Safety Data Sheet. Page 1 of 6. MSDS for # MOLOTOW MASK MARKER. physical effects. and chemical properties. Accidental release measures.

Transcription

1 Page 1 of 6 Safety Data Sheet Specific Mixtures. Reference Persistence R50 gravity. to other and degradability. VERY sections. TOXIC TO AQUATIC ORGANISMS. 1,050 Kg/l Any Information Solubility information not available. on personal protection and disposal very is given soluble in sections 8 and Contains: Partition Identification coefficient: of the n-octanol/water substance/mixture and Not of the available. company/undertaking GENERAL Ignition Handling Bioaccumulative temperature. BIBLIOGRAPHY and storage. potential Identification. Information Decomposition Product Directive identifier 1999/45/EC not temperature. available. and Conc. following %. amendments Classification Not 67/548/EEC. available. Classification 1272/2008 (CLP) Viscosity Precautions Directive 67/548/EEC for safe handling. following amendments and 3-5 adjustments cps a 25 C Do Code: Reactive Regulation Mobility not smoke Properties in (EC) soil. while 1907/2006 handling and (REACH) use. of the European PLY Parliament 4. Information CAS ,5-5 C R34, N R50, Note B Skin Corr. 1B H314, STOT SE 3 H335, Aquatic Acute 1 H400, Note B Product Regulation name not (EC) available. 1272/2008 (CLP) of the European PEELY Parliament INKS EC. Other Conditions Regulation information (EC) safe 790/2009 storage, (I Atp. including CLP) of any the incompatibilities. European Parliament Store VOC INDEX. Relevant Regulation Results (Directive in a well of identified (EC) PBT ventilated 1999/13/EC) 453/2010 and uses vpvb place, of : of assessment. the the keep substance European far away Parliament or from mixture sources 10,00 and % of - uses heat, 105,00 advised bright flames against g/litre. and sparks and other sources of ignition. 7. Information VOC The (volatile Merck not Index. carbon) available. - 10th : Edition 4,73 % - 49,68 g/litre. T+ = Very Toxic(T+), T = Toxic(T), Xn = Harmful(Xn), C = Corrosive(C), Xi = Irritant(Xi), O = Oxidizing(O), E = Explosive(E), F+ = Extremely Flammable(F+), F = Highly Flammable(F) Intended Specific Handling use end Chemical use(s). Safety PEELY INKS FOR VALVE MARKERS Information Stability Niosh Other - adverse Registry not and available. reactivity. effects. of Toxic Effects of Chemical Substances The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet Information Details INRS of - Fiche not the available. supplier Toxicologique of the (toxicological safety data sheet sheet) Exposure Reactivity. Patty - Industrial controls/personal Hygiene and Toxicology protection There First Disposal N.I. aid are Sax no measures. - considerations. particular Dangerous risks properties of reaction of Industrial with other Materials-7, substances MOLOTOW 1989 in DISTRIBUTION normal Editionconditions of use Name Control parameters. Feuerstein REINOL s.p.a. GmbH : Description of first aid measures. Full Waste address treatment corrodes methods. aluminium, iron, zinc, copper and Willy-Brandt-Str. S.da their del alloys. Francese 9/2 21 Note POLYETHYLENGLYCOL: EYES: Wash immediately with plenty of water for at least 15 minutes and seek medical advice at once. Reuse, District Namefor and when users: Country possible. Neat decomposes product residues slowly should at high D be temperatures considered Type Borgaro Lahr / in special Schwarzwald T.se the CountryTWA/8h presence non-hazardous of Germany air. waste. (TO) STEL/15min The 1,2-PROPANEDIOL: SKIN: Disposal information Immediately must be contained performed take it off is all hygroscopic in through contaminated the present an authorised and clothing sheet stable waste Tel.: are and under based +49 have management normal a shower. Seek medical advice. Italia (0) on 7821 our conditions; - firm, own in knowledge compliance 0mg/m3 at high temperatures on with the ppm national date it mg/m3 of tends and the local to last oxidate regulations. version. ppm to form Users propionaldehyde must verify the suitability INGESTION: and CONTAMINATED lactic and thoroughness acetic Have PACKAGING acid. the patient of provided drink water information as much Fax: as possible and seek medical advice immediately. Do not induce vomiting before Tel. according (0) to each specific use 99of the product. This consulting Contaminated a doctor. document packaging must not be must regarded be recovered as a guarantee or disposed Fax on any of TLV-ACGIH in specific +39 compliance 011 product with property. national waste management 25 regulations The INHALATION: Immediately seek medical advice. In the meantime, remove the patient to open air, far from the contaminated premises; if Chemical use address of stability. this of the product competent is not person subject to our direct control; therefore, users must, under their own responsibility, comply with the current health respiration stops or is difficult, give an artificial respiration adopting the proper measure for the helper. 14. and The responsible Transport safety product laws for is information. stable the and Safety regulations. normal Data conditions Sheet The producer of use is and relieved m.reith@molotow.com massi@reinol.it storage. from any liability arising from improper uses Exposure controls Most important symptoms and effects, both acute and delayed Changes The Emergency Possibility product to previous telephone is of not hazardous review: dangerous number reactions. under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail The For symptoms and effects caused by contained substances see chap. 11. As (RID), the vapours following of use the may International of sections adequate also form were Maritime technical explosive modified: Dangerous mixtures equipment with Goods must the Code air. always (IMDG), take and priority of the over International personal protection Air Transport equipment, Association make (IATA) sure that regulations. the workplace is 09 For well / urgent 10 aired / 11. through inquiries effective refer to local aspiration or bad air vent. 011 (0) Indication of any immediate medical attention and special treatment needed. 15. : HAND PROTECTION Follow Regulatory risk doctor's information. of explosion on contact with strong acids and iodine. Can react dangerously with strong bases. orders. 2. 1,2-PROPANEDIOL: Protect Hazards hands identification. with category can react I dangerously (ref. Directive with: 89/686/EEC acid chlorides, and acid standard anhydrides EN 374) and oxidising work gloves, agents. such as those in latex, PVC or equivalent. The following should be considered when choosing work glove material: degradation, breakage times and permeation. Work glove resistance to preparations Firefighting Conditions Safety, health should measures. to avoid. and be environmental checked before regulations/legislation use, as it can be unpredictable. specific Gloves for the limit substance depends or on mixture. the duration of exposure SKIN Avoid Classification PROTECTION overheating, of electrostatic the substance discharge or mixture. and all sources of ignition Seveso Wear Extinguishing category. I media. professional long-sleeved overalls and safety footwear (ref. Directive 89/686/CEE and standard EN 344). Wash body with soap SUITABLE EXTINGUISHING MEDIA The Incompatible product and water is not after materials. classified removing as overalls. hazardous pursuant to the provisions set forth in Directives 67/548/EEC and 1999/45/EC and/or EC Restrictions RESPIRATORY The extinction equipment should be of the conventional kind: carbon dioxide, foam, powder and nebulised water. Regulation : 1272/2008 relating silver, PROTECTION lead, to the (CLP) zinc product and (and or their subsequent contained salts; hydrochloric substances amendments pursuant acid, and nitric supplements). to Annex acid, oleum, XVII to However, halogens, EC Regulation since acrolein, 1907/2006. the product nitromethane contains and hazardous acrylic acid. substances EXTINGUISHING MEDIA WHICH SHALL NOT BE USED FOR SAFETY REASONS If in POLYETHYLENGLYCOL: concentrations the threshold value such as for to avoid one be declared contact or more with in of section oxidising the substances no. agents 3, it requires and present concentrated a safety in the data preparation inorganic sheet with acids. for appropriate daily exposure information, the compliant workplace to EC or to a fraction None in particular. established Regulation 1907/2006 by the company s and subsequent prevention amendments. and protection service is exceeded, wear a mask with an A or universal filter, the class (1, 2 or 3) of which Hazardous must be decomposition chosen according products. to the limit concentration of use (ref. standard EN 141) Special hazards arising from the substance or mixture Substances The In Label the use event elements. of in of breathing Candidate thermal decomposition List protection (Art. 59 equipment, REACH). or fire, vapours such as potentially masks dangerous with organic to health vapour may and be dust/mist released. cartridges, is necessary in the absence of technical HAZARDS measures CAUSED limiting BY EXPOSURE worker exposure. IN THE The EVENT protection OF FIRE provided by masks is in any case limited. If Do not breathe combustion products (carbon oxide, toxic pyrolysis products, etc). This : the product substance nitric is oxides. in not question subject is to odourless hazard labeling or its olfactory pursuant threshold to Directives is higher 67/548/EEC than the relative and exposure 1999/45/EC limit and and subsequent in the event amendments of an emergency, and or supplements. 1,2-PROPANEDIOL: when exposure levels carbon are oxides. unknown or the concentration of oxygen in the workplace is less than 17% volume, wear self-contained, 5.3. Substances open-circuit Advice for subject firefighters. compressed to authorisarion air breathing (Annex apparatus XIV REACH). (ref. standard EN 137) or fresh air hose breathing apparatus for use with full face mask, half 11. mask GENERAL Toxicological or mouthpiece INFORMATION information. (ref. standard EN 138). EYE Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for Warning PROTECTION symbols: Use health. According of protective Always to currently wear airtight full available goggles fire prevention (ref. data, standard this gear. product EN Collect 166) has recommended. extinguishing not yet produced water health to prevent damages. it from Anyway, draining it must into be the handled sewer carefully system. according Dispose of to Healthcare contaminated water used for extinction and the remains of the fire according to applicable regulations. good industrial controls. Hazard sentences practices. (R): This product may have slight health effects on sensitive people, by inhalation and/or cutaneous absorption and/or SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS 9. contact Information Physical with not and eyes available. chemical and/or ingestion. properties. Hardhat with visor, fireproof clothing (fireproof jacket and trousers with straps around arms, legs and waist), work gloves (fireproof, cut proof Caution recommendations (S): and dielectric), a depressurised mask with facemask covering the whole of the operator s face or a self-respirator (self-protector) in the event Information Chemical safety on on basic toxicological assessment. physical effects. and chemical properties. of large quantities of fume. Appearance liquid Safety Colour LD50 No chemical (Oral): data sheet safety 350 available assessment mg/kg upon Rathas request been for processed professional Not for available. the users. mixture and the substances it contains. 6. Odour 1,2-PROPANEDIOL Accidental release measures. amine 16. Odour LD50 Other (Oral): threshold. information mg/kg Rat ph. LD50 Other Personal (Dermal): hazards. precautions, mg/kg protective Rat equipment and 11emergency procedures. Eliminate Melting Text of hazard or freezing all sources (H) indications point. of ignition mentioned (cigarettes, in section flames, 2-3 Not of available. sparks, the sheet: etc.) from the leakage site. If there are no contraindications, spray solid products 12. with Information Boiling Ecological water point. not to information. prevent available. the formation of dust. > Use 100 breathing C. equipment if fumes or powders are released into the air. Block the leakage if there Distillation no Skin hazard. Corr. range. 1BDo not Skin handle corrosion, damaged category containers 1B Not or available. the leaked product before donning appropriate protective gear. For information on risks for STOT the environmental SE 3 and health, respiratory tract protection, ventilation and personal protection equipment, see the other sections of this Flash No specific point. data are Specific available target for organ this toxicity product. > - single Handle 100 exposure, it according C. category to good 3 3. Composition/information working practices. Avoid littering. Do not contaminate soil, sewers sheet. Aquatic Acute 1 Hazardous on to ingredients. the aquatic environment, acute toxicity category 1 Evaporation and waterways. Rate Inform the competent authorities, Not should available. the product reach waterways or sewers or contaminate soil or vegetation. Please H314 Causes severe skin burns and eye damage Flammability take Substances. all the proper of solids measures and gases to reduce harmful effects Not on available. aquifers Lower Environmental H335 Toxicity. inflammability precautions. May cause respiratory irritation. H400 limit. The product must not Very penetrate toxic to the aquatic sewers, life. surface water, ground water and neighbouring areas. Upper Information inflammability not relevant. limit. Lower explosive limit Text Upper LC50 Methods of risk (96h): explosive and (R) phrases material mentioned limit. 47 mg/l/96h for containment in section Channa punctata and 2-3 cleaning of the sheet: up. Use Vapour EC50 inert (48h): pressure. absorbent 20 mg/l/48h material Daphnia (sand, magna vermiculite, Not diatomeous available. earth, Kieselguhr, etc.) to soak up leaked product. Collect the majority of the R34 CAUSES BURNS. Vapour remaining density material and deposit it in containers for disposal. If there are no contraindications, use jets of water to eliminate product residues. Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13. Item Numbers: , , Page 1 of 6

2 Page 2 of Mixtures. Contains: Identification. Conc. %. Classification 67/548/EEC. Classification 1272/2008 (CLP). CAS ,5-5 C R34, N R50, Note B Skin Corr. 1B H314, STOT SE 3 H335, Aquatic Acute 1 H400, Note B EC INDEX T+ = Very Toxic(T+), T = Toxic(T), Xn = Harmful(Xn), C = Corrosive(C), Xi = Irritant(Xi), O = Oxidizing(O), E = Explosive(E), F+ = Extremely Flammable(F+), F = Highly Flammable(F) The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet. 4. First aid measures Description of first aid measures. EYES: Wash immediately with plenty of water for at least 15 minutes and seek medical advice at once. SKIN: Immediately take off all contaminated clothing and have a shower. Seek medical advice. INGESTION: Have the patient drink water as much as possible and seek medical advice immediately. Do not induce vomiting before consulting a doctor. INHALATION: Immediately seek medical advice. In the meantime, remove the patient to open air, far from the contaminated premises; if respiration stops or is difficult, give an artificial respiration adopting the proper measure for the helper Most important symptoms and effects, both acute and delayed. For symptoms and effects caused by contained substances see chap Indication of any immediate medical attention and special treatment needed. Follow doctor's orders. 5. Firefighting measures Extinguishing media. SUITABLE EXTINGUISHING MEDIA The extinction equipment should be of the conventional kind: carbon dioxide, foam, powder and nebulised water. EXTINGUISHING MEDIA WHICH SHALL NOT BE USED FOR SAFETY REASONS None in particular Special hazards arising from the substance or mixture. HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE Do not breathe combustion products (carbon oxide, toxic pyrolysis products, etc) Advice for firefighters. GENERAL INFORMATION Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated water used for extinction and the remains of the fire according to applicable regulations. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS Hardhat with visor, fireproof clothing (fireproof jacket and trousers with straps around arms, legs and waist), work gloves (fireproof, cut proof and dielectric), a depressurised mask with facemask covering the whole of the operator s face or a self-respirator (self-protector) in the event of large quantities of fume. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures. Eliminate all sources of ignition (cigarettes, flames, sparks, etc.) from the leakage site. If there are no contraindications, spray solid products with water to prevent the formation of dust. Use breathing equipment if fumes or powders are released into the air. Block the leakage if there is no hazard. Do not handle damaged containers or the leaked product before donning appropriate protective gear. For information on risks for the environmental and health, respiratory tract protection, ventilation and personal protection equipment, see the other sections of this sheet Environmental precautions. The product must not penetrate the sewers, surface water, ground water and neighbouring areas Methods and material for containment and cleaning up. Use inert absorbent material (sand, vermiculite, diatomeous earth, Kieselguhr, etc.) to soak up leaked product. Collect the majority of the remaining material and deposit it in containers for disposal. If there are no contraindications, use jets of water to eliminate product residues. Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13. Item Numbers: , , Page 2 of 6

3 Page 3 of Reference to other sections. Any information on personal protection and disposal is given in sections 8 and Handling and storage Precautions for safe handling. Do not smoke while handling and use Conditions for safe storage, including any incompatibilities. Store in a well ventilated place, keep far away from sources of heat, bright flames and sparks and other sources of ignition Specific end use(s). 8. Exposure controls/personal protection Control parameters. Name Type Country TWA/8h STEL/15min mg/m3 ppm mg/m3 ppm TLV-ACGIH Exposure controls. As the use of adequate technical equipment must always take priority over personal protection equipment, make sure that the workplace is well aired through effective local aspiration or bad air vent. HAND PROTECTION Protect hands with category I (ref. Directive 89/686/EEC and standard EN 374) work gloves, such as those in latex, PVC or equivalent. The following should be considered when choosing work glove material: degradation, breakage times and permeation. Work glove resistance to preparations should be checked before use, as it can be unpredictable. Gloves limit depends on the duration of exposure. SKIN PROTECTION Wear category I professional long-sleeved overalls and safety footwear (ref. Directive 89/686/CEE and standard EN 344). Wash body with soap and water after removing overalls. RESPIRATORY PROTECTION If the threshold value for one or more of the substances present in the preparation for daily exposure in the workplace or to a fraction established by the company s prevention and protection service is exceeded, wear a mask with an A or universal filter, the class (1, 2 or 3) of which must be chosen according to the limit concentration of use (ref. standard EN 141). The use of breathing protection equipment, such as masks with organic vapour and dust/mist cartridges, is necessary in the absence of technical measures limiting worker exposure. The protection provided by masks is in any case limited. If the substance in question is odourless or its olfactory threshold is higher than the relative exposure limit and in the event of an emergency, or when exposure levels are unknown or the concentration of oxygen in the workplace is less than 17% volume, wear self-contained, open-circuit compressed air breathing apparatus (ref. standard EN 137) or fresh air hose breathing apparatus for use with full face mask, half mask or mouthpiece (ref. standard EN 138). EYE PROTECTION Use of protective airtight goggles (ref. standard EN 166) recommended. 9. Physical and chemical properties Information on basic physical and chemical properties. Appearance liquid Colour Odour amine Odour threshold. ph. 11 Melting or freezing point. Boiling point. > 100 C. Distillation range. Flash point. > 100 C. Evaporation Rate Flammability of solids and gases Lower inflammability limit. Upper inflammability limit. Lower explosive limit. Upper explosive limit. Vapour pressure. Vapour density Item Numbers: , , Page 3 of 6

4 Page 4 of 6 Specific gravity. 1,050 Kg/l Solubility very soluble Partition coefficient: n-octanol/water Ignition temperature. Decomposition temperature. Viscosity 3-5 cps a 25 C Reactive Properties 9.2. Other information. VOC (Directive 1999/13/EC) : 10,00 % - 105,00 g/litre. VOC (volatile carbon) : 4,73 % - 49,68 g/litre. 10. Stability and reactivity Reactivity. There are no particular risks of reaction with other substances in normal conditions of use. : corrodes aluminium, iron, zinc, copper and their alloys. POLYETHYLENGLYCOL: decomposes slowly at high temperatures in the presence of air. 1,2-PROPANEDIOL: it is hygroscopic and stable under normal conditions; at high temperatures it tends to oxidate to form propionaldehyde and lactic and acetic acid Chemical stability. The product is stable in normal conditions of use and storage Possibility of hazardous reactions. The vapours may also form explosive mixtures with the air. : risk of explosion on contact with strong acids and iodine. Can react dangerously with strong bases. 1,2-PROPANEDIOL: can react dangerously with: acid chlorides, acid anhydrides and oxidising agents Conditions to avoid. Avoid overheating, electrostatic discharge and all sources of ignition Incompatible materials. : silver, lead, zinc and their salts; hydrochloric acid, nitric acid, oleum, halogens, acrolein, nitromethane and acrylic acid. POLYETHYLENGLYCOL: avoid contact with oxidising agents and concentrated inorganic acids Hazardous decomposition products. In the event of thermal decomposition or fire, vapours potentially dangerous to health may be released. : nitric oxides. 1,2-PROPANEDIOL: carbon oxides. 11. Toxicological information. According to currently available data, this product has not yet produced health damages. Anyway, it must be handled carefully according to good industrial practices. This product may have slight health effects on sensitive people, by inhalation and/or cutaneous absorption and/or contact with eyes and/or ingestion Information on toxicological effects. LD50 (Oral): 350 mg/kg Rat 1,2-PROPANEDIOL LD50 (Oral): mg/kg Rat LD50 (Dermal): mg/kg Rat 12. Ecological information. No specific data are available for this product. Handle it according to good working practices. Avoid littering. Do not contaminate soil, sewers and waterways. Inform the competent authorities, should the product reach waterways or sewers or contaminate soil or vegetation. Please take all the proper measures to reduce harmful effects on aquifers Toxicity. LC50 (96h): EC50 (48h): 47 mg/l/96h Channa punctata 20 mg/l/48h Daphnia magna Item Numbers: , , Page 4 of 6

5 Page 5 of Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects. 13. Disposal considerations Waste treatment methods. Reuse, when possible. Neat product residues should be considered special non-hazardous waste. Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. CONTAMINATED PACKAGING Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. 14. Transport information. The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations. 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture. Seveso category. Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006. Substances in Candidate List (Art. 59 REACH). Substances subject to authorisarion (Annex XIV REACH). Healthcare controls Chemical safety assessment. No chemical safety assessment has been processed for the mixture and the substances it contains. 16. Other information. Text of hazard (H) indications mentioned in section 2-3 of the sheet: Skin Corr. 1B Skin corrosion, category 1B STOT SE 3 Specific target organ toxicity - single exposure, category 3 Aquatic Acute 1 Hazardous to the aquatic environment, acute toxicity category 1 H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H400 Very toxic to aquatic life. Text of risk (R) phrases mentioned in section 2-3 of the sheet: R34 CAUSES BURNS. Item Numbers: , , Page 5 of 6

6 Page 6 of 6 R50 VERY TOXIC TO AQUATIC ORGANISMS. GENERAL BIBLIOGRAPHY 1. Directive 1999/45/EC and following amendments 2. Directive 67/548/EEC and following amendments and adjustments 3. Regulation (EC) 1907/2006 (REACH) of the European Parliament 4. Regulation (EC) 1272/2008 (CLP) of the European Parliament 5. Regulation (EC) 790/2009 (I Atp. CLP) of the European Parliament 6. Regulation (EC) 453/2010 of the European Parliament 7. The Merck Index. - 10th Edition 8. Handling Chemical Safety 9. Niosh - Registry of Toxic Effects of Chemical Substances 10. INRS - Fiche Toxicologique (toxicological sheet) 11. Patty - Industrial Hygiene and Toxicology 12. N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition Note for users: The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability and thoroughness of provided information according to each specific use of the product. This document must not be regarded as a guarantee on any specific product property. The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health and safety laws and regulations. The producer is relieved from any liability arising from improper uses. Changes to previous review: The following sections were modified: 09 / 10 / 11. Item Numbers: , , Page 6 of 6