SAFETY DATA SHEET according to applicable EC directive

Transcription

1 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING Product information Trade name : Use : Resin for adhesive systems Company : Huntsman Advanced Materials (Europe)BVBA Everslaan Everberg / Belgium Telephone : Telefax : Emergency telephone : (in France ORFILA : +33(0) ) number For further Product EHS related questions concerning this document or its contents, please contact: global_product_ehs_admat@huntsman.com 2. HAZARDS IDENTIFICATION Flammable Limited evidence of a carcinogenic effect. Harmful: may cause lung damage if swallowed. Vapours may cause drowsiness and dizziness. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature Bisphenol A epoxy resin containing solvent preparation Hazardous components Chemical Name CAS-No. Symbol(s): R-phrase(s) Concentration [%] solvent naphtha (petroleum), Xn, N R65 R66 R67 R51/ heavy arom. (R66-67) EC-No.: butoxyethanol EC-No.: Xn R20/21/22 R36/ xylene EC-No.: Xn R10 R20/21 R methylpentan-2-ol Xi R10 R EC-No.: naphthalene, pure Xn, N R22 R50/53 R EC-No.: ,2,4-trimethylbenzene Xn, N R10 R20 R36/37/ EC-No.: mesitylene EC-No.: R51/ Xi, N R10 R37 R51/ /8

2 4. FIRST AID MEASURES Inhalation Eye contact Skin contact Ingestion : Move to fresh air. Call a physician immediately. : Rinse immediately with plenty of water for at least 15 minutes. If eye irritation persists, consult a specialist. : Wash off with soap and plenty of water. If skin irritation persists, call a physician. : Do not induce vomiting. Immediately give plenty of water (if possible charcoal slurry). Obtain medical attention. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Extinguishing media which must not be used for safety reasons Specific hazards during fire fighting Special protective equipment for fire-fighters : Water spray. Dry powder. Carbon dioxide (CO2). Foam. : High volume water jet. : Burning produces obnoxious and toxic fumes. Carbon oxides. : Wear self-contained breathing apparatus and protective suit. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for cleaning up : Do not breathe vapours/dust. Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. : Do not allow material to contaminate ground water system. : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). 7. HANDLING AND STORAGE Handling Advice on safe handling : Provide sufficient air exchange and/or exhaust in work rooms. Handle and open container with care. 2/8

3 Storage Further information on storage conditions Storage hazard class Huntsman Advanced Materials : Keep away from food, drink and animal feeding stuffs. Keep container tightly closed. Keep at temperatures between 2 and 40 C. No special storage conditions required : Storage class 3, Flammable liquids 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Control parameters 2-butoxyethanol mg/m3 246 mg/m3 xylene mg/m3 441 mg/m3 4-methylpentan-2-ol mg/m3 170 mg/m3 Update Basis GB-OES 8H GB-OES 15M GB-OES 8H GB-OES 15M GB-OES 8H GB-OES 15M naphthalene, pure ,2,4-trimethylbenzene mg/m3 GB-OES 8H Engineering measures Ensure adequate ventilation, especially in confined areas. Personal protective equipment Respiratory protection : In case of insufficient ventilation wear suitable respiratory equipment. Filter type AX-P2 (organic vapours, particles) Eye protection Hand protection : goggles : Material of gloves for long term application (BTT>480 min): Butyl rubber Ethyl Vinyl Alcohol Laminate (EVAL) Material of gloves for short term/splash application (10 min<btt<480 min): Nitrile rubber Neoprene rubber Use gloves approved to relevant standards e.g. EN 374 (Europe), F739 (US). Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material and dexterity. Always seek advice from glove suppliers. Additonal information can be found for instance at 3/8

4 Skin and body protection Hygiene measures Protective measures : long sleeved clothing : Keep away from food, drink and animal feeding stuffs. Wash hands before breaks and immediately after handling the product. : Avoid contact with skin, eyes and clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Colour Odour : liquid : amber : solvent Boiling point : > 200 C Thermal decomposition : > 200 C Flash point : 23 C Method: DIN (Pensky-Martens Closed Cup) Density : approx.0.95 g/cm3 at 25 C Water solubility : at 20 C Note: insoluble Miscibility with water Viscosity, dynamic : immiscible at 20 C : 2,000-2,800 mpa.s at 25 C 10. STABILITY AND REACTIVITY Conditions to avoid Materials to avoid Hazardous decomposition products : Note: Take necessary action to avoid static electricity discharge. : Strong acids and strong bases. Strong oxidizing agents. : Carbon oxides. Burning produces obnoxious and toxic fumes. 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50 rat Dose: > 5,000 mg/kg 4/8

5 Eye irritation Skin irritation Sensitization : No eye irritation rabbit : No skin irritation rabbit dermal : Causes sensitization. guinea pig dermal 12. ECOLOGICAL INFORMATION Ecotoxicity effects Further information on ecology Additional ecological information : Avoid subsoil penetration. Prevent product from entering drains. Do not contaminate surface water. 13. DISPOSAL CONSIDERATIONS Product : Waste Key Number: Must be incinerated, when in compliance with local regulations. Container : Empty containers can be landfilled after cleaning, when in compliance with the Environmental Protection (Duty of Care) Regulations TRANSPORT INFORMATION Land transport ADR: UN-No: 1866 Class: 3 Classification code: F1 Packaging group: III Risk No.: 30 ADR/RID-Labels: 3 Proper shipping name: RESIN SOLUTION, FLAMMABLE RID: UN-No: 1866 Class: 3 Packaging group: III Risk No.: 30 ADR/RID-Labels: 3 5/8

6 Proper shipping name: RESIN SOLUTION, FLAMMABLE Sea transport IMDG: UN-No: 1866 Class: 3 Packaging group: III ADR/RID-Labels: 3 MFAG: EmS: F-E S-E Proper shipping name: RESIN SOLUTION Air transport IATA-DGR: UN/ID No.: UN 1866 Class: 3 Packaging group: III Packing instruction (cargo 310 aircraft): Max. Qty/Pack.: L ( = No limit ) Packing instruction 309 (passenger aircraft): Max. Qty/Pack.: L ( = No limit ) ADR/RID-Labels: 3 Proper shipping name: RESIN SOLUTION 15. REGULATORY INFORMATION Labelling according to EEC Directive Labelling required Symbol(s): : Xn Harmful N Dangerous for the environment R-phrase(s) : R10 Flammable R40 Limited evidence of a carcinogenic effect. R65 Harmful: may cause lung damage if swallowed. R67 Vapours may cause drowsiness and dizziness. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s) : S23 Do not breathe vapour, spray. S24/25 Avoid contact with skin and eyes. 6/8

7 S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Hazardous components which must be listed on the label : solvent naphtha (petroleum), heavy arom. (R66-67) EC-No.: naphthalene, pure EC-No.: National legislation Notification status : EINECS yes : TSCA yes : DSL yes : AICS yes : KECI (KR) yes : JEX (JP) yes 16. OTHER INFORMATION List of R-phrases (Section 3) 7/8

8 R10 Flammable R20 Harmful by inhalation. R20/21 Harmful by inhalation and in contact with skin. R20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R22 Harmful if swallowed. R36/37/38 Irritating to eyes, respiratory system and skin. R36/38 Irritating to eyes and skin. R37 Irritating to respiratory system. R38 Irritating to skin. R40 Limited evidence of a carcinogenic effect. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. The provision of Safety Data Sheets comes under Regulation 6 of CHIP (CHIP is the recognised abbreviation for the Chemicals Hazard Information and Packaging Regulations). This is an addition to the Health and Safety at Work Act 1974.Users of products supplied by Huntsman Advanced Materials should take appropriate measures to ensure working practices are in accordance with the Control of Substances Hazardous to Health Regulations (COSHH). All information is based on results gained from experience and tests and is believed to be accurate but is given without acceptance of liability for loss or damage attributable to reliance thereon as conditions of use lie outside our control. Users should always carry out sufficient tests to establish the suitability of any products for their intended applications. No statements shall be incorporated in any contract unless expressly agreed in writing nor construed as recommending the use of any product in conflict of any patent. All goods are supplied subject to Huntsman Advanced Materials General Conditions of Sale. 8/8