Material Safety Data Sheet

Transcription

1 Product code: SS-171A, SS-171A-EU, SS-172A, SS-172A-EU Page 1 of 6 SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifier Chemical characterization (Mixture) Details of the supplier of the safety data sheet Company name: Street: Place: WESCOR, INC. 370 West 1700 South USA Logan, UT Telephone: +1 (435) Telefax: +1 (435) Responsible Department: QA/RA Department Tel.: +1 (435) West 1700 South qarawescor@elitechgroup.com Logan, UT USA Emergency telephone: Tel: (7:00-15:00) USA SECTION 2: Hazards identification Route(s) of Entry Signs and Symptoms of Exposure Ingestion: Toxic: danger of very serious irreversible effects if swallowed. Carcinogenicity (NTP): Formaldehyde (Gas) (CAS ) is listed in group 2. Carcinogenicity (IARC): Formaldehyde (Gas) (CAS ) is listed in group 1. Carcinogenicity (OSHA): Formaldehyde (Gas) (CAS ) is listed. SECTION 3: Composition/information on ingredients Mixtures Hazardous components CAS No. Components Quantity formaldehyde... % <12 % maleic acid <15 % imidazole <15 % methanol <5 % caustic potash, potassium hydroxide <1 % (p-tert-octylphenoxy) polyethoxyethanol < 1 % Further Information Note: This hazard characteristics refer to the properties of pure ingredients, for the identification of the preparation (product), see Section 2 and 15. Product itself does not burn. SECTION 4: First aid measures Description of first aid measures General information In case of accident or if you feel unwell, seek medical advice immediately (show safety data sheet if DOC-00319E.doc 1 of 6

2 possible). Product code: SS-171A, SS-171A-EU, SS-172A, SS-172A-EU Page 2 of 6 After inhalation IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. After contact with skin After contact with skin, wash immediately with: Water and soap. In case of skin irritation, seek medical treatment. After contact with eyes In case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart. Subsequently consult an ophthalmologist. After ingestion Rinse mouth thoroughly with water. Make affected person vomit if conscious. Never give anything by mouth to an unconscious person or a person with cramps. Immediately get medical attention. Indication of any immediate medical attention and special treatment needed - Advice for first medical aid: After contact with solutions / concentrated vapors rinse eyes persistently with water. Always follow-up by ophthalmologist as soon as possible. Wash contaminated skin thoroughly with water. Treat irritated areas with Dermatocorticoid. After extensive wetting a clarification is recommended. SECTION 5: Firefighting measures Extinguishing media Suitable extinguishing media The product itself is not combustible. Special hazards arising from the substance or mixture Can be released in case of fire: Carbon monoxide. Carbon dioxide (CO2). Formaldehyde. Advice for firefighters Wear a self-contained breathing apparatus and chemical resistant suit. Additional information Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures Wear personal protection equipment. (Refer to chapter 8.) Environmental precautions Dumping into the environment must be prevented. Methods and material for containment and cleaning up Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the assimilated material according to the section on waste disposal. The contaminated area should be cleaned up immediately with: SECTION 7: Handling and storage Precautions for safe handling Advice on safe handling Wear personal protection equipment. (Refer to chapter 8.) Advice on protection against fire and explosion No special fire protection measures are necessary. Conditions for safe storage, including any incompatibilities DOC-00319E.doc 2 of 6

3 Product code: SS-171A, SS-171A-EU, SS-172A, SS-172A-EU Page 3 of 6 Requirements for storage rooms and vessels Unsuitable materials for Container: Base metals and alloys Advice on storage compatibility Do not store together with: Food and fodder. Explosives. Oxidizing solids. Oxidizing liquids. Organic peroxides. Gases under pressure. Further information on storage conditions Keep locked up. Keep container tightly closed and in a well-ventilated place. Keep/Store only in original container. Ensure adequate ventilation of the storage area. Store small quantities in appropriate dangerous substance cabinets. Protect against: UV-radiation/sunlight. Maximum period of storage (time): 18 M SECTION 8: Exposure controls/personal protection Control parameters Exposure limits CAS No. Components ppm mg/m³ fib/cc Category Origin Formaldehyde TWA (8 h) PEL TWA (8 h) REL 2 - STEL (15 min) PEL C Ceiling REL Methyl alcohol TWA (8 h) PEL TWA (8 h) REL STEL (15 min) REL Potassium hydroxide TWA (8 h) REL Exposure controls - C 2 Ceiling REL Protective and hygiene measures Always close containers tightly after the removal of product. Do not eat, drink, smoke or sneeze at the workplace. Wash hands before breaks and at the end of work. Remove contaminated clothing immediately and dispose off safely. Wash contaminated clothing prior to re-use. Used working clothes should not be used outside the work area. Street clothing should be stored separately from work clothing. Respiratory protection Respiratory protection required in case of: insufficient ventilation. exceeding critical value insufficient absorption. Suitable respiratory protective equipment: gas filtering equipment (EN 141). Type : AX In case of increasing hazard add: Combination filter device (DIN EN 141).. : B-P2/P3 Hand protection Pull-over gloves of rubber. DIN EN 374 Suitable material: (penetration time (maximum wearing period): >= 8 h ): NBR (Nitrile rubber). (0,35 mm) FKM (fluororubber). (0,4 mm) Butyl rubber. (0,5 mm) DOC-00319E.doc 3 of 6

4 Product code: SS-171A, SS-171A-EU, SS-172A, SS-172A-EU Page 4 of 6 (penetration time (maximum wearing period): >= 4 h ): CR (polychloroprenes, Chloroprene rubber). (0,5 mm) (penetration time (maximum wearing period): >= 2 h ): PVC (Polyvinyl chloride). (0,5 mm) Before using check leak tightness / impermeability. In case of reutilization, clean gloves before taking off and store in well-aired place. Eye protection Suitable eye protection: Tightly sealed safety glasses. DIN EN 166 Skin protection Suitable protection of the body: Lab apron. Environmental exposure controls No special measures are necessary. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties Form: Color: Odor: liquid colourless characteristic ph-value: 6,5-7,5 Changes in the physical state Melting point: Flash point: Water solubility: Solubility in other solvents: Ethanol. 0 C > 200 C complete miscible Test method SECTION 10: Stability and reactivity Stability: Possibility of Hazardous Reactions: Conditions to avoid Keep away from heat. Stable Will not occur Incompatible materials Acid. Alkalis (alkalis). Oxidizing agents, strong. Nitrogen oxides (NOx). Nitric acid. Hydrogenium peroxide. Oxidizing agents, strong. Aniline. Hazardous decomposition products Can be released in case of fire: Carbon monoxide. Carbon dioxide (CO2). Formaldehyde. SECTION 11: Toxicological information Information on toxicological effects Irritation and corrosivity Irritant effect on the eye: irritant. Irritant effect on the skin: irritant. Sensitizing effects Contains: maleic acid: Formaldehyde. May cause sensitization in susceptible people. People who suffer from skins problems, asthma, allergies, chronic or recurring respiratory illnesses must not be deployed in processes, which use this substance. DOC-00319E.doc 4 of 6

5 Product code: SS-171A, SS-171A-EU, SS-172A, SS-172A-EU Page 5 of 6 Severe effects after repeated or prolonged exposure Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed. Formaldehyde.: NOAEL: 15 mg/kg Methanol. : NOAEL: 270 mg/kg Carcinogenic/mutagenic/toxic effects for reproduction Formaldehyde.: Limited evidence of a carcinogenic effect. Carcinogenic Cat. 3 (Carc. Cat. 3) maleic acid: No evidence for: Carcinogenicity No evidence for: In-vitro mutagenicity During animal experiments no indications of reproductive toxicity were observed. Methanol.: No evidence for: Carcinogenicity No evidence for: Developmental toxicity/teratogenicity No evidence for: In-vitro mutagenicity During animal experiments no indications of reproductive toxicity were observed. SECTION 12: Ecological information Persistence and degradability Product is biodegradable. Bioaccumulative potential No indication of bio-accumulation potential. SECTION 13: Disposal considerations Waste treatment methods Advice on disposal Waste disposal according to official state regulations. Consult the local waste disposal expert about waste disposal. Moreover, national legislation has to be observed! Contaminated packaging Cleaned containers may be recycled. SECTION 14: Transport information US DOT 49 CFR Proper shipping name Not a hazardous material with respect to these transport regulations. && Not controlled under DOT. Land transport (ADR/RID) Other applicable information Not restricted SECTION 15: Regulatory information U.S. Regulations SARA Section 302 Extremely Hazardous Substances (EHS) Formaldehyde (solution), RQ = 100 lbs, TPQ = 500 lbs. DOC-00319E.doc 5 of 6

6 State Regulations Section 313 Toxic Release Chemicals Formaldehyde (CAS ). Product code: SS-171A, SS-171A-EU, SS-172A, SS-172A-EU Page 6 of 6 This product contains chemicals known to the state of California to cause cancer. SECTION 16: Other information Hazardous Materials Information Label (HMIS) Health: 3 Physical Hazard: 1 NFPA Hazard Ratings Health: Flammability: Reactivity: Unique Hazard: Changes Rev. 1,0 ( ) Initial release Other data The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.) DOC-00319E.doc 6 0f 6