Page: 1/17 BASF Safety data sheet according to Regulation (EC) No. 1907/2006 Date / Revised: Version: 2.1 Product: Efka PB 2010

Transcription

1 Safety data sheet Page: 1/17 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Efka PB Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: process chemical 1.3. Details of the supplier of the safety data sheet Company: BASF SE Ludwigshafen GERMANY Regional Business Unit Dispersions and Resins Europe Telephone: address: 1.4. Emergency telephone number International emergency number: Telephone: SECTION 2: Hazards Identification 2.1. Classification of the substance or mixture According to Regulation (EC) No 1272/2008 [CLP] Asp. Tox. 1 Flam. Liq. 3 STOT SE 3 (Vapours may cause drowsiness and dizziness.)

2 Page: 2/17 STOT SE 3 (irritating to respiratory system) Aquatic Chronic 2 According to Directive 67/548/EEC or 1999/45/EC Possible Hazards: Flammable. Irritating to respiratory system. Harmful: may cause lung damage if swallowed. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. For the classifications not written out in full in this section the full text can be found in section Label elements Globally Harmonized System, EU (GHS) Pictogram: Signal Word: Danger Hazard Statement: H226 H304 H336 H335 H411 Flammable liquid and vapour. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. May cause respiratory irritation. Toxic to aquatic life with long lasting effects. Precautionary Statements (Prevention): P273 Avoid release to the environment. P271 Use only outdoors or in a well-ventilated area. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P280f Wear protective gloves and eye/face protection. P243 Take precautionary measures against static discharge. P260i Do not breathe dust/gas/mist/vapours. P241 Use explosion-proof electrical/ventilating/lighting/equipment. P240 Ground/bond container and receiving equipment. P242 Use only non-sparking tools. Precautionary Statements (Response):

3 Page: 3/17 P312 Call a POISON CENTER or doctor/physician if you feel unwell. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P391 Collect spillage. P331 Do NOT induce vomiting. P370 + P In case of fire: Use foam or dry powder for extinction. Precautionary Statements (Storage): P233 Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection point. Labeling of special preparations (GHS): Repeated exposure may cause skin dryness or cracking. According to Regulation (EC) No 1272/2008 [CLP] Hazard determining component(s) for labelling: SOLVENT NAPHTHA, Naphtha (petroleum), hydrodesulfurized heavy ( < 0,1% Benzene ) According to Directive 67/548/EEC or 1999/45/EC EEC Directives Hazard symbol(s) N Dangerous for the environment. Xn Harmful. R-phrase(s) R10 Flammable. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R37 Irritating to respiratory system. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. S-phrase(s)

4 Page: 4/17 S24 Avoid contact with skin. S23.3 Do not breathe vapour/spray. S51 Use only in well-ventilated areas. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Hazard determining component(s) for labelling: SOLVENT NAPHTHA, Naphtha (petroleum), hydrodesulfurized heavy ( < 0,1% Benzene ) 2.3. Other hazards According to Regulation (EC) No 1272/2008 [CLP] No specific dangers known, if the regulations/notes for storage and handling are considered. SECTION 3: Composition/Information on Ingredients 3.1. Substances Not applicable 3.2. Mixtures Chemical nature Polymer based on: vinyl ether, derivative dissolved in: organic solvents Hazardous ingredients (GHS) according to Regulation (EC) No. 1272/2008 Solvent naphtha (petroleum), light arom.; Low boiling point naphtha - unspecified Content (W/W): >= 70 % - <= 90 % Asp. Tox. 1 CAS Number: Flam. Liq. 3 EC-Number: STOT SE 3 (drowsiness and dizziness) REACH registration number: 01- STOT SE 3 (irr. to respiratory syst.) Aquatic Chronic 2 INDEX-Number: H411, H226, H304, H336, H335, EUH066 Hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics (2-25%)

5 Page: 5/17 Content (W/W): >= 2.5 % - < 10 % Asp. Tox. 1 REACH registration number: 01- Flam. Liq STOT SE 3 (drowsiness and dizziness) INDEX-Number: Aquatic Chronic 2 H411, H226, H304, H336, EUH066 styrene Content (W/W): >= 0.1 % - < 2.5 % CAS Number: EC-Number: REACH registration number: INDEX-Number: Asp. Tox. 1 Flam. Liq. 3 Acute Tox. 4 (Inhalation - vapour) Skin Corr./Irrit. 2 Eye Dam./Irrit. 2 STOT SE 3 (irr. to respiratory syst.) STOT RE (Auditory organ) 1 H226, H319, H315, H332, H304, H335, H372 Hazardous ingredients according to Directive 1999/45/EC Solvent naphtha (petroleum), light arom.; Low boiling point naphtha - unspecified Content (W/W): >= 70 % - <= 90 % CAS Number: EC-Number: REACH registration number: INDEX-Number: Hazard symbol(s): Xn, N R-phrase(s): 10, 37, 65, 66, 51/53, 67 Hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics (2-25%) Content (W/W): >= 2.5 % - < 10 % REACH registration number: INDEX-Number: Hazard symbol(s): Xn, N R-phrase(s): 10, 65, 66, 67, 51/53 styrene Content (W/W): >= 0.1 % - < 2.5 % CAS Number: EC-Number: REACH registration number: INDEX-Number: Hazard symbol(s): Xn R-phrase(s): 10, 20, 36/37/38, 48/20, 65 For the classifications not written out in full in this section, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, the full text is listed in section 16.

6 Page: 6/17 SECTION 4: First-Aid Measures 4.1. Description of first aid measures Immediately remove contaminated clothing. If inhaled: If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention. On skin contact: Wash thoroughly with soap and water. On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. On ingestion: Immediately rinse mouth and then drink plenty of water, do not induce vomiting, seek medical attention Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section Indication of any immediate medical attention and special treatment needed Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote, administer corticosteroid dose aerosol to prevent pulmonary odema. SECTION 5: Fire-Fighting Measures 5.1. Extinguishing media Suitable extinguishing media: dry powder, foam 5.2. Special hazards arising from the substance or mixture harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire Advice for fire-fighters Special protective equipment: Wear a self-contained breathing apparatus. Further information: The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations.

7 Page: 7/17 SECTION 6: Accidental Release Measures 6.1. Personal precautions, protective equipment and emergency procedures Use personal protective clothing. Breathing protection required Environmental precautions Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater Methods and material for containment and cleaning up For large amounts: Pump off product. For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations Reference to other sections Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13. SECTION 7: Handling and Storage 7.1. Precautions for safe handling Ensure thorough ventilation of stores and work areas. Protection against fire and explosion: Sources of ignition should be kept well clear. Take precautionary measures against static discharges. If delivered in plastic packing, highest permissable emptying temperature is 5 Kelvin below the flash point Conditions for safe storage, including any incompatibilities Further information on storage conditions: Keep container tightly closed and in a cool place Specific end use(s) For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed. SECTION 8: Exposure Controls/Personal Protection 8.1. Control parameters Components with occupational exposure limits : styrene : Naphtha (petroleum), hydrodesulfurized heavy; Low boiling point hydrogen treated naphtha

8 Page: 8/ : Solvent naphtha (petroleum), light arom. Components with PNEC : styrene freshwater: mg/l marine water: mg/l intermittent release: 0.04 mg/l sediment (freshwater): mg/kg sediment (marine water): mg/kg soil: 0.2 mg/kg STP: 5 mg/l Components with DNEL : Solvent naphtha (petroleum), light arom. worker: Long-term exposure- systemic effects, Inhalation: ppm consumer: Long-term exposure- systemic effects, Inhalation: 179 mg/m : styrene worker: Long-term exposure- systemic effects, Inhalation: 85 mg/m3 worker: Long-term exposure- systemic effects, dermal: 406 mg/m Exposure controls Personal protective equipment Respiratory protection: Suitable respiratory protection for higher concentrations or long-term effect: Gas filter for gases/vapours of organic compounds (boiling point >65 C, e. g. EN Type A) Hand protection: Chemical resistant protective gloves (EN 374) Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): fluoroelastomer (FKM) mm coating thickness Polyethylene-Laminate (PE laminate) - ca. 0.1 mm coating thickness Suitable materials short-term contact and/or splashes (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN 374) nitrile rubber (NBR) mm coating thickness Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing. Manufacturer's directions for use should be observed because of great diversity of types. Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166) Body protection:

9 Page: 9/17 Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN in case of splashes or EN ISO in case of dust). General safety and hygiene measures Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Form: Colour: Odour: Odour threshold: liquid colourless product specific Not determined due to potential health hazard by inhalation. ph value: not soluble Freezing point: not determined Boiling range: C (1,013 hpa) Information applies to the solvent. Flash point: 41 C Evaporation rate: not determined Flammability: Flammable. Lower explosion limit: For liquids not relevant for classification and labelling., The lower explosion point may be 5-15 C below the flash point. Upper explosion limit: For liquids not relevant for classification and labelling. Ignition temperature: 210 C (DIN 51794) Vapour pressure: not determined Density: 0.88 g/cm3 (20 C) Relative density: 0.88 (20 C) Relative vapour density (air): not determined Solubility in water: not soluble Solubility (qualitative) solvent(s): organic solvents soluble (DIN 53217)

10 Page: 10/17 Partitioning coefficient n-octanol/water (log Kow): not applicable for mixtures Self ignition: not self-igniting Thermal decomposition: not determined Viscosity, dynamic: mpa.s (20 C, 60 1/s) Explosion hazard: not explosive Fire promoting properties: not fire-propagating (DIN EN ISO 2555 (LV)) 9.2. Other information Hygroscopy: Surface tension: Grain size distribution: Non-hygroscopic No data available. The substance / product is marketed or used in a non solid or granular form. SECTION 10: Stability and Reactivity Reactivity No hazardous reactions if stored and handled as prescribed/indicated Chemical stability The product is stable if stored and handled as prescribed/indicated Possibility of hazardous reactions No hazardous reactions when stored and handled according to instructions Conditions to avoid See MSDS section 7 - Handling and storage Incompatible materials Substances to avoid: No substances known that should be avoided Hazardous decomposition products Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. SECTION 11: Toxicological Information Information on toxicological effects Acute toxicity

11 Page: 11/17 Experimental/calculated data: LD50 rat (oral): > 5,000 mg/kg LC50 rat (by inhalation): 4 h not determined LD50 rat (dermal): not determined Irritation Experimental/calculated data: Skin corrosion/irritation rabbit: non-irritant Serious eye damage/irritation rabbit: non-irritant Respiratory/Skin sensitization Experimental/calculated data: No data available. Germ cell mutagenicity Assessment of mutagenicity: No data available concerning mutagenic effects. Carcinogenicity Assessment of carcinogenicity: No data available. Information on: styrene Assessment of carcinogenicity: A clear indication of an increased risk of cancer in humans has so far not been shown. IARC (International Agency for Research on Cancer) has classified this substance as group 2B (The agent is possibly carcinogenic to humans) Reproductive toxicity Assessment of reproduction toxicity: No data available. Developmental toxicity

12 Page: 12/17 Assessment of teratogenicity: No data available. Specific target organ toxicity (single exposure) Assessment of STOT single: A single exposure may have relevant toxic effects on organs named in section 2 of this safety data sheet. Remarks: The product has not been tested. The statement has been derived from the properties of the Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: Effects on the kidney of male rats were detected after repeated exposure. These effects are specific for the male rat and are known to be of no relevance to humans. After repeated exposure the prominent effect is local irritation. The product has not been tested. The statement has been derived from the properties of the Aspiration hazard Aspiration hazard Other relevant toxicity information Has a degreasing effect on skin. SECTION 12: Ecological Information Toxicity Toxicity to fish: LC50 (96 h) 1-10 mg/l, Fish Aquatic invertebrates: LC50 (48 h) 1-10 mg/l, daphnia Aquatic plants: EC50 (72 h) 1-10 mg/l, algae Microorganisms/Effect on activated sludge: EC50 (0.5 h) 1-10 mg/l, bacteria

13 Page: 13/17 Chronic toxicity to fish: No data available. Chronic toxicity to aquatic invertebrates: No data available. Assessment of terrestrial toxicity: No data available concerning terrestrial toxicity Persistence and degradability Assessment biodegradation and elimination (H2O): Not readily biodegradable (by OECD criteria). The product is not very soluble in water and can thus be removed from water mechanically in suitable effluent treatment plants. The product has not been tested. The statement has been derived from the properties of the Bioaccumulative potential Assessment bioaccumulation potential: Because of the n-octanol/water distribution coefficient (log Pow) accumulation in organisms is possible Mobility in soil Assessment transport between environmental compartments: The substance will slowly evaporate into the atmosphere from the water surface. Adsorption to solid soil phase is expected Results of PBT and vpvb assessment According to Regulation (EC) No.453/2010: The product does not fulfill the criteria for PBT (Persistent/bioaccumulative/toxic) and vpvb (very persistent/very bioaccumulative) Other adverse effects No data available Additional information Add. remarks environm. fate & pathway: Treatment in biological waste water treatment plants has to be performed according to local and administrative regulations.

14 Page: 14/17 SECTION 13: Disposal Considerations Waste treatment methods Must be disposed of or incinerated in accordance with local regulations. Contaminated packaging: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents. SECTION 14: Transport Information Land transport ADR UN number UN1866 UN proper shipping name: RESIN SOLUTION (contains SOLVENT NAPHTHA) Transport hazard class(es): 3, EHSM Packing group: III Environmental hazards: yes Special precautions for user: Tunnel code: D/E SP 640 E RID UN number UN1866 UN proper shipping name: RESIN SOLUTION (contains SOLVENT NAPHTHA) Transport hazard class(es): 3, EHSM Packing group: III Environmental hazards: yes Special precautions for SP 640 E user: Inland waterway transport ADN UN number UN1866 UN proper shipping name: RESIN SOLUTION (contains SOLVENT NAPHTHA) Transport hazard class(es): 3, EHSM Packing group: III Environmental hazards: yes Special precautions for SP 640 E user: Transport in inland Not evaluated waterway vessel:

15 Page: 15/17 Sea transport IMDG UN number: UN 1866 UN proper shipping name: RESIN SOLUTION (contains SOLVENT NAPHTHA) Transport hazard class(es): 3, EHSM Packing group: III Environmental hazards: yes Marine pollutant: YES Special precautions for None known user: Air transport IATA/ICAO UN number: UN 1866 UN proper shipping name: RESIN SOLUTION (contains SOLVENT NAPHTHA) Transport hazard class(es): 3 Packing group: III Environmental hazards: No Mark as dangerous for the environment is needed Special precautions for None known user: UN number See corresponding entries for UN number for the respective regulations in the tables above UN proper shipping name See corresponding entries for UN proper shipping name for the respective regulations in the tables above Transport hazard class(es) See corresponding entries for Transport hazard class(es) for the respective regulations in the tables above Packing group See corresponding entries for Packing group for the respective regulations in the tables above Environmental hazards See corresponding entries for Environmental hazards for the respective regulations in the tables above Special precautions for user See corresponding entries for Special precautions for user for the respective regulations in the tables above.

16 Page: 16/ Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Regulation: Not evaluated Shipment approved: Not evaluated Pollution name: Not evaluated Pollution category: Not evaluated Ship Type: Not evaluated SECTION 15: Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture If other regulatory information applies that is not already provided elsewhere in this safety data sheet, then it is described in this subsection Chemical Safety Assessment Chemical Safety Assessment not yet performed due to registration timelines SECTION 16: Other Information Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, if mentioned in section 2 or 3: Xn Harmful. N Dangerous for the environment. 10 Flammable. 37 Irritating to respiratory system. 65 Harmful: may cause lung damage if swallowed. 66 Repeated exposure may cause skin dryness or cracking. 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 67 Vapours may cause drowsiness and dizziness. 20 Harmful by inhalation. 36/37/38 Irritating to eyes, respiratory system and skin. 48/20 Harmful: Danger of serious damage to health by prolonged exposure through inhalation. Asp. Tox. Aspiration hazard Flam. Liq. Flammable liquid STOT SE Specific target organ toxicity single exposure Aquatic Chronic Hazardous to the aquatic environment - chronic Acute Tox. Acute toxicity Skin Corr./Irrit. Skin corrosion/irritation Eye Dam./Irrit. Serious eye damage/eye irritation STOT RE Specific target organ toxicity repeated exposure H411 Toxic to aquatic life with long lasting effects. H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H336 May cause drowsiness or dizziness.

17 Page: 17/17 H335 May cause respiratory irritation. EUH066 Repeated exposure may cause skin dryness or cracking. H319 Causes serious eye irritation. H315 Causes skin irritation. H332 Harmful if inhaled. H372 Causes damage to organs (Auditory organ) through prolonged or repeated exposure. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed. Vertical lines in the left hand margin indicate an amendment from the previous version.