Sulfuric Acid, 95-97%

Transcription

1 Sulfuric Acid, 95-97% 1. Product Identification Synonyms: Oil of vitriol; Babcock acid; sulphuric acid CAS No.: Molecular Weight: Chemical Formula: H2SO4 in H2O Product Codes: 2. Composition/Information on Ingredients Ingredient CAS No Percent Hazardous Sulfuric Acid % Yes 3. Hazards Identification Emergency Overview POISON! DANGER! CORROSIVE. LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE. MAY BE FATAL IF SWALLOWED OR CONTACTED WITH SKIN. HARMFUL IF INHALED. AFFECTS TEETH. WATER REACTIVE. CANCER HAZARD. STRONG INORGANIC ACID MISTS CONTAINING SULFURIC ACID CAN CAUSE CANCER. Risk of cancer depends on duration and level of exposure. Health Rating: 4 - Extreme (Poison) Flammability Rating: 0 - None Reactivity Rating: 2 - Moderate Contact Rating: 4 - Extreme (Corrosive) Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES Storage Color Code: White (Corrosive) Potential Health Effects Inhalation: Inhalation produces damaging effects on the mucous membranes and upper respiratory tract. Symptoms may include irritation of the nose and throat, and labored breathing. May cause lung edema, a medical emergency. Ingestion: Corrosive. Swallowing can cause severe burns of the mouth, throat, and stomach, leading to death. Can cause sore throat, vomiting, diarrhea. Circulatory collapse with clammy skin, weak and rapid pulse, shallow respirations, and scanty urine may follow ingestion or skin contact. Circulatory shock is often the immediate cause of death. Skin Contact: Corrosive. Symptoms of redness, pain, and severe burn can occur. Circulatory collapse with clammy skin, weak and rapid pulse, shallow respirations, and scanty urine may follow skin contact or ingestion. Circulatory shock is often the immediate cause of death. Eye Contact: Corrosive. Contact can cause blurred vision, redness, pain and severe tissue burns. Can cause blindness. Chronic Exposure: Long-term exposure to mist or vapors may cause damage to teeth. Chronic exposure to mists containing sulfuric acid is a cancer hazard. Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems or impaired respiratory function may be more susceptible to the effects of the substance. 4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician immediately.

2 Ingestion: DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Call a physician immediately. Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Excess acid on skin can be neutralized with a 2% solution of bicarbonate of soda. Call a physician immediately. Eye Contact: Immediately flush eyes with gentle but large stream of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Call a physician immediately. 5. Fire Fighting Measures Fire: Concentrated material is a strong dehydrating agent. Reacts with organic materials and may cause ignition of finely divided materials on contact. Explosion: Contact with most metals causes formation of flammable and explosive hydrogen gas. Fire Extinguishing Media: Dry chemical, foam or carbon dioxide. Do not use water on material. However, water spray may be used to keep fire exposed containers cool. Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. Structural firefighter's protective clothing is ineffective for fires involving this material. Stay away from sealed containers. 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Neutralize with alkaline material (soda ash, lime), then absorb with an inert material (e. g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer! US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. 7. Handling and Storage Store in a cool, dry, ventilated storage area with acid resistant floors and good drainage. Protect from physical damage. Keep out of direct sunlight and away from heat, water, and incompatible materials. Do not wash out container and use it for other purposes. When diluting, always add the acid to water; never add water to the acid. When opening metal containers, use non-sparking tools because of the possibility of hydrogen gas being present. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: For Sulfuric Acid: - OSHA Permissible Exposure Limit (PEL) -1 mg/m3 (TWA) - ACGIH Threshold Limit Value (TLV) -1 mg/m3(twa), 3 mg/m3 (STEL), A2 - suspected human carcinogen for sulfuric acid contained in strong inorganic acid mists. Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded and engineering controls are not feasible, a full facepiece respirator with an acid gas cartridge and particulate filter (NIOSH type N100 filter) may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids, glycerine, etc.) are present, use a NIOSH type R or P particulate filter. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres. Where respirators are required, you must have a written program

3 covering the basic requirements in the OSHA respirator standard. These include training, fit testing, medical approval, cleaning, maintenance, cartridge change schedules, etc. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: Clear oily liquid. Odor: Odorless. Solubility: Miscible with water, liberates much heat. Specific Gravity: 1.84 (98%), 1.40 (50%), 1.07 (10%) ph: 1 N solution (ca. 5% w/w) = 0.3; 0.1 N solution (ca. 0.5% w/w) = 1.2; 0.01 N solution (ca. 0.05% w/w) = 2.1. % Volatiles by 21C (70F): No information found. Boiling Point: ca. 290C (ca. 554F) (decomposes at 340C) Melting Point: 3C (100%), -32C (93%), -38C (78%), -64C (65%). Vapor Density (Air=1): 3.4 Vapor Pressure (mm Hg): 145.8C (295F) Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Concentrated solutions react violently with water, spattering and liberating heat. Hazardous Decomposition Products: Toxic fumes of oxides of sulfur when heated to decomposition. Will react with water or steam to produce toxic and corrosive fumes. Reacts with carbonates to generate carbon dioxide gas, and with cyanides and sulfides to form poisonous hydrogen cyanide and hydrogen sulfide respectively. Hazardous Polymerization: Will not occur. Incompatibilities: Water, potassium chlorate, potassium perchlorate, potassium permanganate, sodium, lithium, bases, organic material, halogens, metal acetylides, oxides and hydrides, metals (yields hydrogen gas), strong oxidizing and reducing agents and many other reactive substances. Conditions to Avoid: Heat, moisture, incompatibles. 11. Toxicological Information Toxicological Data: Oral rat LD50: 2140 mg/kg; inhalation rat LC50: 510 mg/m3/2h; standard Draize, eye rabbit, 250 ug (severe); investigated as a tumorigen, mutagen, reproductive effector. Carcinogenicity: Cancer Status: The International Agency for Research on Cancer (IARC) has classified "strong inorganic acid mists containing sulfuric acid" as a known human carcinogen, (IARC category 1). This classification applies only to mists containing sulfuric acid and not to sulfuric acid or sulfuric acid solutions \Cancer Lists\ NTP Carcinogen--- Ingredient Known Anticipated IARC Category Sulfuric Acid ( ) No No None Water ( ) No No None 12. Ecological Information Environmental Fate: When released into the soil, this material may leach into groundwater. When released into the air, this material may be removed from the atmosphere to a moderate extent by wet deposition. When released into the air, this material may be removed from the atmosphere to a moderate extent by dry deposition.

4 Environmental Toxicity: LC50 Flounder 100 to 330 mg/l/48 hr aerated water/conditions of bioassay not specified; LC50 Shrimp 80 to 90 mg/l/48 hr aerated water /Conditions of bioassay not specified; LC50 Prawn 42.5 ppm/48 hr salt water /Conditions of bioassay not specified. This material may be toxic to aquatic life. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved incinerator or disposed in a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Domestic (Land, D.O.T.) Proper Shipping Name: SULFURIC ACID (WITH MORE THAN 51% ACID) Hazard Class: 8 UN/NA: UN1830 Packing Group: II Information reported for product/size: 440LB International (Water, I.M.O.) Proper Shipping Name: SULPHURIC ACID (WITH MORE THAN 51% ACID) Hazard Class: 8 UN/NA: UN1830 Packing Group: II Information reported for product/size: 440LB 15. Regulatory Information \Chemical Inventory Status - Part 1\ Ingredient TSCA EC Japan Australia Sulfuric Acid ( ) Yes Yes Yes Yes Water ( ) Yes Yes Yes Yes \Chemical Inventory Status - Part 2\ Canada-- Ingredient Korea DSL NDSL Phil. Sulfuric Acid ( ) Yes Yes No Yes Water ( ) Yes Yes No Yes \Federal, State & International Regulations - Part 1\ SARA SARA Ingredient RQ TPQ List Chemical Catg. Sulfuric Acid ( ) Yes No Water ( ) No No No No \Federal, State & International Regulations - Part 2\ RCRA- -TSCA- Ingredient CERCLA (d) Sulfuric Acid ( ) 1000 No No Water ( ) No No No

5 Chemical Weapons Convention: No TSCA 12(b): No CDTA: Yes SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure: No Reactivity: Yes (Pure / Liquid) Australian Hazchem Code: 2P Poison Schedule: None allocated. WHMIS: This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. 16. Other Information NFPA Ratings: Health: 3 Flammability: 0 Reactivity: 2 Other: Water reactive Label Hazard Warning: POISON! DANGER! CORROSIVE. LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE. MAY BE FATAL IF SWALLOWED OR CONTACTED WITH SKIN. HARMFUL IF INHALED. AFFECTS TEETH. WATER REACTIVE. CANCER HAZARD. STRONG INORGANIC ACID MISTS CONTAINING SULFURIC ACID CAN CAUSE CANCER. Risk of cancer depends on duration and level of exposure. Label Precautions: Do not get in eyes, on skin, or on clothing. Do not breathe mist. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Do not contact with water. Label First Aid: In all cases call a physician immediately. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before re-use. Excess acid on skin can be neutralized with a 2% bicarbonate of soda solution. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Product Use: Laboratory Reagent. Revision Information: MSDS Section(s) changed since last revision of document include: 3.