: U-POL GRAVITEX PLUS - BLACK (GRA/NB1-AU)

Transcription

1 Date of issue:07/12/2016 Revision date: : Version: 1.0 SECTION 1: Identification : Product identifier and chemical identity Product name : Other means of identification : GRA/NB1 Company identification : U-POL AUSTRALIA PTY LIMITED Unit A, Cassola Place Penrith, NSW Australia T F technical.depatment@u-pol.com - Emergency telephone number : + (61) SECTION 2: Hazards identification 2.1. Classification of the hazardous chemical Classification (GHS-AU) Flam. Liq. 3 H226 Skin Irrit. 2 H315 STOT RE 2 H Label elements Hazard pictograms (GHS-AU) : Signal word (GHS-AU) Contains Hazard statements (GHS-AU) Precautionary statements (GHS-AU) Additional hazard statements (GHS-AU) : Warning Flame Exclamation mark Health hazard : ethylbenzene : H226 - Flammable liquid and vapour H315 - Causes skin irritation H373 - May cause damage to organs through prolonged or repeated exposure : P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking P260 - Do not breathe vapours, fume P264 - Wash hands thoroughly after handling P280 - Wear eye protection, protective gloves, protective clothing P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P314 - Get medical advice/attention if you feel unwell : AUH066 - Repeated exposure may cause skin dryness or cracking 2.3. Other hazards SECTION 3: Composition/information on ingredients Name CAS No Compound type % ethylbenzene SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the victim to rest. : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Get medical advice/attention. If skin irritation or rash occurs: Get medical advice/attention. 16/12/2016 EN (English) SDS ID: GRA/NB1-AU 1/7

2 First-aid measures after eye contact First-aid measures after ingestion 4.2. Symptoms caused by exposure Symptoms/injuries Symptoms/injuries after inhalation Symptoms/injuries after skin contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. : Causes damage to organs. : May cause an allergic skin reaction. May cause cancer by inhalation. : Repeated exposure to this material can result in absorption through skin causing significant health hazard. Harmful in contact with skin. Causes skin irritation Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture Fire hazard Explosion hazard General measures : Flammable liquid and vapour. : May form flammable/explosive vapour-air mixture Special protective equipment and precautions for fire-fighters Firefighting instructions Protection during firefighting Hazchemcode : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment. : Do not enter fire area without proper protective equipment, including respiratory protection. : 3YE SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking For non-emergency personnel Protective equipment Emergency procedures For emergency responders Protective equipment Emergency procedures : Safety glasses. Protective clothing. Gloves. : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up For containment Methods for cleaning up : Contain leaking substance. Collect spillage. : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. SECTION 7: Handling and storage, including how the chemical may be safely used 7.1. Precautions for safe handling Additional hazards when processed Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Handle empty containers with care because residual vapours are flammable. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. No open flames. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools. Avoid breathing spray, vapours. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. : Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. : Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical, Lighting equipment equipment. 16/12/2016 EN (English) 2/7

3 Storage conditions Incompatible products Incompatible materials Storage temperature : < 25 C Storage area Special rules on packaging : Keep only in the original container in a cool, well ventilated place away from : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking, Ignition sources, Heat sources. Keep container tightly closed. : Strong bases. Strong acids. : Sources of ignition. Direct sunlight. Heat sources. : Store in well ventilated area. : Keep only in original container. SECTION 8: Exposure controls/personal protection 8.1. Control parameters - exposure standards ethylbenzene ( ) Australia Local name Ethyl benzene Australia TWA (mg/m³) 434 mg/m³ Australia TWA (ppm) 100 ppm Australia STEL (mg/m³) 543 mg/m³ Australia STEL (ppm) 125 ppm Exposure limit values for the other components 8.2. Monitoring 8.3. Appropriate engineering controls 8.4. Personal protective equipment Personal protective equipment Materials for protective clothing Hand protection Eye protection Skin and body protection Respiratory protection : Avoid all unnecessary exposure. Gloves. Protective clothing. Safety glasses. : Impermeable clothing : Wear protective gloves : Chemical goggles or safety glasses : Wear suitable protective clothing : Wear appropriate mask : Do not eat, drink or smoke during use SECTION 9: Physical and chemical properties Physical state : Liquid Appearance : Viscous. Liquid. Colour : Black. Odour : characteristic. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point / Freezing point Boiling point Flash point : 26 C Auto-ignition temperature Flammability (solid, gas) Vapour pressure Relative density 16/12/2016 EN (English) 3/7

4 Density : Density : Solubility Log Pow Viscosity Explosive properties Explosive limits Minimum ignition energy VOC content - Regulatory SECTION 10: Stability and reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : insoluble in water. soluble in most organic solvents. : Flammable liquid and vapour. May form flammable/explosive vapour-air mixture. : Not established SECTION 11: Toxicological information Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) : Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks. : Strong acids. Strong bases. : fume. Carbon monoxide. Carbon dioxide. May release flammable gases. Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity : Causes skin irritation. Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard : May cause damage to organs through prolonged or repeated exposure. Density Potential adverse human health effects and symptoms : Harmful in contact with skin. Based on available data, the classification criteria are not met SECTION 12: Ecological information According to the National Code of Practice for the Preparation of Material s mandatory. Information relevant for GHS classification is available on request Ecotoxicity Acute aquatic toxicity Chronic aquatic toxicity : Avoid release to the environment., Environmental classification information is not Persistence and degradability Persistence and degradability Not established Bioaccumulative potential Bioaccumulative potential Not established Mobility in soil Other adverse effects Ozone Other adverse effects : 16/12/2016 EN (English) 4/7

5 Fluorinated greenhouse gases False ethylbenzene ( ) Fluorinated greenhouse gases False SECTION 13: Disposal considerations Regional legislation (waste) Waste treatment methods Product/Packaging disposal recommendations Additional information Ecology - waste materials SECTION 14: Transport information UN number UN-No. (ADG) : 1263 UN-No. (IMDG) : 1263 UN-No. (IATA) : 1263 : Disposal must be done according to official regulations. : Dispose of contents/container in accordance with licensed collector s sorting instructions. : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to Remove waste in accordance with local and/or national regulations. : Handle empty containers with care because residual vapours are flammable. : Avoid release to the environment Proper Shipping Name - Addition Proper Shipping Name (ADG) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) : PAINT : PAINT : Paint Transport hazard class(es) ADG Transport hazard class(es) (ADG) : 3 Danger labels (ADG) : 3 : IMDG Transport hazard class(es) (IMDG) : 3 Danger labels (IMDG) : 3 : IATA Transport hazard class(es) (IATA) : 3 Hazard labels (IATA) : 3 : Packing group Packing group (ADG) Packing group (IMDG) Packing group (IATA) Environmental hazards Marine pollutant Special precautions for user Specific storage requirement : III : III : III : No 16/12/2016 EN (English) 5/7

6 Shock sensitivity Additional information : No supplementary information available Transport by road and rail UN-No. (ADG) : 1263 Special provision (ADG) : 163, 223 Limited quantities (ADG) Packing instructions (ADG) Special packing provisions (ADG) Portable tank and bulk container instructions (ADG) Portable tank and bulk container special provisions (ADG) Transport by sea : 5l : P001, IBC03, LP01 : PP1 : T2 : TP1, TP29 UN-No. (IMDG) : 1263 Special provisions (IMDG) : 163, 223, 955 Limited quantities (IMDG) : 5 L Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P001, LP01 Special packing provisions (IMDG) : PP1 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T2 Tank special provisions (IMDG) : TP1, TP29 EmS-No. (Fire) : F-E - FIRE SCHEDULE Echo - NON-WATER-REACTIVE FLAMMABLE LIQUIDS EmS-No. (Spillage) : S-E - SPILLAGE SCHEDULE Echo - FLAMMABLE LIQUIDS, FLOATING ON WATER Stowage category (IMDG) : A Properties and observations (IMDG) : Miscibility with water depends upon the composition. Air transport UN-No. (IATA) : 1263 PCA Excepted quantities (IATA) PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) : E1 : Y344 : 10L PCA packing instructions (IATA) : 355 PCA max net quantity (IATA) : 60L CAO packing instructions (IATA) : 366 CAO max net quantity (IATA) Special provisions (IATA) ERG code (IATA) Hazchem or Emergency Action Code Hazchemcode SECTION 15: Regulatory information : 220L : A3, A72, A192 : 3L : 3YE Safety, health and environmental regulations/legislation specific for the substance or mixture Listed on the AICS (Australian Inventory of Chemical Substances) International agreements SECTION 16: Any other relevant information : Listed on the AICS (Australian Inventory of Chemical Substances) : None. Classification: Flam. Liq. 3 H226 Skin Irrit. 2 H315 STOT RE 2 H373 16/12/2016 EN (English) 6/7

7 Full text of H-statements: Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4 Asp. Tox. 1 Aspiration hazard, Category 1 Flam. Liq. 2 Flammable liquids, Category 2 Flam. Liq. 3 Flammable liquids, Category 3 Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT RE 2 Specific target organ toxicity Repeated exposure, Category 2 H225 H226 H304 H315 H332 H373 Highly flammable liquid and vapour Flammable liquid and vapour May be fatal if swallowed and enters airways Causes skin irritation Harmful if inhaled May cause damage to organs through prolonged or repeated exposure SDS Australia U-POL For professional use only. The information contained within this (SDS) is believed to be correct as of the date issued however it is subject to change from time to time. It does not purport to be all inclusive or exhaustive and shall only be used as a guide. U-POL makes no warranties, expressed or implied, including but not limited to, any implied warranty of fitness for a given purpose or usage. It is the Buyers responsibility to ensure the suitability of the products for their own use and to check the information is up to date. U-POL cannot be held responsible for the suitability of use for any of its products, considering the wide range of factors such as application, substrates and handling methods. Since these conditions of use are outside of our control, the company shall not be held liable for any damage resulting from handling or from contact with the product detailed. Moreover, addition of reducers, hardeners or other additives over and above U-POL s recommendations for use, may substantially alter the composition and hazards of the product. U-POL data sheets are available via the U-POL website at 16/12/2016 EN (English) 7/7