Safety Data Sheet. according to Regulation (EC) No 1907/2006. Miele Backofenreiniger

Transcription

1 Page 1 of 6 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Oven Cleaner 1.3. Details of the supplier of the safety data sheet Manufacturer Company name: Street: Place: Westring D Leopoldshöhe Telephone: +49(0) Telefax: +49(0) info@becker-chemie.de Contact person: Dr. Bogner Telephone: +49(0) Internet: Responsible Department: Supplier Company name: Street: info@becker-chemie.de Department product safety tel.: +49(0) Miele & Cie. KG Gütersloh Place: D Carl-Miele-Straße 29 Telephone: +49(0) Internet: Responsible Department: Verkauf +49(0) ( 0,09/Min.) 1.4. Emergency telephone number: Poison information outside office opening times: see emergency call number +49(0) (0) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Indications of danger: Xi - Irritant R phrases: Irritating to eyes and skin. GHS classification Hazard categories: Serious eye damage/eye irritation: Eye Irrit. 2 Hazard Statements: Causes serious eye irritation Label elements Signal word: Pictograms: Warning GHS07

2 Page 2 of 6 Hazard statements H319 Causes serious eye irritation. Precautionary statements P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention Other hazards The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII. SECTION 3: Composition/information on ingredients 3.2. Mixtures Hazardous components EC No CAS No Index No REACH No Chemical name Classification GHS classification Quantity Alcohols, C12-14, ethoxylated, sulfates, sodium salts 1 - < 5 % Xi - Irritant R38-41 Full text of R-, H- and EUH-phrases: see section 16. SECTION 4: First aid measures 4.1. Description of first aid measures Skin Irrit. 2, Eye Dam. 1, Aquatic Chronic 3; H315 H318 H412 General information Remove contaminated, saturated clothing immediately. Do NOT induce vomiting. After inhalation Provide fresh air. Move victim out of danger zone. After contact with skin After contact with skin, wash immediately with: Water. In case of skin irritation, seek medical treatment. After contact with eyes If product gets into the eye, keep eyelid open and rinse immediately with large quantities of water, for at least 5 minutes. Subsequently consult an ophthalmologist. After ingestion Do NOT induce vomiting. Call a physician immediately. Let water be drunken in little sips (dilution effect). Do not leave affected person unattended Most important symptoms and effects, both acute and delayed no data available 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically.

3 Page 3 of 6 SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media The product itself does not burn. Co-ordinate fire-fighting measures to the fire surroundings. Foam. Carbon dioxide (CO2). Extinguishing powder. Water spray. Unsuitable extinguishing media Foam Special hazards arising from the substance or mixture At high temperatures may produce hazardous decomposition products such as: carbon dioxide, carbon monoxide, oxides of nitrogen Advice for firefighters In case of fire: Wear self-contained breathing apparatus. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid contact with skin and eyes. High slip hazard because of leaking or spilled product Methods and material for containment and cleaning up Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents) Reference to other sections Wear personal protection equipment (see chapter 8). SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling Avoid contact with skin and eyes. When using do not eat, drink or smoke. Advice on protection against fire and explosion The product is not: Combustible Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep only in the original container. Keep away from food, drink and animal feedingstuffs. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Additional advice on limit values 8.2. Exposure controls Observe in addition any national regulations! Protective and hygiene measures Wash hands before breaks and after work. When using do not eat or drink. Contact with the skin and inhalation of aerosols/vapors from the preparation must be avoided. Eye/face protection Tightly sealed safety glasses.

4 Page 4 of 6 Hand protection Tested protective gloves are to be worn: Suitable material: PVC (Polyvinyl chloride). NR (Natural rubber (Caoutchouc), Natural latex). CR (polychloroprenes, Chloroprene rubber). NBR (Nitrile rubber). FKM (fluororubber). Breakthrough times and swelling characteristics of the material must be taken into consideration. Skin protection For the protection against direct skin contact, body protective clothing is essential (in addition to the usual working clothes). Respiratory protection With correct and proper use, and under normal conditions, breathing protection is not required. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: Colour: Odour: liquid colourless opaque product-specific ph-value (at 20 C): 11,4 Test method Changes in the physical state Density (at 20 C): 1,009 g/cm³ SECTION 10: Stability and reactivity Reactivity No dangerous reactions at a correct storage and handling Chemical stability No dangerous reactions at a correct storage and handling Conditions to avoid Offering protection against frost Incompatible materials No dangerous reactions at a correct storage and handling Hazardous decomposition products No decomposition at storage as agreed and handling. SECTION 11: Toxicological information Information on toxicological effects Toxicocinetics, metabolism and distribution There are no data available on the preparation/mixture itself. Acute toxicity There are no data available on the preparation/mixture itself. CAS No Chemical name Exposure routes Method Alcohols, C12-14, ethoxylated, sulfates, sodium salts oral dermal LD50 LD50 Dose >2000 mg/kg >2000 mg/kg Species Ratte Ratte Source

5 Page 5 of 6 Irritation and corrosivity Irritant effect on the eye: irritant. Irritant effect on the skin: Irritant. Specific effects in experiment on an animal There are no data available on the preparation/mixture itself. SECTION 12: Ecological information Toxicity CAS No No environmental toxicological data available. Chemical name Aquatic toxicity Method Dose [h] [d] Species Source Alcohols, C12-14, ethoxylated, sulfates, sodium salts Acute fish toxicity Acute algae toxicity Acute crustacea toxicity LC50 > 1-10 mg/l 96 h Brachydanio rerio ErC mg/l 72 h Desmodesmus subspicatus EC50 > 1-10 mg/l 48 h Daphnia magna Persistence and degradability The Tenside used in the mixture correspond to the Detergenzienverordnung (no. 648/2004) and are degradable completely aerobically. The product doesn't contribute to the AOX value of the water Bioaccumulative potential On the basis of existing data about disposal/decomposition and bio-accumulation potential, long term environmental damage is unlikely Mobility in soil No data available Other adverse effects Not expecting. SECTION 13: Disposal considerations Waste treatment methods Advice on disposal Appropriate disposal/product: According to EAKV, allocation of waste identity numbers/waste descriptions must be carried out in a specific way for every industry and process. Contaminated packaging Contaminated packaging: Completely emptied packings can be re-cycled. SECTION 14: Transport information Land transport (ADR/RID) UN number: Transport hazard class(es): Packing group: Inland waterways transport (ADN) UN number: Transport hazard class(es): Packing group:

6 Page 6 of 6 Marine transport (IMDG) UN number: Transport hazard class(es): Packing group: Air transport (ICAO) UN number: Transport hazard class(es): Packing group: Environmental hazards ENVIRONMENTALLY HAZARDOUS: Special precautions for user No-one Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. SECTION 15: Regulatory information no Safety, health and environmental regulations/legislation specific for the substance or mixture National regulatory information Water contaminating class (D): Chemical safety assessment 1 - slightly water contaminating Chemical safety assessments for substances in this mixture were not carried out. SECTION 16: Other information Relevant R-phrases (Number and full text) 38 Irritating to skin. 41 Risk of serious damage to eyes. Relevant H- and EUH-phrases (Number and full text) H315 Causes skin irritation. H318 Causes serious eye damage. H319 Causes serious eye irritation. H412 Harmful to aquatic life with long lasting effects. Further Information The processing and application notes are on the technical leaflets to the products. The details are based on today's stand of our knowledge, they don't represent any assurance of product qualities, however, and don't justify any contractual facts of the case. The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)