Date of Print: Revision Date: Page 1 of 6. Safety Data Sheet according to Regulation (EC) No. 1907/2006

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1 Date of Print: Revision Date: Page 1 of 6 Safety Data Sheet according to Regulation (EC) No. 1907/ Identification of substance/preparation and of the company/undertaking Trade name: KLEEN CARE Mega KLEEN Stone impregnating Fluid Use of the substance/preparation: Impregnation for natural- and concrete stone and unglazed tiles for professional users only Company/undertaking identification: KLEEN PURGATIS GmbH Dieselstraße 10 D Hiddenhausen Telephone: +49/(0) Telefax: +49/(0) info@kleen-purgatis.de s.tiemann@budich.de; a.klumpe@budich.de Department responsible for information: Product Development Department Emergency telephone number: 24 hours Hotline: +49/(0) Giftinformationszentrum Nord 2. Hazards Identification Hazards statements: Xn Harmful R 10: Flammable R 65: Harmful: may cause lung damage if swallowed R 66: Repeated exposure may cause skin dryness or cracking Information pertaining to special dangers for human and environment: none 3. Composition/information on ingredients Chemical characterization: Mixture of the substances and additives listed below Hazardous ingredients: CAS-No. EINECS-No. Chemical name % Hazard Symbol R-phrases aliphatic carbohydrates > 50 Xn 10, 65, 66 (C9-C11) Full text of R-phrases: see under section 16

2 Date of Print: Revision Date: Page 2 of 6 4. First aid measures General information: In case of indisposition, seek medical advice. In case of inhalation: Move affected person into fresh air. In case of respiratory tract irritation, consult a physician. In case of skin contact: After contact with skin, wash immediately with soap and plenty of water. In case of skin reaction, consult a physician. In case of eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult an ophthalmologist. In case of ingestion: Do not induce vomiting. Give nothing to drink. Seek medical advice immediately. Observe risk of aspiration if vomiting occurs. Information to physician: No data available. 5. Fire-fighting measures Suitable extinguishing media: Foam, water spray-jet or water mist. Extinguishing media which must not be used for safety reasons: Water full jet Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases: In case of improper burn-up, carbon monoxide can be released. Floats on water and can ignite again on water surface. Vapours are heavier than air and spread just above ground level. Special protective equipment for fire-fighters: Use suitable breathing apparatus. Wear full chemical protective clothing. Additional information: Collect contaminated fire extinguishing water separately. This must not be discharged into drains. 6. Accidental release measures Personal precautions: Avoid skin and eye contact. Avoid inhalation of vapours keep away from ignition sources Environmental precautions: Do not allow to enter drains/surface water/ground-water. Methods for cleaning up: Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the recovered material as prescribed in the section on waste disposal. Ventilate affected area.

3 Date of Print: Revision Date: Page 3 of 6 7. Handling and storage Handling: Advices on save handling: Keep container tightly closed. The entire working area should be ventilated. Precautions against fire and explosion: The product is combustible. Cooling must be provided for in case of a fire in the vicinity. Storage: Requirements for storage rooms and vessels: Protect against heating. Keep away from sources of ignition No smoking. Take precautionary measures against static discharges. Hints on storage assembly: Keep away from food, drink and animal feeding stuffs. Storage class VCI: 3A (Flammable liquids) Further information on storage conditions: Keep in a cool and dry place. Danger of explosion. Vapours can form an explosive mixture with air. 8. Exposure controls/personal protection Components with occupational exposure limits rsp. biological occupational exposure limits requiring monitoring: Occupational exposure limit value (AGW) ALIPHATIC CARBOHYDRATES (C9-C11) ; CAS-No.: Source: TRGS 900 Occupational exposure limits (DE) Air limit value(s): 100 mg/m 3 Personal protection: General health and safety measures: Remove contaminated, saturated clothing immediately. Avoid contact with skin, eye and clothing. When using do not eat, drink, smoke, sneeze. Wash hands before breaks and after work. Respiratory protection: not required Eye protection: Eye glasses with side protection, EN 166:2001 Hand protection: Protective gloves Suitable material: NR (natural rubber), CR (polychloroprene) or NBR (nitrile rubber), category III according to EN 374

4 Date of Print: Revision Date: Page 4 of 6 The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. Breakthrough time (maximal wear duration): Wear duration with occasional contact, splashes (Level 2: < 30 min): Disposable-gloves, Thickness of the glove material 0,1 mm Wear duration with permanent contact (Level 6: < 480 min): Protective gloves, Thickness of the glove material 0,7 mm. Breakthrough times and swelling properties of the material must be taken into consideration. 9. Physical and chemical properties Appearance Physical state: Colour: Odour: liquid colourless product specific Safety information Value/Range/Unit/Method Boiling temperature: Flash point: 40 o C (Abel-Pensky) Flammability: highly-flammable Oxidising properties: oxidising Explosive properties: Vapour pressure: Density: ca. 0,78 g/cm 3 Water solubility/miscibility: miscible Partition coefficient n-octanol/water: Viscosity: ph (in delivery state): n.a. n.a. not applicable not determined a. no data available 10. Stability and reactivity Conditions to avoid: No hazardous decomposition products known if used as described. Materials to avoid: None known Hazardous decomposition products: No hazardous decomposition products known. 11. Toxicological information Toxicity tests: Preparation not tested. LD/LC 50 values relevant for classification: aliphatic carbohydrates (C9-C11) LD 50 oral >2000 mg/kg body weight (estimated value)

5 Date of Print: Revision Date: Page 5 of 6 Sensitizing: not sensitizing Additional toxicological information/experiences made in practice: If used properly, this product is not hazardous to health in our experience and the information we have available. 12. Ecological information General information: Do not allow uncontrolled discharge of product into the environment Ecotoxicity aliphatic carbohydrates (C9-C11) The product is easily volatile, there is no danger for water creatures. Mobility: No data available. Persistence and degradability: No data available. Bioaccumulative potential: No data available. Results of PBT assessment (REACH) No data available. Other adverse effects The product has not been tested. Data apply to the component with the highest toxicological risk. 13. Disposal considerations Appropriate disposal / Product: Dispose of waste according to applicable local, state and federal regulations. List of proposed waste codes / waste designations in accordance with AVV (other organic solvents, washing liquids and mother liquor) Appropriate disposal/packaging: Completely emptied packings can be recycled. 14. Transport information Land transport (ADR) Class: 3 Danger code: 30 UN-No.: 1268 Classification code: F1 Official transport designation: mineral oil destillates (petroleum naphta) Packing group: III Hazard label: 3 Additional information: limited quantities Tunnel restriction code: E

6 Date of Print: Revision Date: Page 6 of Regulatory information Labelling: The product is classified and marked labelled to EC-regulations or according to the corresponding national laws. Hazard(s) symbol(s) and hazard statements of product: Hazard(ous) component(s) for labelling: R-phrases: S-phrases: Xn - Harmful R 10: Flammable R 65: Harmful: may cause lung damage if swallowed R 66: Repeated exposure may cause skin dryness or cracking S 1/2: Keep locked up and out of the reach of children S 23: Do not breathe gas/fumes/vapour/spray S 24: Avoid contact with skin S 45: If case of accident or if you feel unwell, seek medical advice immediately. Show the label where possible. S 62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label EU-Regulations: The preparation comply with the criteria as laid down in Regulation (EC) No. 648/2004 on detergents Chemical Safety Assessment: For this preparation a chemical safety assessment has not been carried out. 16. Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. The present safety data sheet supersedes all preceding copies. Previous editions are herewith invalidated. Data references: Safety data sheets from our raw material suppliers Relevant R-phrases R 10: Flammable R 65: Harmful: may cause lung damage if swallowed R 66: Repeated exposure may cause skin dryness or cracking Data changed compared with the previous version: Section 7: Handling and storage Section 8: Exposure controls/personal protection Section 9: Physical and chemical properties Section 12: Ecological information Section 14: Transport information Adjustment according to REACH under consideration of 91/155/EEC Department issuing MSDS: Product Development Department

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