: U-POL ACID #8 ETCH PRIMER (ACID-AU)

Transcription

1 Date of issue:01/02/2017 Revision date:07/11/2017 Supersedes: 01/02/2017 Version: 2.0 SECTION 1: Identification : Product identifier and chemical identity Product name : U-POL ACID #8 ETCH PRIMER (ACID-AU) Other means of identification : ACID/1 Company identification : U-POL AUSTRALIA PTY LIMITED Unit A, Cassola Place Penrith, NSW Australia T F technical.depatment@u-pol.com - Emergency telephone number : + (61) SECTION 2: Hazards identification 2.1. Classification of the hazardous chemical Classification (GHS-AU) Flam. Liq. 3 H226 Acute Tox. 4 (Oral) H302 Skin Irrit. 2 H315 Eye Dam. 1 H318 STOT SE 3 H336 STOT SE 3 H Label elements Hazard pictograms (GHS-AU) : Signal word (GHS-AU) : Danger Flame Corrosion Exclamation mark Contains : butan-1-ol (23-43 %); 2-methylpropan-1-ol, iso-butanol (< 5 %); toluene (< 5 %); 2- methoxypropanol (< 5 %); 1-methoxy-2-propanol, monopropylene glycol methyl ether (5-23 %) Hazard statements (GHS-AU) Precautionary statements (GHS-AU) 2.3. Other hazards SECTION 3: Composition/information on ingredients : H226 - Flammable liquid and vapour. H302 - Harmful if swallowed. H315 - Causes skin irritation. H318 - Causes serious eye damage. H335 - May cause respiratory irritation. H336 - May cause drowsiness or dizziness. : P210 - Keep away from heat, hot surfaces, open flames, sparks. No smoking. P261 - Avoid breathing fume, vapours, spray. P264 - Wash hands thoroughly after handling. P280 - Wear eye protection, protective clothing, protective gloves. P308+P313 - IF exposed or concerned: Get medical advice/attention. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation Name CAS-No. Compound type % butan-1-ol methoxy-2-propanol, monopropylene glycol methyl ether methylpropan-1-ol, iso-butanol < 5 2-methoxypropanol < 5 bisphenol-a-(epichlorhydrin), epoxy resin < 5 07/11/2017 EN (English) SDS ID: ACID-AU 1/8

2 Name CAS-No. Compound type % toluene < 5 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion 4.2. Symptoms caused by exposure Symptoms/effects Symptoms/effects after inhalation Symptoms/effects after skin contact Symptoms/effects after eye contact : Call a poison center or a doctor if you feel unwell. : Remove person to fresh air and keep comfortable for breathing. Call a poison center or a doctor if you feel unwell. : Rinse skin with water/shower. Take off immediately all contaminated clothing. If skin irritation occurs: Get medical advice/attention. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician immediately. : Rinse mouth. Call a poison center or a doctor if you feel unwell. : May cause drowsiness or dizziness. : May cause respiratory irritation. : Irritation. : Serious damage to eyes Indication of any immediate medical attention and special treatment needed Other medical advice or treatment : Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide Special hazards arising from the substance or mixture Fire hazard : Flammable liquid and vapour Special protective equipment and precautions for fire-fighters Protection during firefighting Hazchemcode : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. : 3YE SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment Emergency procedures For emergency responders Protective equipment : Safety glasses. Protective clothing. Gloves. : Ventilate spillage area. No open flames, no sparks, and no smoking. Avoid breathing vapours, fume. Avoid contact with skin and eyes. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up For containment Methods for cleaning up : Contain released substance, pump into suitable containers. Collect spillage. : Take up liquid spill into absorbent material. Notify authorities if product enters sewers or public waters. SECTION 7: Handling and storage, including how the chemical may be safely used 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Flammable vapours may accumulate in the container. Use explosion-proof equipment. Wear personal protective equipment. Use only outdoors or in a well-ventilated area. Avoid breathing vapours, fume. Avoid contact with skin and eyes. : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. : Ground/bond container and receiving equipment. 07/11/2017 EN (English) 2/8

3 Storage conditions Storage temperature : < 25 C Storage area Special rules on packaging : Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. : Store in a well-ventilated place. : Keep only in original container. SECTION 8: Exposure controls/personal protection 8.1. Control parameters - exposure standards butan-1-ol ( ) Australia Local name n-butyl alcohol Australia OEL - Ceilings (mg/m³) 152 mg/m³ Australia OEL - Ceilings (ppm) 50 ppm 2-methylpropan-1-ol, iso-butanol ( ) Australia Local name Isobutyl alcohol Australia TWA (mg/m³) 152 mg/m³ Australia TWA (ppm) 50 ppm toluene ( ) Australia Local name Toluene Australia TWA (mg/m³) 191 mg/m³ Australia TWA (ppm) 50 ppm Australia STEL (mg/m³) 574 mg/m³ Australia STEL (ppm) 150 ppm 1-methoxy-2-propanol, monopropylene glycol methyl ether ( ) Australia Local name Propylene glycol monomethyl ether Australia TWA (mg/m³) 369 mg/m³ Australia TWA (ppm) 100 ppm Australia STEL (mg/m³) 553 mg/m³ Australia STEL (ppm) 150 ppm Exposure limit values for the other components 8.2. Monitoring 8.3. Appropriate engineering controls Appropriate engineering controls : Ensure good ventilation of the work station Personal protective equipment Personal protective equipment Materials for protective clothing Hand protection Eye protection Skin and body protection Respiratory protection : Gloves. Protective clothing. Safety glasses. : Impermeable clothing : Protective gloves : Safety glasses : Wear suitable protective clothing : In case of insufficient ventilation, wear suitable respiratory equipment Environmental exposure controls : Avoid release to the environment SECTION 9: Physical and chemical properties Physical state : Liquid 07/11/2017 EN (English) 3/8

4 Appearance : Liquid. Colour : Light grey. Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point / Freezing point : Melting point : Not applicable Boiling point : > 35 C Flash point : 23 C Auto-ignition temperature Flammability (solid, gas) Vapour pressure Relative density Density : Density : Solubility : insoluble in water. soluble in most organic solvents. Log Pow Viscosity Explosive properties Explosive limits Minimum ignition energy VOC content - Regulatory SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Hazardous decomposition products SECTION 11: Toxicological information Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) : Flammable liquid and vapour.flammable liquid and vapour. : Stable under normal conditions. : No dangerous reactions known under normal conditions of use. : Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition. : Under normal conditions of storage and use, hazardous decomposition products should not be produced. : Oral: Harmful if swallowed. ATE AU (oral) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard mg/kg bodyweight : Causes skin irritation. : Causes serious eye damage. : May cause drowsiness or dizziness. May cause respiratory irritation. U-POL ACID #8 ETCH PRIMER (ACID-AU) Density SECTION 12: Ecological information According to the National Code of Practice for the Preparation of Material s, Environmental classification information is not mandatory. Information relevant for GHS classification is available on request Ecotoxicity Ecology - general Acute aquatic toxicity : The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment. 07/11/2017 EN (English) 4/8

5 Chronic aquatic toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects Ozone Other adverse effects U-POL ACID #8 ETCH PRIMER (ACID-AU) butan-1-ol ( ) : 2-methylpropan-1-ol, iso-butanol ( ) toluene ( ) 2-methoxypropanol ( ) 1-methoxy-2-propanol, monopropylene glycol methyl ether ( ) bisphenol-a-(epichlorhydrin), epoxy resin ( ) SECTION 13: Disposal considerations Regional legislation (waste) : Disposal must be done according to official regulations. Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions. Additional information : Flammable vapours may accumulate in the container. SECTION 14: Transport information UN number UN-No. (ADG) : 1263 UN-No. (IMDG) : 1263 UN-No. (IATA) : Proper Shipping Name - Addition Proper Shipping Name (ADG) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) : PAINT : PAINT : Paint Transport hazard class(es) ADG Transport hazard class(es) (ADG) : 3 Danger labels (ADG) : 3 : IMDG 07/11/2017 EN (English) 5/8

6 Transport hazard class(es) (IMDG) : 3 Danger labels (IMDG) : 3 : IATA Transport hazard class(es) (IATA) : 3 Hazard labels (IATA) : 3 : Packing group Packing group (ADG) Packing group (IMDG) Packing group (IATA) Environmental hazards Marine pollutant Special precautions for user Specific storage requirement Shock sensitivity Additional information Other information : III : III : III : No : No supplementary information available Transport by road and rail UN-No. (ADG) : 1263 Special provision (ADG) : 163, 223 Limited quantities (ADG) Packing instructions (ADG) Special packing provisions (ADG) Portable tank and bulk container instructions (ADG) Portable tank and bulk container special provisions (ADG) Transport by sea : 5l : P001, IBC03, LP01 : PP1 : T2 : TP1, TP29 UN-No. (IMDG) : 1263 Special provisions (IMDG) : 163, 223, 955 Limited quantities (IMDG) : 5 L Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P001, LP01 Special packing provisions (IMDG) : PP1 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T2 Tank special provisions (IMDG) : TP1, TP29 EmS-No. (Fire) : F-E - FIRE SCHEDULE Echo - NON-WATER-REACTIVE FLAMMABLE LIQUIDS EmS-No. (Spillage) : S-E - SPILLAGE SCHEDULE Echo - FLAMMABLE LIQUIDS, FLOATING ON WATER Stowage category (IMDG) : A Properties and observations (IMDG) : Miscibility with water depends upon the composition. Air transport 07/11/2017 EN (English) 6/8

7 UN-No. (IATA) : 1263 PCA Excepted quantities (IATA) PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) : E1 : Y344 : 10L PCA packing instructions (IATA) : 355 PCA max net quantity (IATA) : 60L CAO packing instructions (IATA) : 366 CAO max net quantity (IATA) Special provisions (IATA) ERG code (IATA) Hazchem or Emergency Action Code Hazchemcode SECTION 15: Regulatory information : 220L : A3, A72, A192 : 3L : 3YE Safety, health and environmental regulations/legislation specific for the substance or mixture Listed on the AICS (Australian Inventory of Chemical Substances) International agreements SECTION 16: Any other relevant information Revision date : 07/11/2017 Classification: Flam. Liq. 3 Acute Tox. 4 (Oral) Skin Irrit. 2 Eye Dam. 1 STOT SE 3 STOT SE 3 Full text of H-statements: : Listed on the AICS (Australian Inventory of Chemical Substances) H226 H302 H315 H318 H336 H335 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Chronic 2 Hazardous to the aquatic environment Chronic Hazard, Category 2 Asp. Tox. 1 Aspiration hazard, Category 1 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Flam. Liq. 2 Flammable liquids, Category 2 Flam. Liq. 3 Flammable liquids, Category 3 Repr. 1B Reproductive toxicity, Category 1B Repr. 2 Reproductive toxicity, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 Skin Sens. 1 Skin sensitisation, Category 1 STOT RE 2 Specific target organ toxicity Repeated exposure, Category 2 STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Narcosis STOT SE 3 H225 H226 H302 H304 H315 H317 H318 H335 H336 H360 H361 H373 H411 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation Highly flammable liquid and vapour. Flammable liquid and vapour. Harmful if swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. May cause respiratory irritation. May cause drowsiness or dizziness. May damage fertility or the unborn child. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Toxic to aquatic life with long lasting effects. SDS Australia U-POL 07/11/2017 EN (English) 7/8

8 For professional use only. The information contained within this (SDS) is believed to be correct as of the date issued however it is subject to change from time to time. It does not purport to be all inclusive or exhaustive and shall only be used as a guide. U-POL makes no warranties, expressed or implied, including but not limited to, any implied warranty of fitness for a given purpose or usage. It is the Buyers responsibility to ensure the suitability of the products for their own use and to check the information is up to date. U-POL cannot be held responsible for the suitability of use for any of its products, considering the wide range of factors such as application, substrates and handling methods. Since these conditions of use are outside of our control, the company shall not be held liable for any damage resulting from handling or from contact with the product detailed. Moreover, addition of reducers, hardeners or other additives over and above U-POL s recommendations for use, may substantially alter the composition and hazards of the product. U-POL data sheets are available via the U-POL website at 07/11/2017 EN (English) 8/8