DuPont Kalrez. Oil and Gas Product Selector Guide. Technical Information April 2017

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1 DuPont Kalrez Oil and Gas Product Selector Guide Technical Information April 2017 DuPont has more than 30 years of experience providing perfluoroelastomer seals to the oil and gas industry. Over this time, reservoir pressures and temperatures have both risen while an increased focus on safety margin has driven wider use of this most resilient of elastomeric material classes. DuPont scientists have developed seals that can offer Rapid Gas Decompression (RGD) resistance to ISO, Norsok and Total industry certifications while resisting the harshest well fluid environments at temperatures that include both arctic surface conditions and high downhole temperatures and pressures. seals deliver proven reliability in extended lifetime services both above and below ground.

2 Product selector by type of application Type Chemical environment Applications requirements Suggested products DRILLING Drilling Tools Intervention Tools MWD/LWD COMPLETION Packing Elements Packers Formation Evaluation drilling fluids Drilling fluids, Sour gas (H 2 S) Strong acids (Formation opening) Drilling fluids, Sour gas (H 2 S) Drilling fluids Drilling fluids Drilling fluids Permanent, moveable or retrievable high and low temperature V-ring sets / chevron sets Permanent, moveable or retrievable Spectrum 7090 for short term Spectrum 6375 if no required 3065

3 Type Chemical environment Applications requirements Suggested products PRODUCTION Electric Submersible Pump (ESP) High temperature water and steam High temperature Maximise pump life Spectrum 6375 Enhanced Oil Recovery (EOR) Water/Steam injection compatibility Biocides Methanol High temperature steam resistance Enhanced Oil Recovery (EOR) Carbon dioxide compatibility Enhanced Oil Recovery (EOR) Sour gas Extreme sour gas (H 2 S) compatibility Christmas Tree Pipeline Valves Ball valves Control fluids, Spectrum 0040 if no required Spectrum 6375 Subsea Equipment Risers Monitoring/Logging High pressure water Methanol Biocides drilling fluids. drilling fluids Sour gas (H 2 S) Work with high hydrostatic pressures externally as well as internal well bore pressures Low temperature Electrical insulation High Pressure Spectrum 0040 if no required Spectrum 0040 if not required. Spectrum 0040 if RGD resistance required

4 Type Chemical environment Applications requirements Suggested products OTHER Electrical connectors drilling fluids, Low electrical conductivity s Spectrum 6375 Product Selector The following guide provides a quick and easy tool for the selection of products for the oil and gas industry. PHYSICAL PROPERTIES Maximum Application Temperature 2, Unit C F Hardness 3 Shore A % Modulus 4 MPa Not psi applicable 100% Modulus 4 MPa psi Tensile MPa Break 4 psi Break 4 % Compression Set 5, Pellet, C TR-10 Pellet Not AS applicable C F CERTIFICATIONS NORSOK M-710 (Rev. 2) Annex A Ö Annex B Ö ISO RGD Ö Sour Gas Ö TOTAL GS EP PVV 142 (Rev. 5) CSD 5.33 Ö CSD 6.99 Ö

5 SEAL TYPE AVAILABILITY O-ring Ö Ö Ö Ö Vrings Ö Ö Ö Ö Ö Boots Ö Ö T-Seal Ö Ö Ö Packers Ö Seal with embedded anti-extrusion device Ö Other Please Contact DuPont for Additional Information Special remark on low temperature performance: The low temperature capabilities depend on the application conditions. Based on our test results, increasing the pressure improves the low temperature sealing. Low temperature sealing performance does not correlate with measured values such as Tg, TR-10. Low Temperature Performance of Kalrez 0090 Parts AS568 size Leak Detection Gas Compression Pressure (MPa) Low Temp. Sealing ( C) ccm Air 16% radial 0.4 (Before cooling) - 21 * ccm Nitrogen 14% vertical 10 (Before cooling) - 40 ** ccm Nitrogen 14% vertical 10 (After cooling) - 25 ** * DuPont proprietary test method (Thomas, E., "Fluoroelastomer and Perfluoroelastomer Compatibility With Advanced Gas Turbine Lubricants," SAE Technical Paper ) ** James Walker & Co proprietary test method The influence of back up rings on seal performance Back up rings have long been regarded as a necessary evil to prevent o-ring extrusion at high temperatures and pressures. Back up rings increase part count, make assembly more complex and add significant cost. changes this paradigm. By having exceptional mechanical strength, even at high temperatures and pressures such as +232 C (450 F) and 150MPa (22,500 psi) does not extrude. This not only allows the efficiencies described above, but also significantly improves low temperature sealing performance at high and low pressures. shapes O-rings and customer parts

6 Product Description DuPont is an exceptional general purpose compound for use in the oil and gas industry. DuPont perfluoroelastomer parts deliver durable, reliable sealing solutions for applications requiring excellent rapid gas decompression (RGD) properties combined with high hardness and high modulus. Some application areas include downhole equipment such as drilling and completion tools as well as industrial equipment including pumps and valves. has been certified by two independent labs to meet rigorous requirements for resistance to RGD. In addition to demonstrated, DuPont seals have other chemical and temperature properties that provide superior performance. Chemical resistance: can be resistant to sour multi-phase fluids containing H2S as shown by the external NORSOK M-710 Rev 2 Sour Fluid aging resistance certification provided by MERL (UK). Broad temperature capability: retains high levels of resilience up to temperatures as high as 250 C (482 F) and down to 21 C ( 5.8 F). Under pressurized sealing conditions, 0900 has demonstrated low temperature performance down to 40 C ( 40 F) in customer laboratory tests. Highest rating of 0000 in severe test conditions demonstrates outstanding of DuPont. (0000 meaning no damage) Tested according to Norsok M710 rev2 standard (K312 (15.24x5.33mm) O-ring; 67% groove fill; Test gas 10% CO2 in methane) Spectrum 6375 DuPont 6375 perfluoroelastomer parts are designed to give outstanding performance in the widest possible range of chemicals and over a broad range of temperatures. This product is an excellent choice for use in acids, bases, amines, steam, highly alkaline solutions and many other aggressive chemicals. The compound is designed for continuous upper service temperature of 275 C (527 F). This high temperature stability translates into increased chemical resistance and longer life over all temperature ranges, even if high temperature process excursions occur. Spectrum 7090 DuPont Kalrezâ Spectrum 7090 perfluoroelastomer parts are specifically targeted for use in applications requiring high hardness/higher modulus properties. These specialty black parts have excellent mechanical properties including compression set resistance, seal force retention, response to temperature cycling effects and rapid gas decompression resistance. Kalrezâ Spectrum 7090 perfluoroelastomer parts are well suited for both static and dynamic sealing applications, especially applications that require extrusion resistance at higher temperatures. They also offer outstanding thermal stability and chemical resistance. A maximum application temperature of 325 C (617 F) is suggested. Short excursions to higher temperatures may also be possible.

7 Spectrum 0040 DuPont Spectrum 0040 perfluoroelastomer parts are specifically designed for low temperature environments where significant chemical resistance is required. Its chemical resistance is close to Spectrum 6375 which is the reference in the chemical processing industry. In addition, the proprietary polymer and cure technology enables the low temperature sealing performance (-42 C) of 0040 parts typically unattainable from other perfluoroelastomers parts. Spectrum 0040 is an excellent choice in applications for the oil and gas industry, or for other applications, where chemical resistance and elasticity are required in some of the coldest environments. Spectrum 0040 can also operate at temperatures up to 220 C DuPont 3065 is a long- standing compound that has proved its performance over more than 30 years in the field. It is a highly-filled product containing carbon black and fiber reinforcement, designed to function without extrusion under extreme pressure. It has good all round chemical resistance and excellent resistance to sour oil and amines has an upper service temperature of 288 C (550 F). The mechanical properties and chemical resistance of 3065 make it the best choice for many oil and gas well applications. In these applications, it is normally used in the form of V-rings and other custom parts rather than O-rings. With correct design 3065 can remove the need for back-up rings. Visit us at kalrez.dupont.com or vespel.dupont.com Contact DuPont at the following regional locations: North America Greater China Latin America Europe, Middle East, Africa Japan The information provided in this data sheet corresponds to DuPont knowledge on the subject at the date of its publication. This information may be subject to revision as new knowledge and experience becomes available. The data provided fall within the normal range of product properties and relate only to the specific material designated; these data may not be valid for such material used in combination with any other materials, additives or pigments or in any process, unless expressly indicated otherwise. The data provided should not be used to establish specification limits or used alone as the basis of design; they are not intended to substitute for any testing you may need to conduct to determine for yourself the suitability of a specific material for your particular purposes. Since DuPont cannot anticipate all variations in actual end-use and disposal conditions, DuPont does not guarantee results, makes no warranties and assumes no liability in connection with any use of this information. All such information is given and accepted at the buyer s risk. It is intended for use by persons having technical skill, at their own discretion and risk. Nothing in this publication is to be considered as a license to operate under or a recommendation to infringe any patent. CAUTION: Do not use DuPont materials in medical applications involving implantation in the human body or contact with internal body fluids or tissues unless the material has been provided from DuPont under a written contract that is consistent with DuPont policy regarding medical applications and expressly acknowledges the contemplated use. For further information, please contact your DuPont representative. You may also request a copy of DuPont POLICY Regarding Medical Applications H and DuPont CAUTION Regarding Medical Applications H Copyright DuPont The DuPont Oval Logo, DuPont, The miracles of science, Kalrez is a trademark or registered trademark of E.I. du Pont de Nemours and Company or its affiliates. All rights reserved. (8/16) Reference No. KZE A0217

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