Safety Data Sheet. according to Regulation (EC) No. 1907/2006. WICKES Trims Solvent Based

Transcription

1 Page 1 of 7 SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifier Further trade names Trade Eggshell BW (W709690) Trade Liquid Gloss BW (W709462) Trade Non Drip Gloss BW (W709445) Trade Satinwood (W70974) Exterior Gloss (W709866) Primer Wood (W709599) Gloss Liquid (W709881) Gloss Non-Drip (W709848) Eggshell Professional (W709590) Gloss One Coat (W709902) Satin One Coat (W709906) Abbreviation: W004 Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Coating material Alkyd resin lacquer in hydrocarbons Details of the supplier of the safety data sheet Company name: Street: Place: Lodge Way House Harlestone Road NN5 7UG Northampton Telephone: safetydatasheet@jwo.com Contact person: Customer Service Telephone: Internet: Emergency telephone: SECTION 2: Hazards identification Classification of the substance or mixture Label elements R-phrases: Flammable. Repeated exposure may cause skin dryness or cracking. R phrases 10 Flammable. 66 Repeated exposure may cause skin dryness or cracking. S phrases 02 Keep out of the reach of children. 2 Do not breathe vapour. 24 Avoid contact with skin. 46 If swallowed, seek medical advice immediately and show this container or label. 51 Use only in well-ventilated areas. Special labelling of certain mixtures Contains Butanonoxim. May produce an allergic reaction.

2 Page 2 of 7 Additional advice on labelling According to EC-regulations the product is to be labelled as follows: SECTION : Composition/information on ingredients Mixtures Chemical characterization Alkyd resin lacquer in hydrocarbons Hazardous components EC No. CAS No. Index No. REACH No Chemical name Classification GHS classification Naphtha (petroleum) Xn R65-66 Quantity % butanone oxime, ethyl methyl ketone oxime, ethyl methyl ketoxime Carc. Cat., Xn, Xi R Carc. 2, Acute Tox. 4, Eye Dam. 1, Skin Sens. 1; H51 H12 H18 H17 Fatty acids, C6-19-branched, cobalt(ii) salts Xn, Xi R < 1 % <1 % Full text of R- and H-phrases: see section 16. SECTION 4: First aid measures Description of first aid measures General information Remove contaminated soaked clothing immediately. If you feel unwell, seek medical advice. Take away from danger area and lay down affected person. After inhalation Move to fresh air in case of accidental inhalation of vapours. In the event of symptoms refer for medical treatment. After contact with skin Wash off immediately with soap and plenty of water. Treat subsequently with skin cream. After contact with eyes Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye irritation persists, consult a specialist. After ingestion Induce vomiting only upon the advice of a physician. Attention. Beware, danger of aspiration. Do not induce vomiting. Summon a doctor immediately. SECTION 5: Firefighting measures Extinguishing media

3 Page of 7 Suitable extinguishing media Alcohol-resistant foam, dry chemical, carbon dioxide (CO2), water-spray. Extinguishing media which must not be used for safety reasons Full water jet. Special hazards arising from the substance or mixture Carbon monoxide and carbon dioxide. Advice for firefighters Use breathing apparatus with independent air supply. Additional information Vapours are heavier than air and spread along ground. The vapour/air mixture is explosive, even in empty, uncleaned receptacles. Cool containers at risk with water spray jet. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures In case of vapour formation use respirator. Ensure adequate ventilation. Remove persons to safety. Use personal protective clothing. Keep away sources of ignition. Environmental precautions Do not discharge into the drains/surface waters/groundwater. Methods and material for containment and cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder). Shovel into suitable container for disposal. SECTION 7: Handling and storage Precautions for safe handling Advice on safe handling Keep container tightly closed. Avoid contact with eyes and skin. Use only in thoroughly ventilated areas. Advice on protection against fire and explosion Keep away from heat and sources of ignition. Do not smoke. Take precautionary measures against static discharges (earthing (grounding ) at pouring ). Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep container tightly closed in a dry, cool and well-ventilated place. Pay attention to anti-explosion rules. Advice on storage compatibility Incompatible with oxidizing agents. Further information on storage conditions Keep away from food, drink and animal feeding stuffs. SECTION 8: Exposure controls/personal protection Control parameters Exposure controls

4 Page 4 of 7 Occupational exposure controls Ensure adequate ventilation, especially in confined areas. Protective and hygiene measures Avoid contact with eyes and skin. Wash hands before breaks and immediately after handling the product. When using, do not eat, drink or smoke. Take off immediately all contaminated clothing. Respiratory protection If ventilation insufficient, wear respiratory protection. Breathing apparatus in the event of high concentrations. Hand protection Gloves (solvent-resistant) This recommendation refers exclusively to the chemical compatibility and the lab test conforming to EN 74 carried out under lab conditions. Requirements can vary as a function of the use. Therefore it is necessary to adhere additionally to the recommendations given by the manufacturer of protective gloves. Eye protection Tightly fitting goggles. Skin protection Long sleeved clothing. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties Physical state: Colour: Odour: Changes in the physical state Flash point: Density: Water solubility: (at 20 C) Flow time: Solvent content: SECTION 10: Stability and reactivity Liquid - viscous Various Characteristic C 1,15-1,56 g/cm³ Immiscible > 0 s < 50 % Test method mm Conditions to avoid To avoid thermal decomposition, do not overheat. In use formation of flammable/explosive vapour-air mixtures possible. Incompatible materials Oxidizing agents. Hazardous decomposition products Carbon monoxide and carbon dioxide. Further information No decomposition if stored and applied as directed. SECTION 11: Toxicological information Information on toxicological effects

5 Page 5 of 7 Acute toxicity CAS No. Chemical name Exposure routes Method Dose Species butanone oxime, ethyl methyl ketone oxime, ethyl methyl ketoxime Acute dermal toxicity ATE 1100 mg/kg h Source Sensitizing effects No sensitization respnses were observed. Empirical data on effects on humans Components of the product may be absorbed into the body through the skin. (skin absorption). The product causes burns of eye, skin and the mucous membranes. Further information Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea. Repeated or prolonged exposure may cause irritation of eyes and skin. SECTION 12: Ecological information Toxicity CAS No Chemical name Aquatic toxicity Method Dose Species 2-butanone oxime, ethyl methyl ketone oxime, ethyl methyl ketoxime Acute crustacea toxicity EC mg/l Daphnia magna 48 h Source Bioaccumulative potential Partition coefficient n-octanol/water CAS No. Chemical name butanone oxime, ethyl methyl ketone oxime, ethyl methyl ketoxime 0,6 Further information Ecological injuries are not known or expected under normal use. Do not flush into surface water or sanitary sewer system. Hazardous water pollutant. SECTION 1: Disposal considerations Waste treatment methods Advice on disposal Where possible recycling is preferred to disposal. Can be incinerated, when in compliance with local regulations. Old paints, uncured Waste disposal number of waste from residues/unused products WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS; wastes from MFSU and removal of paint and varnish; waste paint and varnish containing organic solvents or other dangerous substances Classified as hazardous waste. Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal. Log Pow

6 Page 6 of 7 SECTION 14: Transport information Land transport (ADR/RID) UN number: UN proper shipping name: Transport hazard class(es): Packing group: Hazard label: 126 Paint III Hazard-no.: 0 Other applicable information (land transport) Viscous substance - excepted quantity if in containers with a capacity up to 450 l (subsection ADR). Marine transport UN number: UN proper shipping name: Transport hazard class(es): Packing group: Marine pollutant: EmS: 126 PAINT III No F-E; S-E Other applicable information (marine transport) Viscous substance - excepted quantity if in containers with a capacity up to 0 l (subsection IMDG Code). Air transport UN/ID number: UN proper shipping name: Transport hazard class(es): Packing group: Hazard label: 126 PAINT III Other applicable information (air transport) PAC 09 (60 L), CAC 10 (220 L) SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulatory information 1999/1/EC (VOC): Additional information Directive 2004/42/EG: compliant 1907/2006/EG REACH: compliant 2004/42/EG A/d 00 (2010) max. 00 g/l VOC 2004/42/EG A/e 500 (2010) max. 500 g/l VOC

7 Page 7 of 7 National regulatory information Water contaminating class (D): 2 - water contaminating Additional information According to annex VI of the Council Directive 67/548/EEC on classification, packaging and labelling of dangerous substances, the R-phrase R65 is not assigned in case of a flow time > 0 s SECTION 16: Other information Changes * (0,14 /Min. aus dem deutschen Festnetz, Mobilfunknetz max. 0,42, ggf. Abweichende Preise aus dem europ. Ausland) Full text of R-phrases referred to under sections 2 and 10 Flammable. 21 Harmful in contact with skin. 22 Harmful if swallowed. 8 Irritating to skin. 40 Limited evidence of a carcinogenic effect. 41 Risk of serious damage to eyes. 4 May cause sensitization by skin contact. 65 Harmful: may cause lung damage if swallowed. 66 Repeated exposure may cause skin dryness or cracking. Full text of H-Statements referred to under sections 2 and H12 Harmful in contact with skin. H17 May cause an allergic skin reaction. H18 Causes serious eye damage. H51 Suspected of causing cancer. Further Information Data of items 4 to 8, as well as 10 to 12, do partly not refer to the use and the regular employing of the product (in this sense consult information on use and on product), but to liberation of major amounts in case of accidents and irregularities. The information describes exclusively the safety requirements for the product(s) and is based on the present level of our knowledge. The delivery specifications are contained in the corresponding product sheet. This data does not constitute a guarantee for the characteristics of the product(s) as defined by the legal warranty regulations. (n.a. = not applicable; n.d. = not determined) (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)