Ammonia/Morpholine Blend

Transcription

1 Page 1 of 8 MATERIAL SAFETY DATA SHEET Ammonia/Morpholine Blend Section 01 - Chemical And Product And Company Information Product Identifier... Ammonia/Morpholine Blend Product Use. Manufacture of rayon, rubber, fertilizers; refrigeration; photography; pharmaceuticals; lubricants; various industrial processes. Supplier Name.. ClearTech Industries Inc Quebec Avenue Saskatoon, SK. Canada S7K 1V7 Prepared By ClearTech Industries Inc. Technical Department Phone: 1 (800) Hour Emergency Phone... 1 (800) Section 02 - Composition / Information on Ingredients Hazardous Ingredients Ammonium Hydroxide Morpholine CAS Number Ammonium Hydroxide Morpholine 53.5%% 3-7% Synonym (s) Not Available

2 Page 2 of 8 Section 03 - Hazard Identification Inhalation Inhalation of vapours may cause severe irritation of the nose, throat and respiratory tract. May be fatal if inhaled. Skin Contact/Absorption.... Contact with skin can cause severe burns, blisters, ulcers, and permanent scarring depeding on the concentratoin of the solution and the duration of contact. Eye Contact Contact with eyes dependent on concentration and duration of contact may lead to corneal scarring and clouding. Glaucoma, cataracts and permanent blindness may also occur. Ingestion Ingesting product may cause severe burning and pain in the mouth, throat and abdomen. Vomiting, diarrhea and perforation of the esophagus and stomach lining may occur. May be fatal if swallowed. Exposure Limits... ACGIH/TLV-STEL: 35ppm (Ammonium hydroxide) ACGIH/TLV: 20ppm (Morpholine) Section 04 - First Aid Measures Inhalation..... Remove victim to fresh air. Give artificial respiration only if breathing has stopped. If breathing is difficult, give oxygen. Seek immediate medical attention. Skin Contact / Absorption.. Remove contaminated clothing. Wash affected area with soap and water for at least 30 minutes and do not interrupt flushing. Seek medical attention if irritation occurs or persists. Eye Contact Flush immediately with water for at least 20 minutes. Forcibly hold eyelids apart to ensure complete irrigation of eye tissue. Seek immediate medical attention Ingestion.... Do not induce vomiting, unless only on the direct advice of a poison control centre. If conscious, drink 1-2 glasses of milk or water. Never give anything by mouth to an unconscious person. Seek immediate medical attention. Additional Information Not Available

3 Page 3 of 8 Conditions of Flammability... Non-flammable Section 05 - Fire Fighting Means of Extinction Use extinguishing media appropriate to the surrounding fire conditions such as water fog, CO 2 or dry chemical. Flash Point..... Not Applicable Auto-ignition Temperature. Not Applicable Upper Flammable Limit.. Not Applicable Lower Flammable Limit Not Applicable Hazardous Combustible Products... Carbon monoxide, carbon dioxide, and ammonia. Special Fire Fighting Procedures... Wear NIOSH-approved self-contained breathing apparatus and protective clothing. Use fog to drift over liquid while flushing. Explosion Hazards... Not Applicable Section 06 - Accidental Release Measures Leak / Spill Wear appropriate personal protective equipment. Ventilate area. Stop or reduce leak if safe to do so. Prevent material from entering sewers. Isolate hazard area and restrict access. Deactivating Materials Not Available Small spills: Stop or reduce leak if safe to do so. Ventilate the area. Contain and soak up spill with absorbent that does not react with spilled product. Flush area with water. Place used absorbent into suitable, covered, labeled containers for disposal. Contaminated absorbent poses the same hazard as the spilled product. Large spills: Contact supplier, local fire and emergency services for help. Dike spilled product to prevent runoff. Cover the spill surface with the appropriate type of foam to reduce the release of vapour/ammonia gas. Ventilate the area to prevent the gas from accumulating, especially in confined spaces. Knock down gas with fog or fine water spray.remove or recover liquid using pumps or vacuum equipment. Flush spill area. Dike and recover contaminated water for appropriate disposal. Store recovered product in suitable containers that are: tightly-covered, corrosionresistant.

4 Page 4 of 8 Section 07 - Handling and Storage Handling Procedures Use proper equipment for lifting and transporting all containers. Use sensible industrial hygiene and housekeeping practices. Wash thoroughly after handling. Avoid all situations that could lead to harmful exposure. Storage Requirements Store in cool, dry, well ventilated area away from incompatibles. Keep out of direct sunlight and away from direct heat sources. Protective Equipment Section 08 - Personal Protection and Exposure Controls Eyes..... Chemical goggles, full-face shield, or a full-face respirator is to be worn at all times when product is handled. Contact lenses should not be worn; they may contribute to severe eye injury. Respiratory... If exposure exceeds occupational exposure limits, use an appropriate NIOSH approved respirator. Gloves... Impervious gloves of chemically resistant material should be worn at all times. Wash contaminated clothing and dry thoroughly before reuse. Clothing..... Body suits, aprons, and/or coveralls of chemical resistant material should be worn at all times. Wash contaminated clothing and dry thoroughly before reuse. Footwear... Impervious boots of chemically resistant material should be worn at all times. Engineering Controls Ventilation Requirements... Mechanical ventilation (dilution or local exhaust), process or personnel enclosure and control of process conditions should be provided. Supply sufficient replacement air to make up for air removed by exhaust systems. Use in a well ventilated area. Other... Emergency shower and eyewash should be in close proximity.

5 Page 5 of 8 Physical State Liquid Section 09 - Physical and Chemical Properties Odor and Appearance..... Clear, colourless liquid with a highly irritating odour Odor Threshold Not Available Specific Gravity (Water=1) Vapor Pressure (mm Hg, 20C)... Not Available Vapor Density (Air=1)..... Not Available Evaporation Rate Not Available Boiling Point Not Available Freeze/Melting Point Not Available ph Strong base Water/Oil Distribution Coefficient... Not Available Bulk Density Not Available % Volatiles by Volume.... Not Available Solubility in Water Completely miscible Molecular Formula Not Available Molecular Weight Not Available Section 10 - Stability and Reactivity Stability Normally stable. Ammonia gas may be given off under normal conditions. Incompatibility Oxidizers, acids, calcium hypochlorite, sodium hypochlorite, gold, mercury, silver. Hazardous Products of Decomposition.. Ammonia, nitrogen oxides Polymerization Not Available

6 Page 6 of 8 Section 11 - Toxicological Information Irritancy Severe irritant, corrosive to eyes and skin. Sensitization Not Available Chronic/Acute Effects..... Repeated or prolonged inhalation may cause running nose, bronchopneumonia, pulmonary oedema and reduction of pulmonary function. Can cause injury to entire respiratory tract. Severe exposure may cause lung damage. Prolonged contact may cause severe burns or dermatitus. Toxic effects on skin may be delayed. Synergistic Materials Not Available Animal Toxicity Data LD 50(oral, rat): 350mg/kg (Ammonium hydroxide) LC 50(rat 4 hour exposure): 3670 ppm (Ammonium hydroxide) LD 50(oral, rat): 1050 mg/kg (Morpholine) LC 50(female rat 4 hour exposure): 2150 ppm (Morpholine) Carcinogenicity No known significant effects as per IARC and ACGIH. Reproductive Toxicity Not Available Teratogenicity Not Available Mutagenicity Not Available Fish Toxicity Not Available Biodegradability Not Available Environmental Effects. Not Available Section 12 - Ecological Information Section 13 - Disposal Consideration Waste Disposal Dispose in accordance with all federal, provincial, and/or local regulations including the Canadian Environmental Protection Act..

7 Page 7 of 8 Section 14 - Transportation Information TDG Classification Class Group II PIN Number UN 1760 Other... Secure containers (full and/or empty) with suitable hold down devises during shipment. WHMIS Classification......D1, E Section 15 - Regulatory Information NOTE: THE PRODUCT LISTED ON THIS MSDS HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CANADIAN CONTROLLED PRODUCTS REGULATIONS. THIS MSDS CONTAINS ALL INFORMATION REQUIRED BY THOSE REGULATIONS. Section 16 - Other Information Preparation Date October 8, 2010 Revision Date... January 6, 2014 March 18, 2014 Note: The responsibility to provide a safe workplace remains with the user. The user should consider the health hazards and safety information contained herein as a guide and should take those precautions required in an individual operation to instruct employees and develop work practice procedures for a safe work environment. The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by the use of this material. It is the responsibility of the user to comply with all applicable laws and regulations. Attention: Receiver of the chemical goods / MSDS coordinator As part of our commitment to the Canadian Association of Chemical Distributors (CACD) Responsible Distribution initiative, ClearTech Industries Inc. and its associated companies require, as a condition of sale, that you forward the attached Material Safety Data Sheet(s) to all affected employees, customers, and end-users. ClearTech will send any available supplementary handling, health, and safety information to you at your request. If you have any questions or concerns please call our customer service or technical service department.

8 Page 8 of 8 ClearTech Industries Inc. - Locations Corporate Head Office: 1500 Quebec Avenue, Saskatoon, SK, S7K 1V7 Phone: 1 (800) Fax: 1 (888) Location Address Postal Code Phone Number Fax Number Richmond, B.C Horseshoe Way V7A 4X6 1 (800) (888) Port Coquitlam, 2023 Kingsway Ave V3C 1S9 1 (800) (888) B.C Calgary, AB. 5516E - 40 th St. S.E. T2C 2A1 1 (800) (888) Edmonton, AB th Street T5S 1N7 1 (800) (888) Saskatoon, SK Quebec Ave S7K 1V7 1 (800) (888) Regina, SK. 555 Henderson Drive S42 5X2 1 (800) (888) Winnipeg, MB. 340 Saulteaux Crescent R3J 3T2 1 (800) (888) Mississauga, ON Bath Road L4T 1L2 1 (800) (888) Hour Emergency Number - All Locations - 1 (800)