Road Marking Paint [yellow,oil based]

Transcription

1 Page 1 of 7 MATERIAL SAFETY DATA SHEET Road Marking Paint [yellow,oil based] Section 01 - Product And Company Information Product Identifier... Yellow marking paint Product Use...Traffic lines on roads, paved surfaces for outside use. Supplier Name.. ClearTech Industries Inc Quebec Avenue Saskatoon, SK. Canada S7K 1V7 Prepared By ClearTech Industries Inc. Technical Department Phone: Hour Emergency Phone Section 02 - Composition / Information on Ingredients Ingredients Toluene VM & P Naphtha Lead Chromate 15-25% 5-15% 5-15% CAS Number Toluene VM & P Naphtha Lead Chromate Synonym (s)......not available Section 03 - Hazard Identification Inhalation Irritating to eyes, nose, throat and lungs. May cause headaches, dizziness, effects of drunkenness or other central nervous system effects.

2 Page 2 of 7 Skin Contact / Absorption.... Frequest or prolonged contact may irritate skin and cause dermatitis. Eye Contact Irritating to eyes, can cause injury if abrasive pigments are rubbed into the eyes. Ingestion.... May cause severe health effects (bronchial pneumonia or pulmonary edema) if swallowed and gets into lungs. Exposure Limits.. ACGIH-TLV/TWA: 100ppm (toluene) ACGIH-TLV/TWA: 300ppm (VM & P Naphtha) ACGIH-TLV/TWA: 0.05mg/m 3 (Lead Chromate) Section 04 - First Aid Measures Inhalation..... Remove victim to fresh air. Give artificial respiration only if breathing has stopped. If breathing is difficult, give oxygen. Seek immediate medical attention. Skin Contact / Absorption.. Remove contaminated clothing. cleaner. Wash affected area with an industrial Eye Contact Check for and remove any contact lenses. Flush immediately with water for at least 20 minutes. Forcibly hold eyelids apart to ensure complete irrigation of eye tissue. Seek immediate medical attention. Ingestion.... Do not induce vomitting if swallowed. Get prompt medical attention. Additional Information Not available Section 05 - Fire Fighting Measures Conditions of Flammability... Flammable liquid will ignite when exposed to flame or spark. Product could flash if spilled over hot engins or hot exhaust pipes. Means of Extinction Use water spray to cool fire-exposed surfaces, and on spills. Fire can be left to burn out or extinguished with foam or dry chemical. Flash Point.... <-10 o C Auto-ignition Temperature. 260 o C Upper Flammable Limit.. Not available

3 Page 3 of 7 Lower Flammable Limit % Hazardous Combustible Products... Carbon monoxide, oxides of lead and chromium Special Fire Fighting Procedures... Wear NIOSH-approved self-contained breathing apparatus and protective clothing. Explosion Hazards... Closed containers may explode if exposed to very high temperatures. Section 06 - Accidental Release Measures Leak / Spill Wear appropriate personal protective equipment. Ventilate area. Stop or reduce leak if safe to do so. Prevent material from entering sewers. Do not use combustible material to absorb product. Deactivating Materials Not available Section 07 - Handling and Storage Handling Procedures..... Use proper equipment for lifting and transporting all containers. Use sensible industrial hygiene and housekeeping practices. Use non-sparking ground straps when pouring. Wash thoroughly after handling. Avoid all situations that could lead to harmful exposure. Storage Requirements Keep containers covered when not in use. Store containers in a cool, well-ventilated area. Keep away open flames, sparks or heat. Do not allow product to freeze. Protective Equipment Section 08 - Personal Protection and Exposure Controls Eyes..... Chemical goggles, full-face shield, or a full-face respirator is to be worn at all times when product is handled. Contact lenses should not be worn; they may contribute to severe eye injury. Respiratory... If engineering controls and work practices are not effective in controlling exposure to this material, then wear suitable personal protective equipment including approved respiratory protection. Gloves... Impervious gloves of chemically resistant material (rubber or PVC) should be worn at all times. Wash contaminated clothing and dry thoroughly before reuse.

4 Page 4 of 7 Clothing..... Body suits, aprons, and/or coveralls of chemical resistant material should be worn at all times. Wash contaminated clothing and dry thoroughly before reuse. Footwear... No special footwear is required other than what is mandated at place of work. Engineering Controls Ventilation Requirements... Mechanical ventilation (dilution or local exhaust), process or personnel enclosure and control of process conditions should be provided. Supply sufficient replacement air to make up for air removed by exhaust systems. Other... Not available Section 09 - Physical and Chemical Properties Physical State Liquid Odor and Appearance..... Petroleum like odor, viscous liquid Odor Threshold Not available Specific Gravity (Water=1) Vapor Pressure (mm Hg, 20C)... > 150mm Hg at 38 o C Vapor Density (Air=1)..... > 1 Evaporation Rate > 3 Boiling Point o C Freeze/Melting Point Not available, will gradually thicken when it cools. ph Not available Water/Oil Distribution Coefficient... Not available Bulk Density Not available VOC Content..... Not available Solubility in Water Not available Molecular Formula Not available

5 Page 5 of 7 Molecular Weight Not available Section 10 - Stability and Reactivity Stability Considered stable, avoid oxidizing agents and fire. Incompatibility Strong oxidizers Hazardous Products of Decomposition.. Carbon monoxide Polymerization Not available Section 11 - Toxicological Information Irritancy Moderately irritating Sensitization Not available Chronic/Acute Effects..... May cause effects of chronic lead toxicity upon repeated ingestion. Prolonged and repeated exposure of male rats to inhalation of light hydrocarbon vapors produced kidney disorders and/or damage. These effects were not observed in similar studies with female rats and male or female mice and in limited studies with other animal species and are believed to be unique to the male rat. A number of human studies have not shown clinical evidence of an association between light hydrocarbon exposure and disease. It is highly unlikely that the kidney effects observed in male rats have significant implications for humans exposed at or below the occupational exposure limits. Synergistic Materials Not available Animal Toxicity Data LD 50(Rabbit, Dermal): 14g/kg (toluene) LC 50(Rat, Inhalation): 8000ppm/4hrs (toluene) LD 50(Rat, Oral): > 2000mg/kg (lead chromate) Carcinogenicity Chromium and certain chromium compounds are classified by I.A.R.C and N.T.P. as known carcinogens but it is stipulated that rat bronchial implant studies have shown that only calcium, strontium and zinc chromate produced significant increases in the numbers of bronchial carcinomas while no such in creases were seen with seven different samples of lead chromate pigments. Reproductive Toxicity Not available Teratogenicity Not available

6 Page 6 of 7 Mutagenicity Not available Fish Toxicity..... Not available Biodegradability Not available Environmental Effects. Not available Section 12 - Ecological Information Section 13 - Disposal Consideration Waste Disposal Dispose in accordance with all federal, provincial, and/or local regulations including the Canadian Environmental Protection Act. TDG Classification Class Group II PIN Number UN 1263 Section 14 - Transport Information Other... Secure containers (full and/or empty) with suitable hold down devises during shipment and ensure all caps, valves, or closures are secured in the closed position. PRODUCT CLASSIFICATION: This product has been classified on the preparation date specified at section 16 of this MSDS / SDS, for transportation in accordance with the requirements of part 2 of the Transportation of Dangerous Goods Regulations. If applicable, testing and/or published test data regarding the classification of this product are listed in the references at section 16 of this MSDS / SDS. WHMIS Classification......B, D2 Section 15 - Regulatory Information NOTE: THE PRODUCT LISTED ON THIS MSDS HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CANADIAN CONTROLLED PRODUCTS REGULATIONS. THIS MSDS CONTAINS ALL INFORMATION REQUIRED BY THOSE REGULATIONS. Section 16 - Other Information

7 Page 7 of 7 Version #... One Preparation Date March 22, 2011 Revision Date May 30, 2014 Revision Note Updated ClearTech Information. Note: The responsibility to provide a safe workplace remains with the user. The user should consider the health hazards and safety information contained herein as a guide and should take those precautions required in an individual operation to instruct employees and develop work practice procedures for a safe work environment. The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by the use of this material. It is the responsibility of the user to comply with all applicable laws and regulations. Attention: Receiver of the chemical goods / MSDS coordinator As part of our commitment to the Canadian Association of Chemical Distributors (CACD) Responsible Distribution initiative, ClearTech Industries Inc. and its associated companies require, as a condition of sale, that you forward the attached Material Safety Data Sheet(s) to all affected employees, customers, and end-users. ClearTech will send any available supplementary handling, health, and safety information to you at your request. If you have any questions or concerns please call our customer service or technical service department. ClearTech Industries Inc. - Locations Corporate Head Office: 1500 Quebec Avenue, Saskatoon, SK, S7K 1V7 Phone: Fax: Location Address Postal Code Phone Number Fax Number Richmond, B.C Horseshoe Way V7A 4X Port Coquitlam 2023 Kingsway Avenue V3C 1S Calgary, AB. 5516E - 40 th St. S.E. T2C 2A Edmonton, AB nd Street T5L 2G Saskatoon, SK. North Corman Industrial Park S7K 1V Regina, SK. 555 Henderson Drive S42 5X Winnipeg, MB. 340 Saulteaux Crescent R3J 3T Mississauga, ON Bath Road L4T 1L Hour Emergency Number - All Locations