SAFETY DATA SHEET according to Regulation (EC) No. 1907/ SUPER RTV-SILIKON ROT 226G

Transcription

1 1. Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Commercial Product Name : SUPER RTV-SILIKON ROT 226G Product code : MSDS-Identcode : Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture : Sealant 1.3 Details of the supplier of the safety data sheet Company : Würth Handelsges.m.b.H. Würth Strasse Böheimkirchen Austria address: thomas.meindorfer@wuerth.at Telephone : +43 (0) Telefax : +43 (0) Responsible/issuing person : address: prodsafe.wurth@sap.com 1.4 Emergency telephone number Vergiftungs-Informations-Zentrale +43 (0) Hazards identification 2.1 Classification of the substance or mixture Classification (67/548/EEC, 1999/45/EC) Carcinogenic Category 3 Sensitising Irritant R40: Limited evidence of a carcinogenic effect. R43: May cause sensitization by skin contact. R36: Irritating to eyes. 2.2 Label elements Labelling according to EC Directives: 1999/45/EC Hazard symbols : Harmful 1 / 15

2 R-phrase(s) : R36 Irritating to eyes. R40 Limited evidence of a carcinogenic effect. R43 May cause sensitization by skin contact. S-phrase(s) : S23 Do not breathe spray, vapour. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S35 This material and its container must be disposed of in a safe way. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S51 Use only in well-ventilated areas. Hazardous components which must be listed on the label: butan-2-one O,O',O''-(vinylsilylidyne)trioxime butanone oxime Special labelling of certain mixtures : Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. 8,2 % by mass of the contents are flammable. 2.3 Other hazards 3. Composition/information on ingredients 3.1 Mixtures Hazardous components Chemical Name CAS-No. EC-No. Classification (67/548/EEC) Registration number butan-2-one O,O',O'' Xi; R38-R41 (vinylsilylidyne)trioxime R43 2-butanone oxime Xn; R21 Xi; R41 Carc.Cat.3; R40 R43 Trimethoxyvinylsilane Xn; R R10 Classification (1272/2008/EC) Skin Irrit. 2; H315 Eye Dam. 1; H318 Skin Sens. 1; H317 Carc. 2; H351 Acute Tox. 4; H312 Eye Dam. 1; H318 Skin Sens. 1; H317 Acute Tox. 4; H332 Flam. Liq. 3; H226 Concentration [%] >= 5 - < 7 >= 1,5 - < 2 >= 1 - < 1, F; R11 Acute Tox. 4; H302 >= 1 - < 1,5 2 / 15

3 Xn; R20/21/22 C; R34 Acute Tox. 4; H312 Acute Tox. 4; H332 Skin Corr. 1B; H314 Flam. Liq. 2; H225 butane F+; R12 Flam. Gas 1; H220 Press. Gas propane F+; R12 Flam. Gas 1; H Press. Gas >= 1 - < 1,5 >= 1 - < 1,5 For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section First aid measures 4.1 Description of first aid measures General advice If inhaled In case of skin contact In case of eye contact If swallowed : In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). First aider needs to protect himself. Move out of dangerous area. Never give anything by mouth to an unconscious person. Take off contaminated clothing and shoes immediately. : If breathed in, move person into fresh air. In the case of inhalation of aerosol/mist consult a physician if necessary. Keep patient warm and at rest. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. : In case of contact, immediately flush skin with soap and plenty of water. Do NOT use solvents or thinners. If skin irritation persists, call a physician. : Protect unharmed eye. If easy to do, remove contact lens, if worn. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. : If swallowed, seek medical advice immediately and show this container or label. If swallowed, DO NOT induce vomiting. If a person vomits when lying on his back, place him in the recovery position. 4.2 Most important symptoms and effects, both acute and delayed 4.3 Indication of any immediate medical attention and special treatment needed 3 / 15

4 5. Firefighting measures 5.1 Extinguishing media Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Specific hazards during firefighting : Do not use a solid water stream as it may scatter and spread fire. Hazardous decomposition products may be formed under fire conditions (see section 10). Exposure to decomposition products may be a hazard to health. 5.3 Advice for firefighters Special protective equipment for firefighters Further information : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. : Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. In the event of fire and/or explosion do not breathe fumes. Use water spray to cool unopened containers. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. If the temperature rises there is danger of the vessels bursting due to the high vapor pressure. 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Refer to protective measures listed in sections 7 and 8. Use personal protective equipment. Avoid contact with skin and eyes. Ensure adequate ventilation, especially in confined areas. Avoid inhalation of vapour or mist. 6.2 Environmental precautions Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3 Methods and materials for containment and cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. Clean contaminated surface thoroughly. 6.4 Reference to other sections see chapter: 7, 8, 11, 12 and 13 4 / 15

5 7. Handling and storage 7.1 Precautions for safe handling Advice on safe handling Advice on protection against fire and explosion : For personal protection see section 8. Limit the stocks at work place. Use only in well-ventilated areas. Do not breathe vapours or spray mist. Avoid contact with skin and eyes. Do not spray on a naked flame or any incandescent material. Persons with a history of skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. : Normal measures for preventive fire protection. Dust explosion class : not applicable 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers : BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 C. Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. Keep containers tightly closed in a dry, cool and well-ventilated place. Please observe the storage instructions for aerosols! Advice on common storage : Keep away from food, drink and animal feedingstuffs. Storage temperature : 5-30 C Other data : No decomposition if stored and applied as directed. 7.3 Specific end uses 8. Exposure controls/personal protection 8.1 Control parameters Components CAS-No. Control parameters Basis Update 5 / 15

6 Components CAS-No. Control parameters Basis Update diiron trioxide TMW (alveolate part): 5 mg/m3, AT OEL TMW (inhalable fraction): 10 mg/m3, KZW (alveolate part): 10 mg/m3, KZW (inhalable fraction): 20 mg/m3, butane TMW: mg/m3, 800 ppm AT OEL KZW: mg/m3, ppm propane TMW: mg/m3, ppm AT OEL KZW: mg/m3, ppm Other information on limit values: see chapter Exposure controls Engineering measures Provide sufficient air exchange and/or exhaust in work rooms. Personal protective equipment Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Respirator with filter type A Hand protection Directive : DIN EN 374 Remarks Eye protection : Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. : Wear eye/face protection. 6 / 15

7 Skin and body protection : Wear suitable protective clothing. Choose body protection according to the amount and concentration of the dangerous substance at the work place. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. General industrial hygiene practice. Do not inhale aerosol. Avoid contact with skin, eyes and clothing. When using do not eat, drink or smoke. Wash hands before breaks and at the end of workday. Follow the skin protection plan. Wash contaminated clothing before re-use. Environmental exposure controls General advice : Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance : aerosol Propellant : butane, propane Colour : red Odour : characteristic Odour Threshold Flash point Ignition temperature Lower explosion limit Upper explosion limit Explosive properties Flammability (solid, gas) Oxidizing properties Autoignition temperature : not auto-flammable Burning number Molecular Weight ph Boiling point/boiling range Vapour pressure Density : 1,28 g/cm3 at 20 C Bulk density 7 / 15

8 Water solubility Partition coefficient: n- octanol/water Solubility in other solvents Viscosity, dynamic Viscosity, kinematic Flow time Impact Sensitivity Relative vapour density Surface tension Evaporation rate Minimum ignition energy Acid number Refraction index Miscibility in water Solvent separation test 9.2 Other information None known. : hydrolyses 10. Stability and reactivity 10.1 Reactivity 10.2 Chemical stability The product is chemically stable Possibility of hazardous reactions 2-Butanone oxime can be released during processing. Stability: No decomposition if stored and applied as directed. If the temperature rises there is danger of the vessels bursting due to the high vapor pressure Conditions to avoid Extremes of temperature and direct sunlight Incompatible materials Materials to avoid 10.6 Hazardous decomposition products Hazardous decomposition products : Build-up of dangerous/toxic fumes possible in cases of fire/high temperature. Thermal decomposition 8 / 15

9 11. Toxicological information 11.1 Information on toxicological effects Acute toxicity Acute oral toxicity: 2-butanone oxime Trimethoxyvinylsilane : LD50 rat: 930 mg/kg : LD50 rat: mg/kg : LD50 rat: 850 mg/kg Acute inhalation toxicity: 2-butanone oxime Trimethoxyvinylsilane butane propane : LC50 rat: 20 mg/l Exposure time: 4 h : LC50 rat: 16,3 mg/l Exposure time: 4 h : LC50 rat: 8,7 mg/l Exposure time: 4 h : LC50 rat: 658 mg/l Exposure time: 4 h : LC50 rat: ppm Exposure time: 15 min Acute dermal toxicity: 2-butanone oxime Trimethoxyvinylsilane : LD50 rabbit: > mg/kg : LD50 rabbit: mg/kg : LD50 rabbit: 550 mg/kg Acute toxicity (other routes of administration): Skin corrosion/irritation : Extremely corrosive and destructive to tissue. Serious eye damage/eye irritation 9 / 15

10 Eye irritation : Irritating to eyes. Respiratory or skin sensitization Sensitisation : May cause sensitization by skin contact. Germ cell mutagenicity Genotoxicity in vitro: Carcinogenicity Remarks : Carcinogenicity: Limited evidence of a carcinogenic effect. Reproductive toxicity Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration hazard Aspiration toxicity Neurological effects Toxicology Assessment Toxicology, Metabolism, Distribution Acute effects Further information 10 / 15

11 propane : Inhalation of vapours in high concentration may cause shortness of breath (lung oedema). Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea. : May be harmful by inhalation, ingestion, skin absorption. 12. Ecological information 12.1 Toxicity Toxicity to fish 2-butanone oxime Trimethoxyvinylsilane : LC50 : 560 mg/l Exposure time: 48 h : LC50 (Danio rerio (zebra fish)): > 100 mg/l Exposure time: 96 h : LC50 (Pimephales promelas (fathead minnow)): 167 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates. 2-butanone oxime Trimethoxyvinylsilane : EC50 (Daphnia): 750 mg/l Exposure time: 48 h : EC50 (Daphnia magna (Water flea)): 168,7 mg/l Exposure time: 48 h : EC50 (Daphnia magna (Water flea)): 186 mg/l Exposure time: 48 h Toxicity to algae Trimethoxyvinylsilane : IC50 : > 957 mg/l Exposure time: 72 h Toxicity to bacteria : EC50 (Bacteria): mg/l 12.2 Persistence and degradability 12.3 Bioaccumulative potential 11 / 15

12 12.4 Mobility in soil 12.5 Results of PBT and vpvb assessment 12.6 Other adverse effects Adsorbed organic bound halogens (AOX) Additional ecological information : Remarks: not included : The product should not be allowed to enter drains, water courses or the soil. 13. Disposal considerations 13.1 Waste treatment methods Advice on disposal and packaging : Disposal: In accordance with local and national regulations. This material and its container must be disposed of in a safe way. Waste codes should be assigned by the user based on the application for which the product was used. The following Waste Codes are only suggestions: Waste Code (EWC) : Waste Key (unused product): , gases in pressure containers (including halons) containing dangerous substances Waste key (used product): , wastes containing dangerous silicones Disposal of uncleaned packaging : Waste key (uncleaned packaging): , metallic packaging Note: Empty containers should be taken to an approved waste handling site for recycling or disposal. Please ensure aerosol cans are sprayed completely empty (including propellant) Containers that have not been emptied in compliance with regulations are regarded as hazardous waste. Dispose of as unused product. 14. Transport information ADR UN number : 1950 Description of the goods : AEROSOLS 12 / 15

13 Class : 2 Packing group : -- Classification Code : 5F Labels : 2.1 Limited quantity : LQ2 Tunnel restriction code : (D) Environmentally hazardous : no RID UN number : 1950 Description of the goods : AEROSOLS Class : 2 Packing group : -- Classification Code : 5F Labels : 2.1 Limited quantity : LQ2 Environmentally hazardous : no IATA UN number : 1950 Description of the goods : Aerosols, flammable Class : 2.1 Packing group : -- Labels : 2.1 Packing instruction (cargo aircraft) : 203 Environmentally hazardous : no Packing instruction (passenger : 203 aircraft) Packing instruction (LQ) : Y203 IMDG UN number : 1950 Description of the goods : AEROSOLS Class : 2.1 Packing group : -- Labels : 2.1 EmSNumber 1 : F-D EmS Number 2 : S-U Marine pollutant : no Special precautions for user see chapter: 6, 7 and Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture 13 / 15

14 VOC : Directive 1999/13/EC 5,4-6,8 % Directive(96/82/EC) : Update: 2003 Directive 96/82/EC does not apply Other regulations Further information : Take note of Dir 92/85/EEC on the safety and health at work of pregnant workers. : Reserved for industrial and professional use Chemical Safety Assessment 16. Other information Full text of R-phrases referred to under sections 2 and 3 R10 Flammable. R11 Highly flammable. R12 Extremely flammable. R20 Harmful by inhalation. R20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R21 Harmful in contact with skin. R34 Causes burns. R36 Irritating to eyes. R38 Irritating to skin. R40 Limited evidence of a carcinogenic effect. R41 Risk of serious damage to eyes. R43 May cause sensitization by skin contact. Full text of H-Statements referred to under sections 2 and 3. H220 Extremely flammable gas. H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H332 Harmful if inhaled. H351 Suspected of causing cancer. 14 / 15

15 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Prepared by : TechniData BCS GmbH Birlenbacher Str. 19 D Siegen Germany Telephone: +49-(0) Ref.: WIAG / 15