Cut & Cool Cutting And Drilling Oil

Transcription

1 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product information Commercial Product Name : Product code : MSDS-Identcode : Product Use Description : Polishing agent and lubricant Company : Wurth Australia Pty Ltd 2/1 Healey Road Dandenong South, Victoria, 3175 Australia Telephone : Responsible/issuing person : prodsafe.wurth@sap.com Emergency telephone number : Advisory office in case of poisoning - National Poisons Centre: HAZARDS IDENTIFICATION DANGEROUS GOODS. HAZARDOUS SUBSTANCE. Dangerous goods classification according to the Australia Dangerous Goods Code. Classified as hazardous according to the criteria of NOHSC. Standard for the Uniform Scheduling of Medicines and Poisons : No poison schedule number allocated R-phrase(s) Extremely flammable. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Vapours may cause drowsiness and dizziness. S-phrase(s) Do not breathe spray. This material and its container must be disposed of in a safe way. Use only in well-ventilated areas. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components 1 / 14

2 Chemical Name CAS-No. Concentration butane >= 20 - < 25% heptane [and isomers] >= < 15% propane >= 7 - < 10% isobutane >= 5 - < 7% methylcyclohexane >= 2 - < 3% cyclohexane >= < 2% n-octane >= < 0.75% hexane, mixture of isomers >= < 0.5% zinc bis[o,o-bis(2-ethylhexyl)] bis(dithiophosphate) >= < 0.5% 4. FIRST AID MEASURES General advice If inhaled In case of skin contact In case of eye contact If swallowed : If you feel unwell, seek medical advice (show the label where possible). First aider needs to protect himself. Move out of dangerous area. Never give anything by mouth to an unconscious person. Take off contaminated clothing and shoes immediately. : If breathed in, move person into fresh air. In the case of inhalation of aerosol/mist consult a physician if necessary. Keep patient warm and at rest. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. : In case of contact, immediately flush skin with soap and plenty of water. Do NOT use solvents or thinners. If skin irritation persists, call a physician. : If easy to do, remove contact lens, if worn. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. : If swallowed, seek medical advice immediately and show this container or label. 2 / 14

3 If swallowed, DO NOT induce vomiting. If a person vomits when lying on his back, place him in the recovery position. 5. FIREFIGHTING MEASURES Suitable extinguishing media Specific hazards during firefighting Special protective equipment for firefighters : Carbon dioxide (CO2) Dry powder Water spray jet : Do not use a solid water stream as it may scatter and spread fire. Exposure to decomposition products may be a hazard to health. : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. : Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. In the event of fire and/or explosion do not breathe fumes. Use water spray to cool unopened containers. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. If the temperature rises there is danger of the vessels bursting due to the high vapor pressure. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions : Use personal protective equipment. Remove all sources of ignition. Avoid contact with skin and eyes. Ensure adequate ventilation, especially in confined areas. Contaminated surfaces will be extremely slippery. Immediately evacuate personnel to safe areas. Avoid inhalation of vapour or mist. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. : Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. 3 / 14

4 If the product contaminates rivers and lakes or drains inform respective authorities. Avoid release to the environment. Refer to special instructions/ Safety data sheets. Methods for cleaning up : Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations. Clean contaminated surface thoroughly. 7. HANDLING AND STORAGE Handling Advice on safe handling Advice on protection against fire and explosion Dust explosion class : Limit the stocks at work place. Use only in well-ventilated areas. Do not breathe vapours or spray mist. Avoid contact with skin and eyes. Do not spray on a naked flame or any incandescent material. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration higher than the occupational exposure limits. Take precautionary measures against static discharges. Use appropriate container to avoid environmental contamination. Do not carry cloths that have come into contact with the product in your clothing. : Normal measures for preventive fire protection. Vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures with air. Keep away from heat and sources of ignition. Do not smoke. No sparking tools should be used. Electrical equipment should be protected to the appropriate standard. : not applicable Storage Requirements for storage areas and containers : BEWARE: Aerosol is pressurized. Keep away from heat. Keep away from direct sunlight. Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. Keep containers tightly closed in a dry, cool and well- 4 / 14

5 ventilated place. Please observe the storage instructions for aerosols! on storage conditions Advice on common storage Advice on common storage Materials to avoid Other data : AS/NZS 3833 The storage and handling of mixed classes of Dangerous Goods in packages and intermediate bulk containers. : Incompatible with oxidizing agents. : Keep away from food, drink and animal feedingstuffs. Do not store together with oxidizing and self-igniting products. : Oxidizing agents : No decomposition if stored and applied as directed. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value Control parameters butane TWA 800 ppm 1,900 mg/m3 Update Basis heptane [and isomers] : H: ACGIH is the documentation source STEL 500 ppm 2,050 mg/m3 : H: ACGIH is the documentation source TWA 400 ppm 1,640 mg/m3 methylcyclohexane : H: ACGIH is the documentation source TWA 400 ppm 1,610 mg/m3 : H: ACGIH is the documentation source 5 / 14

6 cyclohexane TWA 100 ppm 350 mg/m3 STEL 300 ppm 1,050 mg/m3 n-octane TWA 300 ppm 1,400 mg/m3 : H: ACGIH is the documentation source STEL 375 ppm 1,750 mg/m3 : H: ACGIH is the documentation source Adopted National Exposure Standards for Atmospheric Contaminants in the Occupational Environment [NOHSC:1003], as amended through August 2005 Biological occupational exposure limits no biological limit allocated Engineering measures Provide sufficient air exchange and/or exhaust in work rooms. Personal protective equipment Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Product contains low-boiling liquids. Respiratory protective equipment must be air supplied respirators. Hand protection : Nitrile rubber Break through time: > 480 min Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. 6 / 14

7 Eye protection Skin and body protection Hygiene measures : Avoid contact with eyes. In case of splash hazard, please wear protective goggles. Safety glasses with side-shields conforming to EN166 : Flame retardant antistatic protective clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. : Handle in accordance with good industrial hygiene and safety practice. General industrial hygiene practice. Do not inhale aerosol. Avoid contact with skin, eyes and clothing. When using do not eat, drink or smoke. Wash hands before breaks and at the end of workday. Follow the skin protection plan. Wash contaminated clothing before re-use. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Colour Odour Odour Threshold : aerosol : light brown : characteristic Safety data Flash point Ignition temperature : > 250 C Lower explosion limit Upper explosion limit : 1 %(V) : 32 %(V) Flammability Autoignition temperature ph Melting point/range Boiling point/boiling range Vapour pressure : 3,000 hpa 7 / 14

8 Density Water solubility Partition coefficient: n- octanol/water Solubility in other solvents Viscosity, dynamic Viscosity, kinematic Relative vapour density Evaporation rate Thermal decomposition : g/cm3 : immiscible 10. STABILITY AND REACTIVITY Conditions to avoid : Heat, flames and sparks. Materials to avoid Hazardous decomposition products : Oxidizing agents : Carbon monoxide Carbon dioxide (CO2) Hazardous reactions : Vapours may form explosive mixtures with air. If the temperature rises there is danger of the vessels bursting due to the high vapor pressure. Stability : No decomposition if stored and applied as directed. 11. TOXICOLOGICAL INFORMATION Acute toxicity Acute oral toxicity Acute oral toxicity (Components) heptane [and isomers] : LD50: 15,001 mg/kg Species: rat zinc bis[o,o-bis(2- ethylhexyl)] bis(dithiophosphate) : LD50: 3,100 mg/kg Species: rat Acute inhalation toxicity (Components) 8 / 14

9 butane heptane [and isomers] propane cyclohexane n-octane : LC50: 658 mg/l Exposure time: 4 h Species: rat : LC50: 103 g/m3 Exposure time: 4 h Species: rat : LC50: Exposure time: 15 min Species: rat : LC50: 14 mg/l Exposure time: 4 h Species: rat : LC50: 118 mg/l Exposure time: 4 h Species: rat Acute dermal toxicity (Components) methylcyclohexane : LD50: 86,001 mg/kg Species: rabbit cyclohexane zinc bis[o,o-bis(2- ethylhexyl)] bis(dithiophosphate) Skin corrosion/irritation Skin irritation : LD50: 2,001 mg/kg Species: rabbit : LD50: 5,001 mg/kg Species: rabbit : May irritate skin. Serious eye damage/eye irritation Eye irritation : May irritate eyes. Respiratory or skin sensitization Sensitisation Chronic toxicity Mutagenicity Carcinogenicity Teratogenicity Reproductive toxicity Specific target organ toxicity - single exposure 9 / 14

10 no data available Specific target organ toxicity - repeated exposure no data available Aspiration toxicity : Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Vapours may cause drowsiness and dizziness. 12. ECOLOGICAL INFORMATION Toxicity to fish (Components) heptane [and isomers] : LC50: 4 mg/l Exposure time: 24 h Species: Carassius auratus (goldfish) Toxicity to daphnia and other aquatic invertebrates. (Components) heptane [and isomers] : EC50: 1.5 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea) methylcyclohexane cyclohexane n-octane : EC50: 1.47 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea) : EC50: 3.78 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea) : EC50: 0.38 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea) Elimination information (persistence and degradability) Bioaccumulation Biodegradability Mobility in soil 10 / 14

11 on ecology Adsorbed organic bound halogens (AOX) Results of PBT assessment Additional ecological information : not included : The product should not be allowed to enter drains, water courses or the soil. 13. DISPOSAL CONSIDERATIONS Product Disposal of contaminated packaging : In accordance with local and national regulations., This material and its container must be disposed of as hazardous waste. : Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not burn, or use a cutting torch on, the empty drum. Please ensure aerosol cans are sprayed completely empty (including propellant) Containers that have not been emptied in compliance with regulations are regarded as hazardous waste. Dispose of as unused product. 14. TRANSPORT INFORMATION ADG UN number : 1950 Description of the goods : AEROSOLS Class : 2 Labels : 2 Hazchem Code : 2YE Environmentally hazardous : no IATA UN number : / 14

12 Description of the goods : Aerosols, flammable Class : 2.1 Labels : 2.1 Packing instruction (cargo : 203 aircraft) Packing instruction (passenger : 203 aircraft) Packing instruction (passenger : Y203 aircraft) Environmentally hazardous : no IMDG UN number : 1950 Description of the goods : AEROSOLS Class : 2.1 Packing group : -- Labels : 2.1 EmSNumber 1 : F-D EmS Number 2 : S-U Marine pollutant : no 15. REGULATORY INFORMATION Labelling according to EC Directives 1999/45/EC R-phrase(s) : R12 Extremely flammable. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R67 Vapours may cause drowsiness and dizziness. S-phrase(s) : S23 Do not breathe spray. S35 This material and its container must be disposed of in a safe way. S51 Use only in well-ventilated areas. Special labelling of certain mixtures : Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. 12 / 14

13 Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. Keep out of the reach of children. National regulatory information For detailed advice on Personal Protective equipment, refer to the following Australian Standards :- HB 9 (Handbook 9) Manual of industrial personal protection. AS/NZS 1337 Eye protectors for industrial applications. AS/NZS 1715 Selection, use and maintenance of respiratory protective devices. AS/NZS 1716 Respiratory protective devices. AS/NZS : Occupational protective gloves - Selection, use and maintenance. AS/NZS 2919: Industrial clothing. Hazard category Extremely flammable National Code of Practice for the Preparation of Material Safety Data Sheets [NOHSC:2011] List of Designated Hazardous Substances [NOHSC]. Approved Criteria for Classifying Hazardous Substances [NOHSC:1008]. Amendment to National Exposure Standards for Atmospheric Contaminants in the Occupational Environment [NOHSC](2005) Australian Dangerous Goods Code. Standard Uniform Scheduling of Drugs and Poisons. Notification status AICS : On the inventory, or in compliance with the inventory 16. OTHER INFORMATION Full text of R-phrases referred to under sections 2 and 3 R12 Extremely flammable. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R67 Vapours may cause drowsiness and dizziness. 13 / 14

14 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet 14 / 14