Safety Data Sheet. ProCare Shine 10 MA.
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1 Page 1 of 7 1. Identification Product identifier Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Cleaner Details of the supplier of the safety data sheet Manufacturer Company name: Street: Place: Miele & Cie. KG Carl-Miele-Straße 29 D Gütersloh Telephone: +49 (0)5241/89-0 Responsible Department: sdb@etol.de Supplier Company name: Street: Place: Miele Limited 161 Four Valley Drive CDN- L4K 4V8 VAUGHAN, Ontario Telephone: professional@miele.ca Internet: Emergency telephone number: GBK/Infotrac ID : (USA domestic) or international (001) Emergency CONTACT (24-Hour-Number):GBK GmbH +49 (0) Hazard identification Classification of the substance or mixture UN-GHS (ST/SG/AC.10/11/Rev.5) Hazard categories: Skin corrosion/irritation: Skin Irrit. 2 Serious eye damage/eye irritation: Eye Irrit. 2A Hazard Statements: Causes skin irritation. Causes serious eye irritation. Label elements UN-GHS (ST/SG/AC.10/11/Rev.5) Signal word: Pictograms: Warning Hazard statements Causes skin irritation. Causes serious eye irritation. Precautionary statements Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
2 Page 2 of 7 Continue rinsing. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Other hazards No information available. 3. Composition/information on ingredients Mixtures Hazardous components CAS No Chemical name Quantity Sodium hydroxide 1 - < 5 % 4. First-aid measures Description of first aid measures General information In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). After inhalation In case of accident by inhalation: remove casualty to fresh air and keep at rest. In case of respiratory tract irritation, consult a physician. After contact with skin After contact with skin, wash immediately with plenty of water. If skin irritation or rash occurs: Get medical advice/attention. After contact with eyes Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. In case of troubles or persistent symptoms, consult an ophthalmologist. After ingestion Rinse mouth. Let water be drunken in little sips (dilution effect). Do NOT induce vomiting. In all cases of doubt, or when symptoms persist, seek medical advice. Indication of immediate medical attention and special treatment needed Treat symptomatically. 5. Fire-fighting measures Extinguishing media Suitable extinguishing media Carbon dioxide (CO2). Water spray. Foam. Extinguishing powder. Unsuitable extinguishing media High power water jet. Specific hazards arising from the hazardous product In case of fire may be liberated: Carbon dioxide (CO2). Carbon monoxide Special protective equipment and precautions for fire-fighters Wear a self-contained breathing apparatus and chemical protective clothing. In case of fire and/or explosion do not breathe fumes. Additional information Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water. Use water spray jet to protect personnel and to cool endangered containers.
3 Page 3 of 7 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Do not breathe vapour/aerosol. Avoid contact with skin, eyes and clothes. Wear personal protection equipment (refer to section 8). High slip hazard because of leaking or spilled product. Environmental precautions Do not allow to enter into surface water or drains. Eliminate leaks immediately. Methods and material for containment and cleaning up Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Collect in closed containers for disposal. Clean contaminated articles and floor according to the environmental legislation. Reference to other sections Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section Handling and storage Precautions for safe handling Advice on safe handling Wear personal protection equipment. (refer to chapter 8) Do not breathe gas/fumes/vapour/spray. Do not mix with acids. Advice on protection against fire and explosion Usual measures for fire prevention. Further information on handling Avoid contact with skin, eyes and clothes. General protection and hygiene measures: refer to chapter 8 Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep container tightly closed in a cool, well-ventilated place. Advice on storage compatibility Do not store together with: Explosives. Oxidizing solids. Oxidizing liquids. Radioactive substances. Infectious substances Further information on storage conditions Protect against: moisture. UV-radiation/sunlight. heat. frost. 8. Exposure controls/personal protection Control parameters Additional advice on limit values Sodium hydroxide: Long term occupational exposure limit value: - Short term occupational exposure limit value: 2 mg/3 (Alberta, British Columbia) Exposure controls
4 Page 4 of 7 Appropriate engineering controls Vapours / aerosols must be extracted by suction immediately at point of origin. Protective and hygiene measures Always close containers tightly after the removal of product. Keep away from food, drink and animal feedingstuffs. Wash hands before breaks and after work. Do not eat, drink, smoke or sneeze at the workplace. Eye/face protection Recommended eye protection brand: Tightly sealed safety glasses. Standards: EN 166 or 29 CFR Hand protection In case of prolonged or frequently repeated skin contact: Pull-over gloves of rubber. DIN EN 374 Suitable material: CR (polychloroprenes, Chloroprene rubber). (0,5 mm) NBR (Nitrile rubber). (0,35 mm) FKM (fluororubber). (0,4 mm) PVC (Polyvinyl chloride). (0,5 mm) Butyl rubber. (0,5 mm) Breakthrough time > 8h Before using check leak tightness / impermeability. In the case of wanting to use the gloves again, clean them before taking off and air them well. Skin protection No special measures are necessary. Respiratory protection With correct and proper use, and under normal conditions, breathing protection is not required. Respiratory protection necessary at: generation/formation of aerosols Suitable respiratory protective equipment: Particulate Respirators, Standard: 42 CFR Part 84, Type : R/N/P-95/99/100 The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If the concentration is exceeded, closed-circuit breathing apparatus must be used! Environmental exposure controls Do not allow uncontrolled discharge of product into the environment. 9. Physical and chemical properties Information on basic physical and chemical properties Physical state: Colour: Odour: ph-value: Changes in the physical state Melting point: Initial boiling point and boiling range: Flash point: Explosive properties none Lower explosive limits: Upper explosive limits: liquid colourless characteristic ~0 C ~100 C >100 C Test method
5 Page 5 of 7 Ignition temperature: Oxidizing properties none Vapour pressure: Density (at 20 C): Water solubility: Solubility in other solvents Viscosity / dynamic: Solvent content: Other information Solid content: 1,3 g/cm³ miscible. 0% 22,8% No information available. 10. Stability and reactivity Conditions to avoid Keep away from heat. Incompatible materials Reducing agents, strong. Hazardous substances that release flammable gases when in contact with water Acid. Hazardous decomposition products In case of fire may be liberated: Carbon dioxide (CO2). Carbon monoxide 11. Toxicological information Information on toxicological effects Acute toxicity Irritation and corrosivity Causes skin irritation. Causes serious eye irritation. Sensitizing effects STOT-single exposure Severe effects after repeated or prolonged exposure Carcinogenic/mutagenic/toxic effects for reproduction Aspiration hazard Specific effects in experiment on an animal There are no data available on the preparation/mixture itself. Name of toxicologically synergistic products No information available.
6 Page 6 of Ecological information Persistence and degradability The methods for determining the biological degradability are not applicable to inorganic substances. Bioaccumulative potential No indication of bioaccumulation potential. Mobility in soil No data available Other adverse effects No data available 13. Disposal considerations Waste treatment methods Advice on disposal Dispose of waste according to applicable legislation. Consult the appropriate local waste disposal expert about waste disposal. Non-contaminated packages may be recycled. Contaminated packaging Handle contaminated packages in the same way as the substance itself. 14. Transport information Canadian TDG Proper shipping name: Marine transport (IMDG) UN number: United Nations proper shipping name: Transport hazard class(es): Packing group: Air transport (ICAO) UN number: United Nations proper shipping name: Transport hazard class(es): Packing group: Environmental hazards ENVIRONMENTALLY HAZARDOUS: Not a hazardous material with respect to these transport regulations. no 15. Regulatory information Canadian regulations This product has been classified according to the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. DSL/NDSL inventory status Sodium hydroxide; caustic soda: listed National Pollutant Release Inventory (NPRI) No substance listed.
7 Page 7 of 7 WHMIS classification Class D2B Provincial regulations See section Other information Changes Rev.1.00; , Initial release Rev. 1,01; Changes in chapter: 1 Further Information The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)
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