MATERIAL SAFETY DATA SHEET. Tabex Shock 'n Swim. Section 01 - Product And Company Information. Section 02 - Composition / Information on Ingredients
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1 Page 1 of 7 MATERIAL SAFETY DATA SHEET Tabex Shock 'n Swim Section 01 - Product And Company Information Product Identifier... Shock 'n Swim Product Use... Non-chlorine shock treatment for swim pool water. Supplier Name... ClearTech Industries Inc Quebec Avenue Saskatoon, SK. Canada S7K 1V7 Prepared By ClearTech Industries Inc. Technical Department Phone: (306) Preparation Date June 21, Hour Emergency Phone Section 02 - Composition / Information on Ingredients Ingredients Peroxymonosulphuric Acid, monopotassium salt Potassium Bisulphate Potassium Persulphate Sodium Carbonate 15-40% 10-30% 1-5% 10-30% CAS Number Peroxymonosulphuric Acid, monopotassium salt Potassium Bisulphate Potassium Persulphate Sodium Carbonate Synonym (s)......none Section 03 - Hazard Identification
2 Page 2 of 7 Inhalation May be harmful if inhaled. May cause irritation to the nose, throat and respiratory tract. Symptoms may include burning sensation, sore throat, runny nose, coughing, wheezing, shortness of breath and difficulty breathing. Skin Contact / Absorption.... Moderate irritation may occur as a result of contact with skin. Eye Contact Moderate eye irritation may occur. Symptoms may include stinging, redness, tearing and pain. Ingestion..... May be harmful if ingested. Symptoms may include irritation to mouth, throat and stomach. Other symptoms may include drowsiness, dizziness, nausea, headache and other central nervous system effects. Exposure Limits... ACGIH-TLV/TWA: 0.1mg/m 3 (potassium persulphate) Section 04 - First Aid Measures Inhalation Remove victim to fresh air. Give artificial respiration only if breathing has stopped. If breathing is difficult, give oxygen. Seek medical attention if difficulties persist. Skin Contact / Absorption... Remove contaminated clothing. Wash affected area with soap and water. Seek medical attention if irritation occurs or persists. Eye Contact Check for and remove any contact lenses. Flush immediately with water for at least 20 minutes. Forcibly hold eyelids apart to ensure complete irrigation of eye tissue. Seek immediate medical attention. Ingestion..... Never give anything by mouth if victim is rapidly losing consciousness, or is unconscious or convulsing. Rinse mouth thoroughly with water. Do not induce vomiting. Have victim drink two glasses of water. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Repeat administration of water. Seek immediate medical attention. Additional Information Section 05 - Fire Fighting Measures Conditions of Flammability... Product will not burn under normal conditions. Likely not sensitive to static discharge or mechanical impact. Product may increase buring rate of surrounding combustible materials.
3 Page 3 of 7 Means of Extinction Carbon dioxide, dry chemical powder and appropriate foam for surrounding products. Flash Point Auto-ignition Temperature.. Upper Flammable Limit... Lower Flammable Limit Hazardous Combustible Products... Carbon oxides and other irritating fumes. Special Fire Fighting Procedures... Wear NIOSH-approved self-contained breathing apparatus and protective clothing. Water spray may be useful to cool containers exposed to flames. Explosion Hazards... Shield personnel to protect from venting, rupturing or bursting containers. Section 06 - Accidental Release Measures Leak / Spill Wear appropriate personal protective equipment if required. Ventilate area. Contain and absorb any spilled liquid concentrate with inert absorbent material, then place material into a container for later disposal. Contaminated absorbent material may pose the same hazards as the spilled product. Deactivating Materials Section 07 - Handling and Storage Handling Procedures Use proper equipment for lifting and transporting all containers. Use sensible industrial hygiene and housekeeping practices. Wash thoroughly after handling. Avoid all situations that could lead to harmful exposure. Storage Requirements Store product in a cool, dry and well ventilated place away from direct sunlight, heat and ignition sources. Store away from incompatible materials such as strong bases, strong acids, oxidizers and some metals.
4 Page 4 of 7 Protective Equipment Eyes..... Respiratory... Gloves... Section 08 - Personal Protection and Exposure Controls Chemical goggles, full-face shield, or a full-face respirator is to be worn at all times when product is handled. Contact lenses should not be worn; they may contribute to severe eye injury. Respiratory protection is required if the concentrations are higher than the exposure limits. Use a NIOSH approved respirators if the exposure limits are unknown. Impervious gloves of chemically resistant material should be worn at all times. Wash contaminated clothing and dry thoroughly before reuse. Clothing..... Footwear... Body suits, aprons, and/or coveralls of chemical resistant material should be worn at all times. Wash contaminated clothing and dry thoroughly before reuse. Impervious boots of chemically resistant material should be worn. Engineering Controls Ventilation Requirements... Mechanical ventilation (dilution or local exhaust), process or personnel enclosure and control of process conditions should be provided. Supply sufficient replacement air to make up for air removed by exhaust systems. Other... Keep an eye wash fountain and safety shower available and in close proximity to work area. Section 09 - Physical and Chemical Properties Physical State Powder Odor and Appearance..... Odorless, white powder Odor Threshold Specific Gravity (Water=1)... Not applicable Vapor Pressure (mm Hg, 20 o C)... Vapor Density (Air=1)..... Evaporation Rate Boiling Point Not applicable
5 Page 5 of 7 Freeze/Melting Point ph (1% solution) Water/Oil Distribution Coefficient... Bulk Density % Volatiles by Volume..... Solubility in Water Product is soluble Molecular Formula Molecular Weight Section 10 - Stability and Reactivity Stability Stable under normal storage and handling conditions. Incompatibility Strong bases, strong acids, oxidizers, some metals. Hazardous Products of Decomposition... Carbon oxides and other irritating fumes. Polymerization Will not occur Section 11 - Toxicological Information Irritancy Moderate irritant to skin and eyes. Ingestion and inhalation may cause severe irritation. Sensitization Possible skin and respiratory tract allergies may occur. Chronic/Acute Effects No other effects noted other than what is listed in Section 3. Synergistic Materials Animal Toxicity Data LD 50(oral, rat): 2340mg/kg (potassium bisulphate) LD 50(oral, rat): 802mg/kg (potassium persulphate) LD 50(oral, rat): 4090mg/kg (sodium carbonate) LC 50(rat, 4 hrs): 1150mg/m 3 (sodium carbonate) Carcinogenicity None of the ingredients are listed as a carcinogen by IARC, ACGIH, NTP and OSHA.
6 Page 6 of 7 Reproductive Toxicity Teratogenicity Mutagenicity Fish Toxicity Section 12 - Ecological Information Biodegradability Environmental Effects.. No available data on the product itself regarding environmental effects. Section 13 - Disposal Consideration Waste Disposal Dispose in accordance with all federal, provincial, and/or local regulations including the Canadian Environmental Protection Act. TDG Classification Class Group III PIN Number UN 1759 Other... Section 14 - Transport Information Secure containers (full and/or empty) with suitable hold down devises during shipment and ensure all caps, valves, or closures are secured in the closed position. PRODUCT CLASSIFICATION: This product has been classified on the preparation date specified at section 16 of this MSDS / SDS, for transportation in accordance with the requirements of part 2 of the Transportation of Dangerous Goods Regulations. If applicable, testing and/or published test data regarding the classification of this product are listed in the references at section 16 of this MSDS / SDS. WHMIS Classification......C, D2, E Section 15 - Regulatory Information
7 Page 7 of 7 NOTE: THE PRODUCT LISTED ON THIS MSDS HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CANADIAN CONTROLLED PRODUCTS REGULATIONS. THIS MSDS CONTAINS ALL INFORMATION REQUIRED BY THOSE REGULATIONS. Section 16 - Other Information Note: The responsibility to provide a safe workplace remains with the user. The user should consider the health hazards and safety information contained herein as a guide and should take those precautions required in an individual operation to instruct employees and develop work practice procedures for a safe work environment. The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by the use of this material. It is the responsibility of the user to comply with all applicable laws and regulations. Attention: Receiver of the chemical goods / MSDS coordinator As part of our commitment to the Canadian Association of Chemical Distributors (CACD) Responsible Distribution initiative, ClearTech Industries Inc. and its associated companies require, as a condition of sale, that you forward the attached Material Safety Data Sheet(s) to all affected employees, customers, and end-users. ClearTech will send any available supplementary handling, health, and safety information to you at your request. If you have any questions or concerns please call our customer service or technical service department. ClearTech Industries Inc. - Locations Corporate Head Office: 1500 Quebec Avenue, Saskatoon, SK, S7K 1V7 Phone: Fax: Location Address Postal Code Phone Number Fax Number Richmond, B.C Horseshoe Way V7A 4X Calgary, AB. 5516E - 40 th St. S.E. T2C 2A Edmonton, AB nd Street T5L 2G Saskatoon, SK. North Corman Industrial Park S7K 1V Regina, SK. 555 Henderson Drive S42 5X Winnipeg, MB. 340 Saulteaux Crescent R3J 3T Mississauga, ON Bath Road L4T 1L Hour Emergency Number - All Locations
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