Safety Data Sheet according to (EC) No 1907/ ISO

Transcription

1 Safety Data Sheet according to (EC) No 1907/ ISO Page 1 of 7 Nitromors All Purpose Paint & Varnish Remover - Dichloromethane Free sds no. : Revision: printing date: Identification of the substance/preparation and of the company/undertaking Trade name: Nitromors All Purpose Paint & Varnish Remover - Dichloromethane Free Intended use: Stripper Company name: Henkel Limited Apollo Court, 2 Bishop Square Business Park Hatfield, Hertfordshire AL10 9EY Great Britain Phone: +44 (0) Fax-no.: +44 (0) address of person responsible for Safety Data Sheet: ua-productsafety.uk@uk.henkel.com Emergency information: 24 Hours Emergency Tel: For further general health & safety, technical and practical advice on this product, please call +44 (0) or write to: Technical Services; Henkel Limited; Road 5; Winsford Industrial Estate; Winsford; Cheshire; CW7 3QY- technical.services@henkel.co.uk 2. Hazards identification The product is classified as hazardous within the meaning of the valid (EU) preparation directive. F - Highly flammable Xn - Harmful R11 Highly flammable. R20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R68/20/21/22 Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed. The solvent vapors are heavier than air and may collect in high concentrations at floor level. In use, may form explosive or highly flammable vapor-air mixtures. Pregnant women should absolutely avoid breathe in and skin contact. General chemical description: Composition Base substances of preparation: Organic solvent 3. Composition / information on ingredients

2 Nitromors All Purpose Paint & Varnish Remover - Dichloromethane Free Page 2 of 7 Declaration of ingredients according to (EC) No 1907/2006: Hazardous components EINECS content Classification CAS-No. 1,3-Dioxolane < 60 % F - Highly flammable; R Naphtha (petroleum), hydrotreated heavy, <0.1% Benzene < 10 % R10 Xn - Harmful; R65, R Methanol < 10 % F - Highly flammable; R11 T - Toxic; R23/24/25, R39/23/24/25 Docusate sodium < 2,5 % Xi - Irritant; R38, R41 Solvent naphtha (petroleum), light arom., <0.1% Benzene < 1 % N - Dangerous for the environment; R51/53 Xn - Harmful; R65 Xi - Irritant; R37 R10, R66, R67 For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available. General information: In case of adverse health effects seek medical advice. Inhalation: After inhalation of vapor: fresh air. 4. First aid measures Skin contact: Wipe off affected skin area immediately with a soft cloth and then wash with running water and mild soap; apply skin care product. Eye contact: Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. Ingestion: Rinse the mouth. Drink plenty of water. Immediate medical advice necessary. 5. Fire fighting measures Suitable extinguishing media: carbon dioxide, foam, powder, water spray jet, fine water spray Extinguishing media which must not be used for safety reasons: High pressure waterjet Special protection equipment for firefighters: Wear self-contained breathing apparatus. Wear protective equipment. In case of fire, keep containers cool with water spray. Personal precautions: Ensure adequate ventilation. Keep away from sources of ignition. Avoid contact with skin and eyes. Keep unprotected persons away. Environmental precautions: Do not empty into drains / surface water / ground water. 6. Accidental release measures

3 Nitromors All Purpose Paint & Varnish Remover - Dichloromethane Free Page 3 of 7 Clean-up methods: Remove with liquid-absorbing material (sand, peat, sawdust). Dispose of contaminated material as waste according to item Handling and storage Handling: Ventilate working rooms thoroughly. Avoid naked flames, sparking and sources of ignition. Switch off electrical devices. Do not smoke, do not weld. Do not empty waste into waste water drains. Take measures to prevent the build-up of electrostatic charges. Storage: Store in a cool, dry place. Store in sealed original container. Store in a cool, well-ventilated place. Do not store together with food or other consumables (coffee, tea, tobacco, etc.). 8. Exposure controls / personal protection Components with specific control parameters for workplace: Valid for Great Britain Ingredient ppm mg/m 3 Type Category Remarks DIMETHOXYMETHANE Short Term Exposure Limit (STEL): DIMETHOXYMETHANE Time Weighted Average (TWA). METHANOL Time Weighted Average (TWA). METHANOL Short Term Exposure Limit (STEL): METHANOL Skin designation: Can be absorbed through the skin. PARAFFIN WAX, FUME 2 Time Weighted Average (TWA). PARAFFIN WAX, FUME Short Term Exposure Limit (STEL): Engineering controls: Draw off vapours directly at the point of generation and exit. In the case of regular work, provide bench-mounted extraction equipment. Ventilate working rooms thoroughly. Avoid naked flames, sparking and sources of ignition. Switch off electrical devices. Do not smoke, do not weld. Do not empty waste into waste water drains. Respiratory protection: In the event of exposure over short periods of time or to small amounts use repiration filter device. Use a prespiratory protection apparatus which is independent of circulating air in the case of more protracted exposure. Hand protection: For shorttime contact (e.g. as protection against splashes) protective gloves made from nitrile rubber are recommended according to EN 374. In case of full contact protective gloves made from butyl rubber are recommended according to EN 374. material thickness > 0.7 mm Perforation time > 10 minutes In the case of longer and repeated contact please note that in practice the penetration times may be considerably shorter than those determined according to EN 374. The protective gloves must always be checked for their suitability for use at the specific workplace (e.g. mechanical and thermal stress, product compatibility, antistatic effects, etc.). The gloves must be replaced immediately at the first signs of wear and tear. The information provided by the manufacturers and given in the relevant trade association regulations for industrial safety must always be observed. We recommend that a hand care plan is drawn up in cooperation with a glove manufacturer and the trade association in accordance with the local operating conditions.

4 Nitromors All Purpose Paint & Varnish Remover - Dichloromethane Free Page 4 of 7 Eye protection: Goggles which can be tightly sealed. Skin protection: Suitable protective clothing General protection and hygiene measures: Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Wash off any dirt that gets onto the skin with lots of soap and water, skin care. 9. Physical and chemical properties General characteristics: Appearance Odor: Gel Gel, Smooth Cloudy, Green Characteristic Phys./chem. properties: Boiling point Flash point Density (20 C (68 F)) Viscosity (dynamic) (; 20 C (68 F)) Solubility (qualitative) (20 C (68 F); Solvent: Water) Explosion limit lower [vol%] upper [vol%] 42 C (107.6 F) -18 C (0.4 F) 0,90-0,95 g/cm mpa.s Partially miscible 2,3 %(V) 30,5 %(V) 10. Stability and reactivity Conditions to avoid: None if used for intended purpose. Materials to avoid: Reaction with oxidants. Hazardous decomposition products: In the event of a fire, hydrochloric acid gas is released. 11. Toxicological information General toxicological information: Possible risks of irreversible effects In the event of protracted or repeated exposure, damage to health cannot be excluded. Vapors may cause drowsiness and dizziness. Oral toxicity: Harmful if swallowed. Inhalative toxicity: Harmful by inhalation. Dermal toxicity: Harmful in contact with skin.

5 Nitromors All Purpose Paint & Varnish Remover - Dichloromethane Free Page 5 of Ecological information Persistence and degradability: Ultimate biodegradation: The total of the organic components contained in the product achieve values below 60% BOD/COD or CO2 liberation, or below 70% DOC reduction in tests for ease of degradability. Threshold values for 'readily degradable' (e.g. to OECD method 301) are not reached. Ecotoxicity: Hazardous components CAS-No. Solvent naphtha (petroleum), light arom., <0.1% Benzene Species Exposure Value Value time type Green algae (Scenedesmus quadricauda) 72 h EC 50 > 1-10 mg/l General ecological information: Do not empty into drains, soil or bodies of water. 13. Disposal considerations Product disposal: Dispose of waste and residues in accordance with local authority requirements. The valid EEC waste code numbers are not product-related but are largely source-related. These can be requested from the manufacturer. Disposal of uncleaned packages: Use packages for recycling only when totally empty. Road transport ADR: 14. Transport information Classification code: F1 Hazard ident. number: 33 Technical name: Special provision 640D Railroad transport RID: Classification code: F1 Hazard ident. number: 33 Technical name: Special provision 640D Inland water transport ADN: Classification code: F1 Hazard ident. number: Technical name: Special provision 640D

6 Nitromors All Purpose Paint & Varnish Remover - Dichloromethane Free Page 6 of 7 Marine transport IMDG: EmS: F-E,S-E Seawater pollutant: - Proper shipping name: Air transport IATA: Packaging instructions (passenger) 305 Packaging instructions (cargo) 307 Proper shipping name: Paint Indication of danger: 15. Regulations - classification and identification F - Highly flammable Xn - Harmful Contains Methanol Risk phrases: R11 Highly flammable. R20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R68/20/21/22 Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed. Safety phrases: S2 Keep out of the reach of children. S9 Keep container in a well-ventilated place. S16 Keep away from sources of ignition - No smoking. S33 Take precautionary measures against static discharges. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S46 If swallowed, seek medical advice immediately and show this container or label. S51 Use only in well-ventilated areas. S52 Not recommended for interior use on large surface areas. S56 Dispose of this material and its container to hazardous or special waste collection point.

7 Nitromors All Purpose Paint & Varnish Remover - Dichloromethane Free Page 7 of Other information The labelling of the product is indicated in Section 15. The full text of the R-phrases indicted by codes in this safety data sheet are as follows: R10 Flammable. R11 Highly flammable. R23/24/25 Toxic by inhalation, in contact with skin and if swallowed. R37 Irritating to respiratory system. R38 Irritating to skin. R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. R41 Risk of serious damage to eyes. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.