Safety Data Sheet according to (EC) No 1907/2006

Transcription

1 Safety Data Sheet according to (EC) No 1907/2006 Loctite Frekote CS-125 5ltr Page 1 of 10 sds no. : Revision: printing date: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Loctite Frekote CS-125 5ltr 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Release agent 1.3. Details of the supplier of the safety data sheet Henkel Limited 2 Bishop Square Business Park AL109EY Herfordshire Hatfield Great Britain Phone: Fax-no.: ua-productsafety.uk@uk.henkel.com 1.4. Emergency telephone number 24 Hours Emergency Tel: +44 (0) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (DPD): F - Highly flammable R11 Highly flammable. Xn - Harmful R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness Label elements

2 Loctite Frekote CS-125 5ltr Page 2 of 10 Label elements (DPD): F - Highly flammable Xn - Harmful Risk phrases: R11 Highly flammable. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. Safety phrases: S16 Keep away from sources of ignition - No smoking. S36 Wear suitable protective clothing. S51 Use only in well-ventilated areas. S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Contains: Naphtha, light alkylate <0.1% benzene 2.3. Other hazards None if used properly. SECTION 3: Composition/information on ingredients Declaration of the ingredients according to CLP (EC) No 1272/2008: Naphtha, light alkylate <0.1% benzene EC Number REACH-Reg No. content Classification > 30- < 50 % Flammable liquids 3 H226 Specific target organ toxicity - single exposure 3 H > 30- < 50 % Flammable liquids 2 H225 Aspiration hazard 1 H > 1- < 5 % Flammable liquids 3 H226 Acute toxicity 4; Inhalation H332 Flammable liquids 3 H226 Acute toxicity 4; Inhalation H332 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available.

3 Loctite Frekote CS-125 5ltr Page 3 of 10 Declaration of ingredients according to DPD (EC) No 1999/45: Naphtha, light alkylate <0.1% benzene EC Number REACH-Reg No. content Classification > 30 - < 50 % R10 R66 R > 30 - < 50 % F - Highly flammable; R11 Xn - Harmful; R > 1 - < 5 % Xn - Harmful; R10, R20 For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available Description of first aid measures SECTION 4: First aid measures Inhalation: Move to fresh air. If symptoms persist, seek medical advice. Skin contact: Immediately wash skin thoroughly with soap and water. Obtain medical attention if irritation persists. Eye contact: Rinse immediately with plenty of running water (for 10 minutes). Seek medical attention if necessary. Ingestion: Rinse out mouth, drink 1-2 glasses of water, do not induce vomiting. Seek medical advice Most important symptoms and effects, both acute and delayed ASPIRATION: Coughing, shortness of breath, nausea. Delayed effect: bronchopneumonia or pulmonary oedema Vapors may cause drowsiness and dizziness. Repeated exposure may cause skin dryness or cracking Indication of any immediate medical attention and special treatment needed Small amounts of liquid aspirated into the respiratory system during ingestion or from vomiting may cause bronchopneumonia or pulmonary oedema. Do not induce vomiting. Seek medical attention from a specialist Extinguishing media Suitable extinguishing media: Carbon dioxide, foam, powder Fine water spray SECTION 5: Firefighting measures Extinguishing media which must not be used for safety reasons: High pressure waterjet 5.2. Special hazards arising from the substance or mixture Can form explosive gas/air mixtures. See section Advice for firefighters Fire fighters should wear positive pressure self-contained breathing apparatus (SCBA). Wear protective equipment.

4 Loctite Frekote CS-125 5ltr Page 4 of 10 Additional information: In case of fire, keep containers cool with water spray. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Keep away from sources of ignition. Ensure adequate ventilation. Wear protective equipment. See advice in chapter Environmental precautions Do not empty into drains / surface water / ground water. Collect contaminated washing water for appropriate disposal Methods and material for containment and cleaning up Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment during cleanup. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Dispose of contaminated material as waste according to Chapter 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Use only in well-ventilated areas. Keep away from sources of ignition - no smoking. Wear suitable protective clothing, safety glasses and gloves. Take measures to prevent the build-up of electrostatic charges. Do not store or use near heat, spark, open flame or other sources of ignition. Hygiene measures: Good industrial hygiene practices should be observed. Ensure adequate ventilation/vacuum off Conditions for safe storage, including any incompatibilities Store in sealed original container. Store in a cool, well-ventilated place. Do not store or use near heat, spark, open flame or other sources of ignition. Take precautionary measures against static discharges during storage and transport. Do not store together with substances which intensify fire. Do not store together with oxidants Specific end use(s) Release agent SECTION 8: Exposure controls/personal protection 8.1. Control parameters Valid for Great Britain Ingredient ppm mg/m 3 Type Category Remarks BUTYL ACETATE Time Weighted Average EH40 WEL (TWA): BUTYL ACETATE Short Term Exposure Limit (STEL): EH40 WEL 8.2. Exposure controls: Engineering controls: Ventilate working rooms thoroughly. Avoid naked flames, sparking and sources of ignition. Switch off electrical devices. Do not smoke, do not weld. Do not empty waste into waste water drains.

5 Loctite Frekote CS-125 5ltr Page 5 of 10 Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment. Use filter A-P2 if vapours/aerosols occur which may be inhaled. Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing. Skin protection: Wear suitable protective clothing. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance liquid Clear, light yellow Odor hydrocarbons ph Initial boiling point (1.013 hpa) Flash point Decomposition temperature Vapour pressure Density (20,0 C (68 F)) Bulk density Viscosity Viscosity (kinematic) Explosive properties Solubility (qualitative) (20 C (68 F); Solvent: Water) Solubility (qualitative) (20 C (68 F); Solvent: other organic solvents) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits lower upper Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties > 112 C (> F) 6 C (42.8 F); Tagliabue closed cup 0,7250 g/cm3 Slight Soluble 0,6 %(V) 7 %(V) The product is not explosive. The formation of explosive vapor/air mixtures is possible Other information

6 Loctite Frekote CS-125 5ltr Page 6 of 10 SECTION 10: Stability and reactivity Reactivity Reacts with strong oxidants. Reaction with water Possibility of hazardous reactions See section reactivity No decomposition if used according to specifications Conditions to avoid Vapours may form explosive mixture with air. Spray mist may be flammable at temperatures below the flash point. Heat, flames, sparks and other sources of ignition Incompatible materials None if used properly Hazardous decomposition products Irritating organic vapours. At higher temperature carbon oxides and nitrogen oxides may be generated. See section Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Narcotic effects at higher concentrations. Oral toxicity: Health hazard: may damage lungs if swallowed. Small amounts of liquid aspirated into the respiratory system during ingestion or from vomiting may cause bronchopneumonia or pulmonary oedema. Accidental ingestion and vomiting can lead to aspiration into the lungs, which can result in chemical pneumonitis. Inhalative toxicity: May cause irritation to respiratory system. Vapors may cause drowsiness and dizziness. Skin irritation: Repeated exposure may cause skin dryness or cracking. Eye irritation: Prolonged or repeated contact may cause eye irritation. Acute toxicity: Naphtha, light alkylate <0.1% benzene Value type LD50 LC50 LD50 LC50 LD50 Value > mg/kg > 23,4 mg/l > mg/kg > 5,04 mg/l > mg/kg Route of application oral inhalation oral inhalation dermal Exposure time 4 h 4 h Species rat rat rat rat rabbit Method OECD Guideline 403 (Acute Inhalation Toxicity) Skin corrosion/irritation: Naphtha, light alkylate <0.1% benzene not irritating Result Exposure time Species rabbit moderately irritating 24 h rabbit Method

7 Loctite Frekote CS-125 5ltr Page 7 of 10 Serious eye damage/irritation: Naphtha, light alkylate <0.1% benzene not irritating not irritating Result Exposure time Species rabbit rabbit Method Respiratory or skin sensitization: Naphtha, light alkylate <0.1% benzene not sensitising not sensitising Result Test type Species Method Guinea pig maximisat ion test Buehler test guinea pig guinea pig Germ cell mutagenicity: Naphtha, light alkylate <0.1% benzene Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g Ames test) negative mammalian cell gene mutation assay Metabolic activation / Exposure time with and without with and without Species Method SECTION 12: Ecological information General ecological information: The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Ecotoxicity: Do not empty into drains / surface water / ground water. Mobility: Cured adhesives are immobile. Persistence and Biodegradability: No data available for the product. Bioaccumulative potential: No data available.

8 Loctite Frekote CS-125 5ltr Page 8 of Toxicity Naphtha, light alkylate <0.1% benzene Naphtha, light alkylate <0.1% benzene Naphtha, light alkylate <0.1% benzene Value type Value Acute Toxicity Study Exposure time Species LC50 62 mg/l Fish 96 h Leuciscus idus EC50 72,8 mg/l Daphnia 24 h Daphnia magna EC50 674,7 mg/l Algae 72 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) Method OECD Guideline 201 (Alga, Growth Inhibition Test) NOEC 2,6 mg/l Fish 14 d Pimephales promelas OECD Guideline 204 (Fish, Prolonged Toxicity Test: 14-day Study) LC50 8,2 mg/l Fish 96 h Pimephales promelas OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 32 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 45 mg/l Algae 96 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) LC50 > 746 mg/l Fish 96 h Brachydanio rerio (new name: Danio rerio) OECD Guideline 201 (Alga, Growth Inhibition Test) OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 > 816 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 > 913 mg/l Algae 72 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) OECD Guideline 201 (Alga, Growth Inhibition Test) Persistence and degradability Result Route of application Degradability Method readily biodegradable aerobic 98 % OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test) aerobic 54 % OECD Guideline 301 A (new version) (Ready Biodegradability: DOC Die Away Test) Bioaccumulative potential / Mobility in soil Naphtha, light alkylate <0.1% benzene LogKow Bioconcentration factor (BCF) Exposure time Species Temperature Method 1,81 23 C OECD Guideline 107 (Partition Coefficient (noctanol / water), Shake Flask Method) 3,11-25 C 4,54 SECTION 13: Disposal considerations Waste treatment methods

9 Loctite Frekote CS-125 5ltr Page 9 of 10 Product disposal: Dispose of in accordance with local and national regulations. Disposal of uncleaned packages: Disposal must be made according to official regulations. Use packages for recycling only when totally empty. Packaging that cannot be cleaned are to be disposed of in the same manner as the product. Waste code The valid EWC waste code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We will be happy to advise you. Road transport ADR: SECTION 14: Transport information Class: 3 Packaging group: II Classification code: F1 Hazard ident. number: 33 UN no.: 1993 Label: 3 Technical name: FLAMMABLE LIQUID, N.O.S. (n-butylacetate,naphtha) Tunnelcode: (D/E) Additional information: Special provision 640D Railroad transport RID: Class: 3 Packaging group: II Classification code: F1 Hazard ident. number: 33 UN no.: 1993 Label: 3 Technical name: FLAMMABLE LIQUID, N.O.S. (n-butylacetate,naphtha) Tunnelcode: Additional information: Special provision 640D Inland water transport ADN: Class: 3 Packaging group: II Classification code: F1 Hazard ident. number: UN no.: 1993 Label: 3 Technical name: FLAMMABLE LIQUID, N.O.S. (n-butylacetate,naphtha) Additional information: Special provision 640D Marine transport IMDG: Class: 3 Packaging group: II UN no.: 1993 Label: 3 EmS: F-E,S-E Seawater pollutant: - Proper shipping name: FLAMMABLE LIQUID, N.O.S. (n-butylacetate,naphtha)

10 Loctite Frekote CS-125 5ltr Page 10 of 10 Air transport IATA: Class: 3 Packaging group: II Packaging instructions (passenger) 353 Packaging instructions (cargo) 364 UN no.: 1993 Label: 3 Proper shipping name: Flammable liquid, n.o.s. (n-butylacetate,naphtha) SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content 79,00 % SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. This safety data sheet was prepared in accordance with Council Directive 67/548/EEC and it's subsequent amendments, and Commission Directive 1999/45/EC.