Risalah Data Keselamatan Safety data sheet

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1 Risalah Data Keselamatan Safety data sheet Mukasurat (Page): 1/18 1. Pengenalan bahan kimia dan pembekal Texapon SB 3 KC Kegunaan: kandungan kosmetik Syarikat: BASF (Malaysia) Sdn Bhd No 2, Jalan Astaka U8/87 Bukit Jelutong, Seksyen U Shah Alam, Selangor, MALAYSIA Nombor Telefon: Nombor Telefax: Maklumat kecemasan: Nombor Kecemasan Antarabangsa Nombor Telefon: Pengenalan Bahaya Pengelasan bahan dan campuran: Kerengsaan mata/ kerosakan mata yang serius: Kat. 1 Unsur label dan pernyataan berjaga-jaga: Piktogram: Kata Isyarat:

2 Mukasurat (Page): 2/18 bahaya Pernyataan Bahaya: Menyebabkan kerosakan mata yang serius. Pernyataan Berjaga-jaga (Pencegahan): Pakai pelindung mata/muka. Pernyataan Berjaga-jaga (Tindak Balas): JIKA TERKENA MATA: Bilas berhati-hati dengan air selama beberapa minit.tanggalkan kanta lekap, jika ada dan dapat dilakukan dengan mudah. Teruskan membilas. Segera hubungi PUSAT RACUN atau doktor/pakar perubatan. Bahaya lain yang tidak menyebabkan pengelasan: Tiada bahaya khusus yang diketahui jika peraturan/nota tentang penyimpanan dan pengendalian diberikan perhatian. 3. Komposisi dan Maklumat Mengenai Ramuan Bahan Kimia Keadaan kimia Larutan akueus berdasarkan : Sulfosuccinic acid, monoester with alcohols C10-16 and EO, disodium salts Ramuan berbahaya Sulfosuccinic acid, monoester with alcohols C10-16 and EO, disodium salts Kandungan (berat/berat): >= 30 % Eye Dam./Irrit.: Kat. 1 - < 50 % Nombor CAS: Bagi pengelasan yang tidak ditulis dengan penuh dalam bahagian ini, teks lengkap boleh didapati di bahagian Langkah-Langkah Pertolongan Cemas Nasihat am: Jika kesan-kesan kesihatan yang buruk berkembang dapatkan rawatan perubatan. Jika tersedut: tidak berkenaan. Apabila terkena kulit: Jika terkena kulit, segera basuh dengan air yang banyak. Apabila terkena mata: Segera basuh dengan air mengalir yang banyak (selama 10 minit), dapatkan rawatan perubatan daripada pakar.

3 Mukasurat (Page): 3/18 Apabila tertelan: Segera basuh mulut dan kemudian minum ml air. Nota kepada doktor: Gejala: Gejala dan kesan terpenting yang diketahui diterangkan didalam label (lihat bahagian 2) dan/atau bahagian 11., Gejala dan kesan penting selanjutnya tidak diketahui setakat ini. Nota kepada doktor: Bahaya: Tiada bahaya dijangka dengan penggunaan yang disyorkan dan pengendalian yang sesuai. Rawatan: Rawat mengukit gejala. 5. Langkah-Langkah Pemadaman Kebakaran Bahan pemadam yang sesuai: semburan air, karbon dioksida, serbuk kering, busa Bahaya tertentu: wap yang merbahaya Evolusi wasap/kabus. Bahan/kumpulan bahan yang dinyatakan boleh dibebaskan jika berlaku kebakaran. Maklumat lanjut: Lupuskan sisa kebakaran dan air pemadam api yang tercemar menurut peraturan rasmi. 6. Langkah-Langkah Pelepasan Tidak Sengaja Langkah pencegahan diri: Gunakan pakaian pelindung diri. Langkah berjaga-jaga untuk alam sekitar: Jangan lepaskan ke dalam parit/air permukaan/air tanah. Kaedah pembersihan atau penyerapan: Bagi sejumlah kecil: Kutip dengan bahap penyerap yang sesuai. Bagi sejumlah besar: Bina benteng tumpahan. Pam produk. Lupuskan bahan yang diserap mengikut peraturan. 7. Pengendalian dan Penyimpanan; Pengendalian Kendalikan mengikut amalan kesihatan dan keselamatan industri yang baik. Perlindungan terhadap kebakaran dan letupan: Ambil langkah berjaga-jaga terhadap luahan statik. Jauhkan dari semua sumber pencucuhan: haba, percikan api, nyalaan terbuka.

4 Mukasurat (Page): 4/18 Penyimpanan Bahan yang sesuai untuk bekas: Polietilena ketumpatan tinggi (HDPE) Maklumat lanjut tentang keadaan penyimpanan: Pastikan bekas tertutup rapat dan kering; simpan di tempat yang dingin. Simpan terlindung daripada pembekuan. Dibawah had suhu, produk tidak boleh dipam. Di bawah had suhu, ciri produk akan berubah. Perubahan ciri boleh berbalik dengan mengacau dan memanaskan bahan. Pengangkutan pukal (pengangkut/lori tangki, kontena) produk perlu diselaraskan dengan pemilik produk terlebih dahulu. Sila rujuk risalah teknikal untuk maklumat lanjut. Pengurangan jirim aktif mungkin berlaku. Sila periksa! Kestabilan penyimpanan: Suhu penyimpanan: <= 40 C Lindungi daripada suhu di bawah : 10 C Dibawah had suhu, produk tidak boleh dipam. Lindungi daripada suhu melebihi : 40 C Cirii produk berubah secara tidak berbalik jika melebihi had suhu. 8. Kawalan pendedahan dan perlindungan diri Komponen dengan parameter kawalan tempat kerja Tiada had pendedahan pekerjaan yang diketahui. Peralatan perlindungan peribadi Perlindungan pernafasan: Perlindungan pernafasan tidak diperlukan. Perlindungan tangan: Perlindungan tangan tidak diperlukan Perlindungan mata: Gogal keselamatan yang betul-betul muat (gogal tahan percikan) (EN 166) Perlindungan badan: Perlindungan badan mesti dipilih bergantung kepada aktiviti dan pendedahan, contohnya apron, kasut perlindungan, pakaian perlindungan bahan kimia (Berdasarkan DIN-EN 465) Langkah kebersihan dan keselamatan am: Kendalikan mengikut amalan kesihatan dan keselamatan industri yang baik. Jangan makan, minum, merokok atau menggunakan tembakau di tempat kerja. Kendalikan mengikut amalan kesihatan dan keselamatan industri yang baik.

5 Mukasurat (Page): 5/18 9. Sifat Fizikal dan Kimia Bentuk: Warna: Bau: Ambang bau: cecair Tidak berwarna sedikit berbau Tidak boleh digunakan nilai ph: (air, 20 C) Suhu didih: > 100 C Takat kilat: > 101 C sediaan berakua Tahap penyejatan: Nilai boleh dianggarkan berdasarkan Pemalar Hukum Henry atau tekanan wap. Kemudahbakaran (pepejal/gas): tidak mencucuh Had letupan bawah: Untuk cecair tiada kaitan untuk pengelasan dan pelabelan. Had letupan atas: Untuk cecair tiada kaitan untuk pengelasan dan pelabelan. Suhu pencucuhan: tidak ditentukan Penguraian terma: pencucuhan sendiri: Tiada penguraian jika disimpan dan dikendalikan seperti yang ditetapkan/dinyatakan. Tidak boleh digunakan Bahaya letupan: tidak mudah meletup Sifat yang menggalakkan kebakaran: tidak merebakkan api Tekanan Wap: tidak ditentukan Kepekatan: g/cm3 (20 C) Ketumpatan wap relatif (udara): Tidak boleh digunakan (DGF C-IV 2; QP1100.0; Ketumpatan) Keterlarutan dalam air: terlarut Pekali petakan n-oktanol/air (log Pow): tidak ditentukan Kelikatan, dinamik: Kelikatan, kinematik: tidak ditentukan tidak ditentukan

6 Mukasurat (Page): 6/18 Maklumat lain: Jika perlu, maklumat tentang parameter fizikal and kimia ada dinyatakan didalam bahagian ini. Tiada maklumat lain didapati. 10. Kestabilan dan Kereaktifan Keadaan yang perlu dielakkan: Lihat MSDS bahagian 7 - Pengendalian dan Penyimpanan. Penguraian terma: Tiada penguraian jika disimpan dan dikendalikan seperti yang ditetapkan/dinyatakan. Bahan yang perlu dielakkan: Tiada bahan yang diketahui perlu dielakkan. Tindak balas berbahaya: Tiada jika digunakan untuk tujuan yang dimaksudkan. Tiada produk penguraian yang berbahaya jika disimpan dan dikendalikan seperti yang ditetapkan/dinyatakan. 11. Maklumat Toksikologi Ketoksikan akut Penilaian ketoksikan akut: Tidak toksik selepas sekali ditelan. Data eksperimen/dikira: LD50 (melalui mulut): > 2,000 mg/kg (Arahan 84/449/EEC, B.1) Kerengsaan Penilaian kesan merengsa: Boleh menyebabkan kerosakkan teruk kepada mata. Tidak merengsakan kulit. Data eksperimen/dikira: Kakisan/Kerengsaan kulit arnab: tidak merengsa (Garispanduan OECD 404) Kerosakkan/kerengsaan mata yang serius arnab: kerosakan tak berbalik (Garispanduan OECD 405) Pemekaan pernafasan/kulit Penilaian pemekaan: Tidak terdapat bukti pemekaan kulit yang berpotensi. Kemutagenan sel germa

7 Mukasurat (Page): 7/18 Penilaian kemutagenan: Struktur kimia tidak menunjukkan amaran khusus bagi kesan tersebut. Data eksperimen/dikira: Ujian Ames Bakteria: negatif (Garispanduan OECD 471) Kekarsinogenan Penilaian kekarsinogenan: Struktur kimia tidak menunjukkan amaran khusus bagi kesan tersebut. Ketoksikan pembiakan Penilaian ketoksikan pembiakan: Struktur kimia tidak menunjukkan amaran khusus bagi kesan tersebut. Ketoksikan perkembangan Penilaian keteratogenan: Tiada data diperoleh tentang ketoksikan. Ketoksikan khusus organ sasaran (sekali pendedahan): Penilaian sekali STOT: Berdasarkan data yang ada, kriteria pengelasan tidak dipenuhi. Ketoksikan dos berulang dan Ketoksikan organ sasaran tertentu (pendedahan berulang) Penilaian ketoksikan dos berulang: Maklumat yang ada tentang produk tidak memberi petunjuk tentang ketoksikan kepada organ sasaran selepas pendedahan secara berulang-ulang. Bahaya penyedutan Tiada bahaya penyedutan dijangka. Maklumat lain yang berkaitan dengan ketoksikan Produk belum diuji. Penyataan tentang toksikologi diambil daripada ciri setiap komponen. 12. Maklumat Ekologi Keekotoksikan Penilaian ketoksikan akuatik: Produk belum diuji. Penyataan diambil daripada ciri setiap komponen.

8 Mukasurat (Page): 8/18 Ketoksikan kepada ikan: LC50 > mg/l (DIN EN ISO ) Mikroorganisma/Kesan ke atas enap cemar diaktifkan: EC0 > mg/l (Garispanduan OECD 209) Mobiliti Penilaian pengangkutan di antara bahagian di persekitaran: Tidak boleh digunakan Keterusan dan boleh keterdegradasikan Penilaian biodegradasi dan penyingkiran (H2O): Mudah terbiodegradasikan (menurut kriteria OECD) Maklumat penyingkiran: (Lampiran III, bahagian A) Zat aktif permukaan yang terkandung didalam sediaan ini mematuhi kriteria keterbiodegradasikan seperti yang ditetapkan dalam Peraturan (EC) No.648/2004 tentang bahan cuci. Data untuk menyokong fakta ini adalah di bawah kawalan pihak berkuasa kompeten Negara Anggota, dan data ini boleh didapati secara terus oleh Negara Anggota atau atas permintaan pengilang bahan cuci. Potensi Biotumpukan Penilaian potensi bioakumilasi: Tiada data diperoleh. 13. Maklumat Pelupusan Mestilah dibuang atau dibakar mengikut peraturan tempatan. 14. Maklumat Pengangkutan Pengangkutan domestik: Tidak dikelaskan sebagai berbahaya di bawah peraturan pengangkutan Pengangkutan laut IMDG Tidak dikelaskan sebagai berbahaya di bawah peraturan pengangkutan Pengangkutan udara IATA/ICAO Tidak dikelaskan sebagai berbahaya di bawah peraturan pengangkutan

9 Mukasurat (Page): 9/18 Pengangkutan secara pukal menurut Lampiran II MARPOL dan IBC Peraturan: Tidak dinilai Penghantaran yang Tidak dinilai diluluskan: Nama pencemaran: Tidak dinilai Kategori pencemaran: Tidak dinilai Jenis Kapal: Tidak dinilai 15. Maklumat Pengawalseliaan Peraturan lain Jika maklumat peraturan lain yang berkenaan tidak dinyatakan dibahagian lain didalam risalah data keselamatan ini, ianya akan dinyatakan bahagian ini. 16. Maklumat lain Maklumat bagi penggunaan yang dirancang: Produk ini adalah berkualiti untuk industri dan sekiranya tidak dinyatakan atau dipersetujui harus digunakan semata-mata untuk kegunaan industri. Ini termasuk penggunaan yang dinyatakan dan disyorkan. Sebarang tujuan penggunaan lain hendaklah dibincangkan dengan pengeluar. Secara khususnya, ini berkaitan dengan penggunaan bagi produk yang menjadi objek piawai dan peraturan khas Teks penuh pengelasan, simbol bahaya dan pernyataan bahaya, jika dinyatakan dalam seksyen 2 atau 3: Eye Dam./Irrit. Kerengsaan mata/ kerosakan mata yang serius Garis menegak pada margin sebelah kiri tangan menunjukkan pindaan dari versi sebelumnya. Data yang terdapat dalam risalah data keselamatan ini adalah berdasarkan pengetahuan dan pengalaman kami, dan menerangkan tentang produk yang berkaitan dengan keperluan keselamatan sahaja. Data tidak menyatakan ciri produk (spesifikasi produk). Data dalam risalah data keselamatan ini juga tidak menyatakan apa-apa ciri khusus atau kesesuaian produk yang dipersetujui untuk apa-apa tujuan tertentu. Penerima produk bertanggungjawab untuk memastikan bahawa apa-apa hak pemilikan serta undang-undang dan perundangan sedia ada dipatuhi.

10 Mukasurat (Page): 10/18 1. Identification of the chemical and of the supplier Texapon SB 3 KC Use: cosmetic ingredient Company: BASF (Malaysia) Sdn Bhd No 2, Jalan Astaka U8/87 Bukit Jelutong, Seksyen U Shah Alam, Selangor, MALAYSIA Telephone: Telefax number: Emergency information: International emergency number: Telephone: Hazard identification Classification of the substance and mixture: Serious eye damage/eye irritation: Cat. 1 Label elements and precautionary statement: Pictogram: Signal Word: Danger Hazard Statement: Causes serious eye damage. Precautionary Statements (Prevention): Wear eye/face protection. Precautionary Statements (Response): IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Other hazards which do not result in classification: No specific dangers known, if the regulations/notes for storage and handling are considered.

11 Mukasurat (Page): 11/18 3. Composition/information on ingredients Chemical nature Aqueous solution based on: Sulfosuccinic acid, monoester with alcohols C10-16 and EO, disodium salts Hazardous ingredients Sulfosuccinic acid, monoester with alcohols C10-16 and EO, disodium salts Content (W/W): >= 30 % - < 50 % Eye Dam./Irrit.: Cat. 1 CAS Number: For the classifications not written out in full in this section the full text can be found in section First-Aid Measures General advice: If adverse health effects develop seek medical attention. If inhaled: not relevant. On skin contact: After contact with skin, wash immediately with plenty of water. On contact with eyes: Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. On ingestion: Rinse mouth and then drink ml of water. Note to physician: Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known. Note to physician: Hazards: No hazard is expected under intended use and appropriate handling. Treatment: Treat symptomatically. 5. Fire-Fighting Measures Suitable extinguishing media: water spray, carbon dioxide, dry powder, foam Specific hazards: harmful vapours

12 Mukasurat (Page): 12/18 Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Further information: Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. 6. Accidental Release Measures Personal precautions: Use personal protective clothing. Environmental precautions: Do not discharge into drains/surface waters/groundwater. Methods for cleaning up or taking up: For small amounts: Pick up with suitable absorbent material. For large amounts: Dike spillage. Pump off product. Dispose of absorbed material in accordance with regulations. 7. Handling and Storage Handling Handle in accordance with good industrial hygiene and safety practice. Protection against fire and explosion: Take precautionary measures against static discharges. Avoid all sources of ignition: heat, sparks, open flame. Storage Suitable materials for containers: High density polyethylene (HDPE) Further information on storage conditions: Keep container tightly closed and dry; store in a cool place. Store protected against freezing. Below the temperature limit, the product is no longer pumpable. Below temperature limit the product properties will change. The property change is reversible by stirring and heating. Bulk shipping (Tank car/truck, container) of the product has to be coordinated with the product owner in advance. Please refer to the technical leaflet for further information. A reduction of the active matter is possible. Please check! Storage stability: Storage temperature: <= 40 C Protect from temperatures below: 10 C Below the temperature limit, the product is no longer pumpable. Protect from temperatures above: 40 C Properties of the product change irreversibly on exceeding the limit temperature.

13 Mukasurat (Page): 13/18 8. Exposure controls and personal protection Components with occupational exposure limits No occupational exposure limits known. Personal protective equipment Respiratory protection: Respiratory protection not required. Hand protection: Hand protection not required. Eye protection: Tightly fitting safety goggles (splash goggles) (e.g. EN 166) Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN in case of splashes or EN ISO in case of dust). General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. No eating, drinking, smoking or tobacco use at the place of work. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and Chemical Properties Form: Colour: Odour: Odour threshold: liquid colourless slight odour not applicable ph value: (water, 20 C) (DGF-H-III 1) boiling temperature: > 100 C Flash point: > 101 C Aqueous preparation Evaporation rate: Value can be approximated from Henry's Law Constant or vapor pressure. Flammability (solid/gas): not flammable

14 Mukasurat (Page): 14/18 Lower explosion limit: Upper explosion limit: Ignition temperature: For liquids not relevant for classification and labelling. For liquids not relevant for classification and labelling. not determined Thermal decomposition: No decomposition if stored and handled as prescribed/indicated. Self ignition: not applicable Explosion hazard: not explosive Fire promoting properties: not fire-propagating Vapour pressure: not determined Density: g/cm3 (20 C) Relative vapour density (air): not applicable (DGF C-IV 2; QP1100.0; Density) Solubility in water: soluble Partitioning coefficient n-octanol/water (log Pow): not determined Viscosity, dynamic: Viscosity, kinematic: not determined not determined Other Information: If necessary, information on other physical and chemical parameters is indicated in this section. No further information available. 10. Stability and Reactivity Conditions to avoid: See MSDS section 7 - Handling and storage. Thermal decomposition: No decomposition if stored and handled as prescribed/indicated. Substances to avoid: No substances known that should be avoided. Hazardous reactions: None if used for intended purpose. No hazardous decomposition products if stored and handled as prescribed/indicated.

15 Mukasurat (Page): 15/ Toxicological Information Acute toxicity Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Experimental/calculated data: LD50 (oral): > 2,000 mg/kg (Directive 84/449/EEC, B.1) Irritation Assessment of irritating effects: May cause severe damage to the eyes. Not irritating to the skin. Experimental/calculated data: Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404) Serious eye damage/irritation rabbit: irreversible damage (OECD Guideline 405) Respiratory/Skin sensitization Assessment of sensitization: There is no evidence of a skin-sensitizing potential. Germ cell mutagenicity Assessment of mutagenicity: The chemical structure does not suggest a specific alert for such an effect. Experimental/calculated data: Ames-test Bacteria: negative (OECD Guideline 471) Carcinogenicity Assessment of carcinogenicity: The chemical structure does not suggest a specific alert for such an effect. Reproductive toxicity Assessment of reproduction toxicity: The chemical structure does not suggest a specific alert for such an effect. Developmental toxicity Assessment of teratogenicity: No data was available concerning toxicity to development.

16 Mukasurat (Page): 16/18 Specific target organ toxicity (single exposure): Assessment of STOT single: Based on available Data, the classification criteria are not met. Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: The information available on the product provides no indication of toxicity on target organs after repeated exposure. Aspiration hazard No aspiration hazard expected. Other relevant toxicity information The product has not been tested. The statements on toxicology have been derived from the properties of the individual components. 12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: The product has not been tested. The statement has been derived from the properties of the individual components. Toxicity to fish: LC50 > mg/l (DIN EN ISO ) Microorganisms/Effect on activated sludge: EC0 > mg/l (OECD Guideline 209) Mobility Assessment transport between environmental compartments: not applicable Persistence and degradability Assessment biodegradation and elimination (H2O): Readily biodegradable (according to OECD criteria). Elimination information: (Annex III, part A) The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them at their direct request or at the request of a detergent manufacturer.

17 Mukasurat (Page): 17/18 Bioaccumulation potential Assessment bioaccumulation potential: No data available. 13. Disposal Considerations Must be disposed of or incinerated in accordance with local regulations. 14. Transport Information Domestic transport: Not classified as a dangerous good under transport regulations Sea transport IMDG Not classified as a dangerous good under transport regulations Air transport IATA/ICAO Not classified as a dangerous good under transport regulations Transport in bulk according to Annex II of MARPOL and the IBC Code Regulation: Not evaluated Shipment approved: Not evaluated Pollution name: Not evaluated Pollution category: Not evaluated Ship Type: Not evaluated 15. Regulatory Information Other regulations If other regulatory information applies that is not already provided elsewhere in this safety data sheet, then it is described in this subsection.

18 Mukasurat (Page): 18/ Other Information Information on intended use: This product is of industrial quality and unless otherwise specified or agreed intended exclusively for industrial use. This includes the mentioned and recommended usage. Any other intended applications should be discussed with the manufacturer. In particular this concerns the application for products that are the object of special standards and regulations. Full text of classifications, hazard symbols and hazard statements, if mentioned in section 2 or 3: Eye Dam./Irrit. Serious eye damage/eye irritation Vertical lines in the left hand margin indicate an amendment from the previous version. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.

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