Safety Data Sheet. according to Regulation (EC) No 1907/2006. ADDINOL Corrosion Protection Fluid KO 6 F Spray

Transcription

1 Page 1 of 10 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Aerosol - Corrosion inhibitor Details of the supplier of the safety data sheet Company name: Street: Place: Gebäude 4609 Am Haupttor D Leuna Telephone: +49 (0) Telefax:+49 (0) Contact person: Internet: Responsible Department: 1.4. Emergency telephone number: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture info@addinol.de Application Technology ADDINOL Application Technology +49 (0) This number is serviced during office hours. Indications of danger: F+ - Extremely flammable R phrases: Extremely flammable. Repeated exposure may cause skin dryness or cracking. GHS classification Hazard categories: Aerosol: Aerosol 1 Hazard Statements: Extremely flammable aerosol. Pressurised container: May burst if heated Label elements Signal word: Pictograms: Danger GHS02 Hazard statements H222 Extremely flammable aerosol. H229 Pressurised container: May burst if heated. Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P211 Do not spray on an open flame or other ignition source. P251 Do not pierce or burn, even after use.

2 Page 2 of 10 P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 C/122 F. Special labelling of certain mixtures EUH066 Repeated exposure may cause skin dryness or cracking. Additional advice on labelling This preparation is hazardous in the sense of regulation (EC) No 1272/2008 [GHS] Other hazards In case of insufficient ventilation and/or through use, explosive/highly flammable mixtures may develop. SECTION 3: Composition/information on ingredients 3.2. Mixtures Hazardous components EC No CAS No Index No REACH No Chemical name Classification GHS classification butane F+ - Extremely flammable R12 Flam. Gas 1; H220 Hydrocarbons, C10-C13, n-alkanes, iso-alkanes, cyclics, < 2% aromatics Xn - Harmful R65-66 Asp. Tox. 1; H304 Quantity < 40 % < 25 % propane F+ - Extremely flammable R12 Flam. Gas 1; H220 Full text of R and H phrases: see Section 16. Further Information DMSO-Extrakt < 3 %, IP 346. < 20 % Concentration of PCBs < 1mg/kg. Classification system: The classification corresponds to the current EC lists and is completed by information from specialist literature and company information. SECTION 4: First aid measures 4.1. Description of first aid measures General information Move victim out of danger zone and lay down. Position and transport victim on their side. In case of respiratory distress, bring into semi-upright, seated position. Self-protection of the first aider.. Change contaminated clothing. Do not put any product-impregnated cleaning rags into your trouser pockets. After inhalation Move victim to fresh air. Put victim at rest and keep warm. Seek medical attention if problems persist. In case of breathing difficulties administer oxygen. After contact with skin After contact with skin, wash immediately with plenty of water and soap. In case of skin irritation, seek medical treatment.

3 Page 3 of 10 After contact with eyes Rinse immediately carefully and thoroughly with eye-bath or water. In case of troubles or persistent symptoms, consult an ophthalmologist. After ingestion Do not induce vomiting. Rinse mouth thoroughly with water. Immediately get medical attention Most important symptoms and effects, both acute and delayed following inhalation: drowsiness. Headache. Nausea Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Carbon dioxide (CO2).Dry extinguishing powder. alcohol resistant foam. Unsuitable extinguishing media High power water jet Special hazards arising from the substance or mixture Can be released in case of fire: Carbon dioxide (CO2). Carbon monoxide. Nitrogen oxides (NOx). Carbon black. Vapours may form explosive mixtures with air Advice for firefighters In case of fire: Wear self-contained breathing apparatus. Wear chemical resistant suit. Additional information Extinguishing materials should be selected according to the surrounding area. Use water spray/stream to protect personnel and to cool endangered containers. In case of fire and/or explosion do not breathe fumes. Contaminated fire-fighting water must be collected separately. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Guide people to safety. Wear a self-contained breathing apparatus and chemical resistant suit. Vapours are heavier than air and will spread at floor level. Avoid contact with skin and eyes. Keep away from sources of ignition - No smoking Environmental precautions Do not empty into drains or the aquatic environment. In case of gas being released or leakage into waters, ground or the drainage system, the appropriate authorities must be informed. Prevent spreading over great surfaces (e.g. by damming or installing oil booms) Methods and material for containment and cleaning up Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the assimilated material according to the section on waste disposal. Clean contaminated objects and areas thoroughly observing environmental regulations Reference to other sections Refer to the provisions listed in Sections 8, 12 and 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling

4 Page 4 of 10 Advice on safe handling Work in well ventilated zones or use proper respiratory protection. Keep away from sources of ignition - No smoking. Take precautionary measures against static discharges. Due to danger of explosion, prevent leakage of vapours into cellars, flues and ditches. Do not spray into flames or ignition sources. Advice on protection against fire and explosion Keep away from sources of ignition - No smoking. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Heating causes rise in pressure with risk of bursting Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep the packing dry and well sealed to prevent contamination and absorbtion of dampness. Keep container tightly closed in a cool place. Keep away from sources of ignition - No smoking. Please note: TRG 300, aerosol directive (75/324/EEC). Advice on storage compatibility Keep away from food, drink and animal feedingstuffs. Keep away from: Oxidizing agents. Material, rich in oxygen, oxidizing. Further information on storage conditions Recommended storage temperature: C. Do not store at temperatures over: 50 C Specific end use(s) Further information: refer to Technical Data Sheet. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Exposure limits (EH40) CAS No Substance ppm mg/m³ fibres/ml Category Origin Hydrocarbons, C10-C13, n-alkanes, 200 TWA (8 h) MAK iso-alkanes, cyclics, < 2% aromatics STEL (15 min) Butane TWA (8 h) WEL Additional advice on limit values source: 8.2. Exposure controls MAK STEL (15 min) WEL Appropriate engineering controls Provide for sufficient ventilation and punctiform suction at critical points. Protective and hygiene measures Wash hands before breaks and at the end of work. Take off immediately all contaminated clothing. Wash contaminated clothing prior to re-use. Do not eat, drink, smoke or sneeze at the workplace. Eye/face protection Tightly sealed safety glasses. German Industry Norms (DIN) / European Norms (EN): DIN EN 166

5 Page 5 of 10 Hand protection Tested protective gloves are to be worn: German Industry Norms (DIN) / European Norms (EN): DIN EN 374 Duration of wearing with permanent contact: 480 min Suitable material: NBR (Nitrile rubber). Thickness of glove material: 0.7 mm. Duration of wearing with occasional contact (splashes): 30 min Suitable material: NBR (Nitrile rubber). Thickness of glove material: 0.4 mm Protect skin by using skin protective cream. Skin protection Wear suitable protective clothing. Change contaminated clothing. Do not put any product-impregnated cleaning rags into your trouser pockets. Respiratory protection Physical state: Colour: If technical suction or ventilation measures are not possible or are insufficient, protective breathing apparatus must be worn. Breathing protection with filter against organic gases and vapours type A - boiling point > 65 C: A1: < 1000 ppm; A2: < 5000 ppm; A3: < ppm SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Odour: Changes in the physical state Initial boiling point and boiling range: Flash point: gaseous light brown like: mineral oil. < -20 C < -20 C Test method DIN EN ISO 2592 Explosive properties In case of insufficient ventilation and/or through use, explosive/highly flammable mixtures may develop. Lower explosion limits: Upper explosion limits: Ignition temperature: 0,6 vol. % 10,8 vol. % 210 C Oxidizing properties In case of insufficient ventilation and/or through use, explosive/highly flammable mixtures may develop. Density (at 15 C): 0,646 g/cm³ calculated Water solubility: insoluble (at 20 C) Viscosity / kinematic: not applicable DIN SECTION 10: Stability and reactivity Reactivity Stable with proper care and handling Chemical stability The product is chemically stable when handled and stored under normal conditions.

6 Page 6 of Possibility of hazardous reactions Ignition hazard. Vapours may form explosive mixtures with air Conditions to avoid Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. Keep out of the reach of children. Take precautionary measures against static discharges. See protective measures under point 7 and Incompatible materials Keep away from: Oxidizing agents. Material, rich in oxygen, oxidizing Hazardous decomposition products Can be released in case of fire: Carbon dioxide (CO2). Carbon monoxide. Nitrogen oxides (NOx). Carbon black. Vapours may form explosive mixtures with air. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity No data available CAS No butane Preparation not tested. Chemical name Exposure routes Method Dose Species Source inhalative (4 h) gas LC ppm Rat GESTIS Hydrocarbons, C10-C13, n-alkanes, iso-alkanes, cyclics, < 2% aromatics oral dermal LD50 LD50 > 5000 mg/kg > 5000 mg/kg Rat. Rabbit. Irritation and corrosivity Irritant effect on the eye: mild irritant. Irritant effect on the skin: Prolonged/repetitive skin contact may cause skin defattening or dermatitis. Sensitising effects Evaluation: no danger of sensitization. STOT-single exposure Vapours may cause drowsiness and dizziness. Severe effects after repeated or prolonged exposure Prolonged/repetitive skin contact may cause skin defattening or dermatitis. Carcinogenic/mutagenic/toxic effects for reproduction No data available Specific effects in experiment on an animal following inhalation: drowsiness. Headache. unconsciousness. Further information If handled with proper care and at intended use, the product does not cause any harmful effects acc. to our experiences and available information.

7 Page 7 of 10 SECTION 12: Ecological information Toxicity CAS No No data available Mixture not tested. Chemical name Aquatic toxicity Method Dose [h] [d] Species Source Hydrocarbons, C10-C13, n-alkanes, iso-alkanes, cyclics, < 2% aromatics Acute fish toxicity Acute algae toxicity LC mg/l 96 h Oncorhynchus mykiss ErC mg/l 72 h Pseudokirchneriella subcapitata Persistence and degradability Not easily bio-degradable (according to OECD-criteria). Do not empty into drains or the aquatic environment Bioaccumulative potential No data available Partition coefficient n-octanol/water CAS No Chemical name butane 2, propane 2, Mobility in soil Product is easily volatile. Product is difficult to dissolve in water Results of PBT and vpvb assessment The components in this formulation do not meet the criteria for classification as PBT or vpvb Other adverse effects No data available SECTION 13: Disposal considerations Waste treatment methods Advice on disposal Must not be disposed of with domestic refuse. Do not empty into drains or the aquatic environment. Waste disposal number of waste from residues/unused products WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded chemicals; gases in pressure containers (including halons) containing dangerous substances Classified as hazardous waste. Contaminated packaging Waste disposal according to official state regulations. SECTION 14: Transport information Land transport (ADR/RID) UN number: UN UN proper shipping name: Transport hazard class(es): Packing group: Hazard label: AEROSOLS Log Pow

8 Page 8 of 10 Classification code: 5F Special Provisions: Limited quantity: 1 L Transport category: 2 Tunnel restriction code: D Other applicable information (land transport) Quantities released: E0 Special provisions: Transportation category: 2 Tunnel restriction code: B1D Inland waterways transport (ADN) UN number: UN UN proper shipping name: Transport hazard class(es): Packing group: - Hazard label: 2.1 AEROSOLS Classification code: Special Provisions: Limited quantity: 5F L Other applicable information (inland waterways transport) Quantities released: E0 Special provisions: Marine transport (IMDG) UN number: UN UN proper shipping name: Transport hazard class(es): Packing group: Hazard label: AEROSOLS Special Provisions: Limited quantity: EmS: Other applicable information (marine transport) Quantities released: E0 Special provisions: 63, 190, 277, 327, 959 Air transport (ICAO) UN number: UN UN proper shipping name: Transport hazard class(es): 63, 190, 277, 327, 344, 959 See SP277 F-D, S-U AEROSOLS, flammable 2.1

9 Page 9 of Packing group: Hazard label: Special Provisions: Limited quantity Passenger: IATA-packing instructions - Passenger: IATA-max. quantity - Passenger: IATA-packing instructions - Cargo: IATA-max. quantity - Cargo: Other applicable information (air transport) Passenger LQ: Y203 Quantities released: E0 Danger: Y203 Special provisions: A145 - A Environmental hazards ENVIRONMENTALLY HAZARDOUS: Special precautions for user Warning: Flammable gases. A145 A167 A kg G no kg kg Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture National regulatory information Employment restrictions: Water contaminating class (D): Chemical safety assessment Observe employment restrictions for young people. 1 - slightly water contaminating Chemical safety assessments for substances in this mixture were not carried out. SECTION 16: Other information Full text of R phrases referred to under Sections 2 and 3 12 Extremely flammable. 65 Harmful: may cause lung damage if swallowed. 66 Repeated exposure may cause skin dryness or cracking. Full text of H statements referred to under Sections 2 and 3 H220 Extremely flammable gas. H222 Extremely flammable aerosol. H229 Pressurised container: May burst if heated. H304 May be fatal if swallowed and enters airways. Further Information This preparation is hazardous in the sense of regulation (EC) No 1272/2008 [GHS]. These given data only refer to the named product. If the product is used together with other materials or in manufacturing processes the data might not be applicable any more. The data are based on today's state of our knowledge and experience. They are, however, no guarantee of any specific product properties and do not established any legally valid contructual relationship.

10 Page 10 of 10 The receiver of our product is singulary responsible for adhering to existing laws and regulations. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)