MATERIAL SAFETY DATA SHEET (MSDS)

Transcription

1 MSDS CAS No: MSDS MATERIAL SAFETY DATA SHEET (MSDS) SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture : Product code : Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Uses advised against 1.3. Details of the supplier of the safety data sheet LOBA CHEMIE PVT.LTD. 107 Wode House Road, Jehangir Villa, Colaba Mumbai - INDIA T F info@lobachemie.com Emergency telephone number Emergency number : (9:00am - 6:00 pm) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Annex II of Regulation (EC) No. 453/2010 (REACH Annex II) Flammable liquids, H225 Category 2 Acute toxicity (oral), H302 Category 4 Acute toxicity (dermal), H312 Category 4 Acute toxicity H332 (inhalation:gas) Category 4 Skin corrosion/irritation, H315 Category 2 Serious eye damage/eye H318 irritation, Category 1 Reproductive toxicity, H361d Category 2 Specific target organ H336 toxicity Single exposure, Category 3, Narcosis Specific target organ H /09/2016 1/11

2 toxicity single exposure, Category 1 Specific target organ toxicity Repeated exposure, Category 2 Aspiration hazard, Category 1 H373 H304 Full text of classification categories and H statements : see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) : Danger GHS02 GHS05 GHS07 GHS08 GHS06 : H225 - Highly flammable liquid and vapour H315 - Causes skin irritation H318 - Causes serious eye damage H361d - Suspected of damaging the unborn child H373 - May cause damage to organs through prolonged or repeated exposure : P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P260 - Do not breathe dust/fume/gas/mist/vapours/spray P280 - Wear protective gloves/protective clothing/eye protection/face protection P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER/doctor/ P307 - IF exposed: P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P311 - Call a POISON CENTER/doctor/ 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture 14/09/2016 2/11

3 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Ethanol (CAS No) (EC no) (EC index no) CHLOROFORM (CAS No) (EC no) (EC index no) ACETIC ACID GLACIAL (CAS No) (EC no) (EC index no) Flam. Liq. 3, H226 Skin Corr. 1A, H Acute Tox. 4 (Oral), H302 Acute Tox. 3 (Inhalation), H331 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Carc. 2, H351 Repr. 2, H361d STOT RE 1, H Flam. Liq. 3, H226 Acute Tox. 4 (Inhalation), H332 Skin Corr. 1A, H314 Eye Dam. 1, H318 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Assure fresh air breathing. If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. : Wash with plenty of soap and water. Wash contaminated clothing before reuse. Get medical advice/attention. : Rinse cautiously with water for several minutes. Get medical advice/attention. : Do not induce vomiting. Give nothing or a little water to drink. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray Special hazards arising from the substance or mixture Fire hazard : Flammable liquid and vapour. Explosion hazard : May form flammable/explosive vapour-air mixture Advice for firefighters Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. No naked lights. No smoking. 14/09/2016 3/11

4 For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel For emergency responders Protective equipment : Use personal protective equipment as required Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials Precautions for safe handling Additional hazards when processed Precautions for safe handling : Handle empty containers with care because residual vapours are flammable. : Avoid contact with skin and eyes. Do not breathe vapours. Keep away from sources of ignition - No smoking. Provide local exhaust or general room ventilation Conditions for safe storage, including any incompatibilities Storage conditions 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Keep away from ignition sources. Store in a well-ventilated place. Keep container tightly closed Exposure controls Hand protection Eye protection Skin and body protection Respiratory protection : Protective gloves : Chemical goggles or face shield : Wear suitable protective clothing : Wear respiratory protection SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour Odour Odour threshold ph : Colorless. 14/09/2016 4/11

5 Relative evaporation rate (butylacetate=1) Melting point : -65 C Freezing point Boiling point : C Flash point : 24 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C : 4.12 Relative density Density : 1.03 at 20 C Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : vol % 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Heat. Open flame. Sparks Incompatible materials Oxidizing agent Hazardous decomposition products 14/09/2016 5/11

6 SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Oral: Harmful if swallowed. Dermal: Harmful in contact with skin. Inhalation:gas: Harmful if inhaled. ATE CLP (oral) ATE CLP (dermal) ATE CLP (gases) mg/kg bodyweight mg/kg bodyweight ppmv/4h Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity : Causes skin irritation. : Causes serious eye damage. : Not classified : Not classified : Not classified Reproductive toxicity Specific target organ toxicity (single exposure) : Suspected of damaging the unborn child. : May cause drowsiness or dizziness. Causes damage to organs. Specific target organ toxicity (repeated exposure) : May cause damage to organs through prolonged or repeated exposure. Aspiration hazard : May be fatal if swallowed and enters airways. SECTION 12: Ecological information Toxicity Persistence and degradability Bioaccumulative potential ACETIC ACID GLACIAL ( ) Log Pow 0.17 CHLOROFORM ( ) Log Pow Mobility in soil Results of PBT and vpvb assessment 14/09/2016 6/11

7 12.6. Other adverse effects SECTION 13: Disposal considerations Waste treatment methods SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) : 1992 UN-No. (IMDG) : 1992 UN-No.(IATA) : 1992 UN-No.(ADN) UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport document description (ADR) Transport document description (IMDG) Transport document description (IATA) : FLAMMABLE LIQUID, TOXIC, N.O.S. : FLAMMABLE LIQUID, TOXIC, N.O.S. : FLAMMABLE LIQUID, TOXIC, N.O.S. : UN 1992 FLAMMABLE LIQUID, TOXIC, N.O.S., 3 (6.1), II, (D/E) : UN 1992 FLAMMABLE LIQUID, TOXIC, N.O.S., 3 (6.1), II : UN 1992 FLAMMABLE LIQUID, TOXIC, N.O.S., 3 (6.1) (6.1), II Transport hazard class(es) ADR Transport hazard class(es) (ADR) : 3 (6.1) Danger labels (ADR) : 3, 6.1 : IMDG Transport hazard class(es) (IMDG) : 3 (6.1) Danger labels (IMDG) : 3, 6.1 : IATA Transport hazard class(es) (IATA) : 3 (6.1) Hazard labels (IATA) : 3, /09/2016 7/11

8 : ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : II : II : II : No : No : No supplementary information available Special precautions for user - Overland transport Classification code (ADR) : FT1 Special provision (ADR) : 274 Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Tank special provisions (ADR) Vehicle for tank carriage : 1L : E2 : P001, IBC02 : MP19 : T7 : TP2 : L4BH : TU15 : FL Transport category (ADR) : 2 Special provisions for carriage - Loading, unloading and handling (ADR) Special provisions for carriage - Operation (ADR) : CV13, CV28 : S2, S22 Hazard identification number (Kemler No.) : 336 Orange plates : Tunnel restriction code (ADR) EAC code APP code : D/E : 3WE : A(fl) - Transport by sea Special provision (IMDG) : /09/2016 8/11

9 Limited quantities (IMDG) Excepted quantities (IMDG) Packing instructions (IMDG) IBC packing instructions (IMDG) Tank instructions (IMDG) Tank special provisions (IMDG) EmS-No. (Fire) EmS-No. (Spillage) Stowage category (IMDG) Stowage and handling (IMDG) - Air transport PCA Excepted quantities (IATA) PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) : 1 L : E2 : P001 : IBC02 : T7 : TP2, TP13 : F-E : S-D : B : SW2 : E2 : Y341 : 1L PCA packing instructions (IATA) : 352 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 364 CAO max net quantity (IATA) Special provision (IATA) ERG code (IATA) - Inland waterway transport Not regulated - Rail transport Not regulated : 60L : A3 : 3HP Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no substances with Annex XVII restrictions Contains no REACH candidate substance Contains no REACH Annex XIV substances National regulations Germany VwVwS Annex reference 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Water hazard class (WGK) 3, strongly hazardous to water (Classification according to VwVwS, Annex 4) : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Denmark 14/09/2016 9/11

10 Class for fire hazard Store unit Classification remarks Recommendations Danish Regulation : Class II-1 : 5 liter : R10 <H225;H302+H312+H332;H304;H315;H318;H336;H361d;H370;H373>; Emergency management guidelines for the storage of flammable liquids must be followed : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal Chemical safety assessment SECTION 16: Other information Full text of H- and EUH-phrases: Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3 Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Acute Tox. 4 (Inhalation:gas) Acute toxicity (inhalation:gas) Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Asp. Tox. 1 Aspiration hazard, Category 1 Carc. 2 Carcinogenicity, Category 2 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 2 Flammable liquids, Category 2 Flam. Liq. 3 Flammable liquids, Category 3 Repr. 2 Reproductive toxicity, Category 2 Skin Corr. 1A Skin corrosion/irritation, Category 1A Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT RE 1 Specific target organ toxicity Repeated exposure, Category 1 STOT RE 2 Specific target organ toxicity Repeated exposure, Category 2 STOT SE 1 Specific target organ toxicity single exposure, Category 1 STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Narcosis H225 Highly flammable liquid and vapour H226 Flammable liquid and vapour H302 Harmful if swallowed H304 May be fatal if swallowed and enters airways H312 Harmful in contact with skin H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H319 Causes serious eye irritation H331 Toxic if inhaled H332 Harmful if inhaled H336 May cause drowsiness or dizziness H351 Suspected of causing cancer H361d Suspected of damaging the unborn child 14/09/ /11

11 H370 H372 H373 Causes damage to organs Causes damage to organs through prolonged or repeated exposure May cause damage to organs through prolonged or repeated exposure This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 14/09/ /11