdom WEL STEL (ppm) 500 ppm 8.2. Exposure controls Appropriate engineering controls Personal protective equipment : Ensure good ventilation of the work station. : Gloves. Protective clothing. Safety glasses. Materials for protective clothing: Impermeable clothing Hand protection: Protective gloves Eye protection: Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment Environmental exposure controls : Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Liquid. Colour : Slightly yellow to green. Odour : alcoholic. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point : Not applicable Freezing point Boiling point : > 35 C Flash point : 19 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) : Not applicable Vapour pressure Relative vapour density at 20 C Relative density Density : Solubility : Miscible with water. soluble in most organic solvents. Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 11/24/2017 EN (English) SDS Ref.: BAR 4/8

5 9.2. Other information VOC content : 469 g/l SECTION 10: Stability and reactivity Reactivity Highly flammable liquid and vapour Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard SECTION 12: Ecological information Toxicity Ecology - general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Regional legislation (waste) : Disposal must be done according to official regulations. Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions. Additional information : Flammable vapours may accumulate in the container. 11/24/2017 EN (English) SDS Ref.: BAR 5/8

6 SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN ADR IMDG IATA ADN RID UN number UN proper shipping name PAINT PAINT Paint PAINT PAINT Transport document description UN 1263 PAINT, 3, II, (D/E) UN 1263 PAINT, 3, II UN 1263 Paint, 3, II UN 1263 PAINT, 3, II UN 1263 PAINT, 3, II Transport hazard class(es) Packing group II II II II II Environmental hazards Marine pollutant : No Special precautions for user - Overland transport Classification code (ADR) : F1 Special provisions (ADR) : 163, 640C, 650 Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Special packing provisions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Vehicle for tank carriage : 5l : P001 : PP1 No supplementary information available : MP19 : T4 : TP1, TP8, TP28 : L1.5BN : FL Transport category (ADR) : 2 Special provisions for carriage - Operation (ADR) Hazard identification number (Kemler No.) : 33 Orange plates : : S2, S20 Tunnel restriction code (ADR) EAC code : D/E : 3YE - Transport by sea Special provisions (IMDG) : 163 Limited quantities (IMDG) : 5 L Excepted quantities (IMDG) Packing instructions (IMDG) : P001 Special packing provisions (IMDG) : PP1 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T4 Tank special provisions (IMDG) : TP1, TP8, TP28 11/24/2017 EN (English) SDS Ref.: BAR 6/8

7 EmS-No. (Fire) EmS-No. (Spillage) Stowage category (IMDG) Properties and observations (IMDG) : F-E : S-E : B : Miscibility with water depends upon the composition. - Air transport PCA Excepted quantities (IATA) PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) : Y341 : 1L PCA packing instructions (IATA) : 353 PCA max net quantity (IATA) : 5L CAO packing instructions (IATA) : 364 CAO max net quantity (IATA) Special provisions (IATA) ERG code (IATA) - Inland waterway transport Classification code (ADN) : 60L : A3, A72, A192 : 3L : F1 Special provisions (ADN) : 163, 64C, 65 Limited quantities (ADN) Excepted quantities (ADN) Equipment required (ADN) Ventilation (ADN) : 5 L Number of blue cones/lights (ADN) : 1 - Rail transport Classification code (RID) : PP, EX, A : VE01 : F1 Special provisions (RID) : 163, 640C, 650 Limited quantities (RID) Excepted quantities (RID) Packing instructions (RID) Special packing provisions (RID) Mixed packing provisions (RID) Portable tank and bulk container instructions (RID) Portable tank and bulk container special provisions (RID) Tank codes for RID tanks (RID) : 5L : P001 : PP1 : MP19 : T4 Transport category (RID) : 2 Colis express (express parcels) (RID) : TP1, TP8, TP28 : L1.5BN : CE7 Hazard identification number (RID) : Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances VOC content : 469 g/l National regulations Chemical safety assessment No chemical safety assessment has been carried out 11/24/2017 EN (English) SDS Ref.: BAR 7/8

8 SECTION 16: Other information Full text of H- and EUH-statements: Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3 Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3 Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3 Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 2 Flammable liquids, Category 2 STOT SE 1 Specific target organ toxicity single exposure, Category 1 STOT SE 3 H225 H301 H311 H312 H319 H331 H332 H336 H370 Specific target organ toxicity Single exposure, Category 3, Narcosis Highly flammable liquid and vapour. Toxic if swallowed. Toxic in contact with skin. Harmful in contact with skin. Causes serious eye irritation. Toxic if inhaled. Harmful if inhaled. May cause drowsiness or dizziness. Causes damage to organs. Flam. Liq. 2 H225 On basis of test data UPOL SDS EU (no product code) For professional use only. The information contained within this (SDS) is believed to be correct as of the date issued however it is subject to change from time to time. It does not purport to be all inclusive or exhaustive and shall only be used as a guide. U-POL makes no warranties, expressed or implied, including but not limited to, any implied warranty of fitness for a given purpose or usage. It is the Buyers responsibility to ensure the suitability of the products for their own use and to check the information is up to date. U-POL cannot be held responsible for the suitability of use for any of its products, considering the wide range of factors such as application, substrates and handling methods. Since these conditions of use are outside of our control, the company shall not be held liable for any damage resulting from handling or from contact with the product detailed. Moreover, addition of reducers, hardeners or other additives over and above U-POL s recommendations for use, may substantially alter the composition and hazards of the product. U-POL data sheets are available via the U-POL website at 11/24/2017 EN (English) SDS Ref.: BAR 8/8