Safety Data Sheet. according to Regulation (EC) No 1907/2006. Miele Glaskeramikreiniger

Transcription

1 Page 1 of 7 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Ceramic and Stainless Steel Hob Cleaner 1.3. Details of the supplier of the safety data sheet Manufacturer Company name: Street: Place: Westring D Leopoldshöhe Telephone: +49(0) Telefax: +49(0) info@becker-chemie.de Contact person: Dr. Bogner Telephone: +49(0) Internet: Responsible Department: Supplier Company name: Street: info@becker-chemie.de Department product safety tel.: +49(0) Miele & Cie. KG Gütersloh Place: D Carl-Miele-Straße 29 Telephone: +49(0) Internet: Responsible Department: Verkauf +49(0) ( 0,09/Min.) 1.4. Emergency telephone number: Poison information outside office opening times: see emergency call number +49(0) (0) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS classification Hazard categories: Skin corrosion/irritation: Skin Irrit. 2 Serious eye damage/eye irritation: Eye Dam. 1 Hazard Statements: Causes serious eye irritation Label elements Signal word: Pictograms: Warning GHS07

2 Page 2 of 7 Hazard statements H319 Causes serious eye irritation. Precautionary statements P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. Special labelling of certain mixtures EUH208 Contains Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no ] and 2-methyl-2H-isothiazol-3-one [EC no ] (3:1). May produce an allergic reaction Other hazards The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII. SECTION 3: Composition/information on ingredients 3.2. Mixtures Hazardous components EC No CAS No Index No REACH No Chemical name Classification GHS classification Quantity Sulfonsäuren, C14-17-sec-Alkan-, Natriumsalze 1 - < 5 % Xn - Harmful, Xi - Irritant R Acute Tox. 4, Skin Irrit. 2, Eye Dam. 1; H302 H315 H Isotridecanol,ethoxylated 1 - < 5 % Xi - Irritant R41 Eye Dam. 1; H Full text of R-, H- and EUH-phrases: see section 16. Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no ] and 2-methyl-2H-isothiazol-3-one [EC no ] (3:1) T - Toxic, C - Corrosive, N - Dangerous for the environment R23/24/ Acute Tox. 3, Acute Tox. 3, Acute Tox. 3, Skin Corr. 1B, Skin Sens. 1, Aquatic Acute 1 (M-Factor = 1), Aquatic Chronic 1 (M-Factor = 1); H331 H311 H301 H314 H317 H400 H410 < 0.1 % SECTION 4: First aid measures 4.1. Description of first aid measures General information Take off immediately all contaminated clothing. After inhalation Provide fresh air. Seek medical attention if problems persist. After contact with skin After skin contact: Water and soap. In case of skin irritation, seek medical treatment. After contact with eyes In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

3 Page 3 of 7 After ingestion Do NOT induce vomiting. Call a physician immediately Most important symptoms and effects, both acute and delayed no data available 4.3. Indication of any immediate medical attention and special treatment needed no data available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Co-ordinate fire-fighting measures to the fire surroundings. Foam. Carbon dioxide (CO2). Extinguishing powder. Water spray Special hazards arising from the substance or mixture At high temperatures may produce hazardous decomposition products such as: carbon dioxide, carbon monoxide, oxides of nitrogen Advice for firefighters In case of fire: Wear self-contained breathing apparatus. Additional information Use water spray jet to protect personnel and to cool endangered containers. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Put on protection equipment and keep away unprotected persons. Provide adequate ventilation Environmental precautions Do not allow to enter into surface water or drains Methods and material for containment and cleaning up Take up mechanically. Wipe up with absorbent material (eg. cloth, fleece). SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling Avoid contact with skin and eyes. When using do not eat, drink or smoke. Advice on protection against fire and explosion The product is not: Combustible Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep only in the original container. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Additional advice on limit values 8.2. Exposure controls Observe in addition any national regulations! Protective and hygiene measures Do not eat, drink, smoke or sneeze at the workplace. Wash hands before breaks and after work. Remove contaminated, saturated clothing immediately. Protect skin by using skin protective cream.

4 Page 4 of 7 Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Keep awy from: food, feeding stuff Eye/face protection Eye protection: not applicable. Hand protection Hand protection: not required. Respiratory protection With correct and proper use, and under normal conditions, breathing protection is not required. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: Colour: Odour: liquid leicht gelblich characteristic ph-value (at 20 C): 9,4-9,8 Test method Changes in the physical state Melting point: Initial boiling point and boiling range: Sublimation point: Softening point: : Flash point: Flammability Solid: Explosive properties not Explosive. Lower explosion limits: Upper explosion limits: Ignition temperature: Auto-ignition temperature Solid: Gas: Vapour pressure: (at 20 C) Vapour pressure: Density (at 20 C): Bulk density: Water solubility: Partition coefficient: Viscosity / dynamic: Viscosity / kinematic: Flow time: Vapour density: 110 C non-flammable miscible.

5 Page 5 of 7 Evaporation rate: Solvent separation test: Solvent content: 9.2. Other information SECTION 10: Stability and reactivity Reactivity No dangerous reactions at a correct storage and handling Chemical stability No dangerous reactions at a correct storage and handling Conditions to avoid Offering protection against frost Incompatible materials No dangerous reactions at a correct storage and handling Hazardous decomposition products No decomposition at storage as agreed and handling. SECTION 11: Toxicological information Information on toxicological effects Toxicocinetics, metabolism and distribution There are no data available on the preparation/mixture itself. Acute toxicity There are no data available on the preparation/mixture itself. CAS No Chemical name Exposure routes Method Sulfonsäuren, C14-17-sec-Alkan-, Natriumsalze oral Isotridecanol,ethoxylated dermal ATE LD50 Dose 500 mg/kg >2000 mg/kg Species Kaninchen Source Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no ] and 2-methyl-2H-isothiazol-3-one [EC no ] (3:1) oral dermal ATE ATE 100 mg/kg 300 mg/kg inhalative vapour ATE 3 mg/l inhalative aerosol ATE 0,5 mg/l Sensitising effects no danger of sensitization. Specific effects in experiment on an animal There are no data available on the preparation/mixture itself. SECTION 12: Ecological information Toxicity According to the present state of knowledge negative ecological effects are not expected.

6 Page 6 of 7 CAS No Chemical name Aquatic toxicity Method Dose [h] [d] Species Source Isotridecanol,ethoxylated Acute fish toxicity Acute algae toxicity Acute crustacea toxicity LC50 > 1-10 mg/l 96 h Cyprinus carpio ErC50 > 1-10 mg/l 72 h Grünalge EC50 > 1-10 mg/l 48 h Daphnia magna Persistence and degradability The Tenside used in the mixture correspond to the Detergenzienverordnung (no. 648/2004) and are degradable completely aerobically. The product doesn't contribute to the AOX value of the water Bioaccumulative potential On the basis of existing data about disposal/decomposition and bio-accumulation potential, long term environmental damage is unlikely Mobility in soil No data available Results of PBT and vpvb assessment No data available Other adverse effects Not expecting. SECTION 13: Disposal considerations Waste treatment methods Advice on disposal Appropriate disposal/product: According to EAKV, allocation of waste identity numbers/waste descriptions must be carried out in a specific way for every industry and process. Contaminated packaging Contaminated packaging: Completely emptied packings can be re-cycled. SECTION 14: Transport information Land transport (ADR/RID) Inland waterways transport (ADN) Marine transport (IMDG) Air transport (ICAO) Environmental hazards ENVIRONMENTALLY HAZARDOUS: Special precautions for user No-one Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. SECTION 15: Regulatory information no Safety, health and environmental regulations/legislation specific for the substance or mixture

7 Page 7 of 7 National regulatory information Water contaminating class (D): Chemical safety assessment 1 - slightly water contaminating For this substance a chemical safety assessment has not been carried out. SECTION 16: Other information Relevant R-phrases (Number and full text) 22 Harmful if swallowed. 23/24/25 Toxic by inhalation, in contact with skin and if swallowed. 34 Causes burns. 38 Irritating to skin. 41 Risk of serious damage to eyes. 43 May cause sensitisation by skin contact. 50 Very toxic to aquatic organisms. 53 May cause long-term adverse effects in the aquatic environment. Relevant H- and EUH-phrases (Number and full text) H301 Toxic if swallowed. H302 Harmful if swallowed. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H331 Toxic if inhaled. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. EUH208 Contains Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no ] and 2-methyl-2H-isothiazol-3-one [EC no ] (3:1). May produce an allergic reaction. Further Information The processing and application notes are on the technical leaflets to the products. The details are based on today's stand of our knowledge, they don't represent any assurance of product qualities, however, and don't justify any contractual facts of the case. The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)