TRICHLOROETHYLENE MSDS TRICHLOROETHYLENE

Transcription

1 1 / 5 MSDS 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING PRODUCT NAME SYNONYMS, TRADE NAMES Triklone,, Trisec D, SUPPLIER Tianjin Feilintake Chemical Co.Ltd 7B,A Block,Huasheng Suqare,No 146 Weidi Road,Hexi District,PR.China Tel: Fax: HAZARDS IDENTIFICATION May cause cancer. Irritating to eyes and skin. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Vapours may cause drowsiness and dizziness. CLASSIFICATION Carc2;R45 Muta3;R68 Xi;R36/38 R67 R52/53 3 COMPOSITION/INFORMATION ON INGREDIENTS EU INDEX NO EC No CAS-No FIRST-AID MEASURES NOTES TO THE PHYSICIAN Treat according to symptoms: Symptomatic treatment. Adrenaline and similar sypathomimetic drugs should be avoided following exposure as cardic arrhythmia may result with possible subsequent cardiac arrest. Gastric lavage may be effective when performed within 4 hours of ingestion. INHALATION Move into fresh air and keep at rest. Get medical attention. INGESTION Provide rest, warmth and fresh air. Immediately rinse mouth and drink plenty of water ( ml). DO NOT induce vomiting. Get medical attention immediately. SKIN CONTACT Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention if any discomfort continues. EYE CONTACT Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention immediately. Continue to rinse. 5 FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. UNUSUAL FIRE & EXPLOSION HAZARDS Solvent vapours may form explosive mixtures with air.

2 2 / 5 SPECIFIC HAZARDS Hydrogen chloride (HCl). Phosgene (COCl2). PROTECTIVE MEASURES IN FIRE Self contained breathing apparatus and full protective clothing must be worn in case of fire. 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS Ensure suitable personal protection (including respiratory protection) during removal of spillages in a confined area. Avoid inhalation of spray mist and contact with skin and eyes. Provide adequate ventilation. ENVIRONMENTAL PRECAUTIONS Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body. SPILL CLEAN UP METHODS Absorb with inert, damp, non-combustible material, then flush area with water. Collect spillage in containers, seal securely and deliver for disposal according to local regulations. 7 HANDLING AND STORAGE USAGE PRECAUTIONS Avoid spilling, skin and eye contact. Eliminate all sources of ignition. Protect electric equipment against sparking in case of risk of explosion. Take precautionary measures against static discharges when there is a risk of dust explosion. Avoid inhalation of vapours/spray and contact with skin and eyes. Provide good ventilation. STORAGE PRECAUTIONS Keep containers tightly closed. Keep in original container. Keep away from heat, sparks and open flame. STORAGE CLASS Miscellaneous hazardous material storage. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Name Std LT - ppm LT - mg/m3 ST - ppm ST - mg/m3 WEL 100 ppm(sk) 550 mg/m3(sk) 150 ppm(sk) 820 mg/m3(sk) PROTECTIVE EQUIPMENT RESPIRATORY EQUIPMENT If ventilation is insufficient, suitable respiratory protection must be provided. HAND PROTECTION Nitrile gloves are recommended. EYE PROTECTION Goggles/face shield are recommended. OTHER PROTECTION Wear rubber apron. Wear rubber footwear. 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE COLOUR ODOUR SOLUBILITY Liquid Clear Sweetish Slightly soluble in water. BOILING POINT ( C) 87 MELTING POINT ( C) -87 RELATIVE DENSITY VAPOUR DENSITY (air=1) 4.54 VAPOUR PRESSURE 59 mm Hg 20

3 3 / 5 AUTO IGNITION TEMPERATURE ( C) STABILITY AND REACTIVITY STABILITY Stable under normal temperature conditions and recommended use. CONDITIONS TO AVOID Avoid heat, flames and other sources of ignition. Avoid excessive heat for prolonged periods of time. MATERIALS TO AVOID Strong alkalis. HAZARDOUS DECOMPOSITION PRODUCTS Hydrogen chloride (HCl). Phosgene (COCl2). 11 TOXICOLOGICAL INFORMATION INHALATION In high concentrations, vapours are anaesthetic and may cause headache, fatigue, dizziness and central nervous system effects. INGESTION Irritating. May be absorbed in the body and cause dizziness, nausea and vomiting. SKIN CONTACT Irritating to skin. Repeated exposure may cause skin dryness or cracking. EYE CONTACT Irritating to eyes. Other Health Effects Carcinogen Category 2. Mutagen Category 3. TARGET ORGANS Kidneys. Liver. 12 ECOLOGICAL INFORMATION ECOTOXICITY The product contains a substance which is harmful to aquatic organisms and which may cause long term adverse effects in the aquatic environment. MOBILITY The product has poor water-solubility. BIOACCUMULATION Bioaccumulation is unlikely to be significant because of the low water solubility of this product. DEGRADABILITY The product is not readily biodegradable. 13 DISPOSAL CONSIDERATIONS GENERAL INFORMATION Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority. Do not puncture or incinerate even when empty. Rags and the like, moistened with flammable liquids, must be discarded into designated fireproof bucket. DISPOSAL METHODS Dispose of waste and residues in accordance with local authority requirements. 14 TRANSPORT INFORMATION

4 4 / 5 UK ROAD CLASS PROPER SHIPPING NAME UN NO. UK ROAD PACK GR. II ROAD ADR CLASS NO. ADR PACK GROUP ADR LABEL NO. CEFIC TEC(R) NO. RID PACK GROUP IMDG EMS UN NO. AIR AIR PACK GR. 61GT1- F-A, S-A ADR CLASS HAZARD No. (ADR) HAZCHEM CODE RID CLASS NO. UN NO. SEA IMDG PACK GR. MARINE POLLUTANT AIR CLASS Class :Toxic substances. 60 2Z CLASS No. 15 REGULATORY INFORMATION LABELLING Toxic RISK PHRASES R45 May cause cancer. R36/38 Irritating to eyes and skin. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R67 Vapours may cause drowsiness and dizziness. SAFETY PHRASES S45 S53 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). Avoid exposure - obtain special instructions before use. STATUTORY INSTRUMENTS S61 Chemicals (Hazard Information and Packaging) Regulations. APPROVED CODE OF PRACTICE Avoid release to the environment. Refer to special instructions/safety data sheets. Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply. GUIDANCE NOTES CHIP for everyone HSG(108). Workplace Exposure Limits EH OTHER INFORMATION REVISION DATE 22nd May 2008 REV. NO./REPL. SDS GENERATED 07 SDS NO. T015 SAFETY DATA SHEET STATUS Approved.

5 DATE 22nd May 2011 SIGNATURE Tianjin Feilintake ChemicalCo.Ltd 5 / 5