: Rust Out. SECTION 1: Identification. SECTION 2: Hazard(s) identification Identification

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1 SECTION 1: Identification 1.1. Identification Product form Trade name Rust Out Date of issue: 03/09/2017 Revision date: 03/21/2017 Supersedes: 03/21/2017 Version: 1.5 : Mixtures : Rust Out Product code : Recommended use and restrictions on use Recommended use 1.3. Supplier Synthetic Labs 24 Victory Lane Dracut, MA United States T F info@syntecpro.com Emergency telephone number : Laundry,Neutralize Emergency number : SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Acute toxicity (oral) Category 4 Acute toxicity (dermal) Category 4 Serious eye damage/eye irritation Category 1 Harmful if swallowed Harmful in contact with skin Causes serious eye damage 2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) : Danger GHS05 GHS07 : Harmful if swallowed or in contact with skin Causes serious eye damage : Wash hands, forearms and face thoroughly after handling Do not eat, drink or smoke when using this product Wear protective gloves/protective clothing/eye protection/face protection If swallowed: Call a poison center/doctor/ if you feel unwell If on skin: Wash with plenty of water/ If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison center/doctor/ Call a poison center/doctor/ if you feel unwell Specific treatment (see... on this label) Rinse mouth Take off contaminated clothing and wash it before reuse Dispose of contents/container to Other hazards which do not result in classification 2.4. Unknown acute toxicity (GHS US) 03/21/2017 EN (English US) Page 1

2 SECTION 3: Composition/Information on ingredients 3.1. Substances 3.2. Mixtures Name Product identifier % GHS-US classification Hydrofluorosilic Acid (CAS-No.) Acute Tox. 4 (Oral), H302 Acute Tox. 3 (Dermal), H311 Skin Corr. 1A, H314 Eye Dam. 1, H318 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Call a poison center/doctor/physician if you feel unwell. : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. Take off contaminated clothing. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician immediately. : Rinse mouth. Call a poison center/doctor/physician if you feel unwell Most important symptoms and effects (acute and delayed) Symptoms/effects after eye contact : Serious damage to eyes Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media 5.2. Specific hazards arising from the chemical Reactivity : Water spray. Dry powder. Foam. Carbon dioxide Special protective equipment and precautions for fire-fighters Protection during firefighting SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures : The product is non-reactive under normal conditions of use, storage and transport. : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Avoid contact with skin, eyes and clothing. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up : Take up liquid spill into absorbent material. Other information : Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Do not get in eyes, on skin, or on clothing. Wear personal protective equipment. : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 03/21/2017 EN (English US) 2/7

3 7.2. Conditions for safe storage, including any incompatibilities Storage conditions SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Store in a well-ventilated place. Keep cool. ACGIH ACGIH TWA (mg/m³) 2.5 mg/m³ OSHA OSHA PEL (TWA) (mg/m³) 2.5 mg/m³ NIOSH NIOSH REL (TWA) (mg/m³) 2.5 mg/m³ 8.2. Appropriate engineering controls Appropriate engineering controls Environmental exposure controls : Ensure good ventilation of the work station. : Avoid release to the environment Individual protection measures/personal protective equipment Hand protection: Protective gloves Eye protection: Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Liquid. Color : Green Odor : characteristic Odor threshold ph : 2 Melting point : Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) :. Vapor pressure Relative vapor density at 20 C Relative density Specific gravity / density : 1.07 g/m³ Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic 03/21/2017 EN (English US) 3/7

4 Explosion limits Explosive properties Oxidizing properties 9.2. Other information SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Rust Out ATE US (oral) ATE US (dermal) LD50 oral rat ATE US (oral) ATE US (dermal) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC group Reproductive toxicity Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard Symptoms/effects after eye contact SECTION 12: Ecological information Toxicity Ecology - general : Oral: Harmful if swallowed. Dermal: Harmful in contact with skin mg/kg body weight mg/kg body weight 1365 mg/kg mg/kg body weight mg/kg body weight ph: 2 : Causes serious eye damage. ph: Not classifiable : Serious damage to eyes. : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. 03/21/2017 EN (English US) 4/7

5 LC50 fish 1 > 10 mg/l (LC50; 96 h; Brachydanio rerio) Threshold limit algae 1 10 mg/l (EC0; 96 h) Persistence and degradability Persistence and degradability Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD Biodegradability: not applicable. Reacts with water: release of toxic/harmful substances. No (test)data on mobility of the components available Bioaccumulative potential Bioaccumulative potential Not bioaccumulative Mobility in soil Other adverse effects Effect on the global warming GWPmix comment : No known effects from this product. : No known effects from this product. SECTION 13: Disposal considerations Disposal methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Transport document description : NA1760 Compounds, cleaning liquid (Fluorosilicic Acid), 8, III UN-No.(DOT) : NA1760 Proper Shipping Name (DOT) : Compounds, cleaning liquid Fluorosilicic Acid Class (DOT) : 8 - Class 8 - Corrosive material 49 CFR Packing group (DOT) : III - Minor Danger Hazard labels (DOT) : 8 - Corrosive DOT Packaging Non Bulk (49 CFR 173.xxx) : 203 DOT Packaging Bulk (49 CFR 173.xxx) : 241 DOT Symbols : D - Proper shipping name for domestic use only, or to and from Canada,G - Identifies PSN requiring a technical name 03/21/2017 EN (English US) 5/7

6 DOT Special Provisions (49 CFR ) DOT Packaging Exceptions (49 CFR 173.xxx) : 154 DOT Quantity Limitations Passenger aircraft/rail (49 CFR ) DOT Quantity Limitations Cargo aircraft only (49 CFR ) DOT Vessel Stowage Location DOT Vessel Stowage Other : IB3 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kpa at 50 C (1.1 bar at 122 F), or 130 kpa at 55 C (1.3 bar at 131 F) are authorized, except for UN2672 (also see Special Provision IP8 in Table 2 for UN2672). N37 - This material may be shipped in an integrally-lined fiber drum (1G) which meets the general packaging requirements of subpart B of part 173 of this subchapter, the requirements of part 178 of this subchapter at the packing group assigned for the material and to any other special provisions of column 7 of the table. T (d)(2) Normal (d)(3) TP1 - The maximum degree of filling must not exceed the degree of filling determined by the following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. TP28 - A portable tank having a minimum test pressure of 2.65 bar (265 kpa) may be used provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous material, as defined in of this subchapter, where the test pressure is 1.5 times the MAWP. : 5 L : 60 L Emergency Response Guide (ERG) Number : 154 : A - The material may be stowed on deck or under deck on a cargo vessel and on a passenger vessel. : 40 - Stow clear of living quarters Other information : No supplementary information available. Transportation of Dangerous Goods Transport by sea Not regulated Air transport Not regulated SECTION 15: Regulatory information US Federal regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory International regulations CANADA Listed on the Canadian DSL (Domestic Substances List) EU-Regulations National regulations US State regulations U.S. - New Jersey - Right to Know Hazardous Substance List SECTION 16: Other information Revision date : 03/21/ /21/2017 EN (English US) 6/7

7 Full text of H-phrases: H302 H311 H312 H314 H318 Harmful if swallowed Toxic in contact with skin Harmful in contact with skin Causes severe skin burns and eye damage Causes serious eye damage Hazard Rating Health Flammability Physical : 3 Serious Hazard - Major injury likely unless prompt action is taken and medical treatment is given : 0 Minimal Hazard - Materials that will not burn : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives. SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 03/21/2017 EN (English US) 7/7